Effect of high temperature compression deformation strain rate on the microstructure and corrosion behavior of 2205 duplex stainless steel

2015 ◽  
Vol 62 (3) ◽  
pp. 163-171 ◽  
Author(s):  
Yinhui Yang ◽  
Biao Yan

Purpose – The aim of this paper was to investigate the effect of strain rate on microstructure and corrosion behavior of 2205 duplex stainless steel, after high-temperature compression tests. Design/methodology/approach – The specimens were prepared using a Gleeble3800 thermo-simulation machine over a range of temperatures from 850 to 1,250°C and strain rates from 0.005 to 5 s−1, and the corresponding flow curves and deformation microstructure obtained were further analyzed. To evaluate the effect of strain rate on corrosion behavior, potentiodynamic polarization tests and double-loop electrochemical potentiodynamic reactivation (DL-EPR) were used to characterize the electrochemical performance. Findings – Compared with strain rate of 0.5 s−1, the worst corrosion resistance behavior from the potentiodynamic polarization test results after deformation at 0.005 s−1 was attributed to more austenite (γ) and ferrite (δ) grain boundaries or δ/γ phase interface formation due to the better effect of γ dynamic recrystallization (DRX) or δ dynamic recovery (DRV). Increasing strain rate to 5 s−1 lowered the corrosion resistance, due to the increase in dislocation density. At the low strain rate of 0.005 s−1, the susceptibility to intergranular corrosion (IGC) was comparatively high after deformation at 1050 and 1150°C with more γ/γ grains and δ/γ phase boundary formation, which was lowered with the strain rate increase to 0.5 s−1, due to suppressing effect of γ DRX. Originality/value – The paper provides the scientific basis for the practical application of hot working of 2205 duplex stainless steel.

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Chuanbo Zheng ◽  
Cheng Zhang ◽  
Xiao Yong Wang ◽  
Jie Gu

Purpose Duplex stainless steel is composed of equal amounts of austenite and ferrite, which has excellent corrosion resistance and strength. However, after the metal was welded, the ratio of austenite and ferrite in the joint is unbalanced, and secondary phase precipitates are produced, which is also an important cause of pitting corrosion in the joint. Design/methodology/approach This paper aims to study the mechanical and corrosion behavior of welded joints, by adjusting the welding parameters of laser hybrid welding, dual heat sources are used to weld 2205 duplex stainless steel. The two-phase content of different parts of the welded joint is measured to study the influence of the ratio of the two-phase on the mechanical and corrosion properties of the joint. Findings The ratio of austenite and ferrite in different welded joints has an obvious difference, and from top to bottom, the austenite content decreased gradually, and the ferrite content increased gradually. The harmful phases are precipitated in the middle and lower part of the joint. The strength of welded joints is slightly lower than that of base metal. At the same time, the fracture analysis shows that some ferrite phases are affected by the precipitate in the grain and produce quasi-cleavage fracture. The corrosion results show that the corrosion resistance of the welded joints is lower than that of the base metal, and the concentration of chloride ions affects the corrosion resistance. Originality/value In this paper, the authors use the influence of different welding processes on the two-phase ratio of the joint to further study the influence of the microstructure on the corrosion resistance and mechanical properties of the weld.


2020 ◽  
Vol 67 (3) ◽  
pp. 313-320 ◽  
Author(s):  
Chuanbo Zheng ◽  
Jiayan Huang ◽  
Gua Yi

Purpose This paper aims to study the effect of current density of hydrogen charging on the semiconductor properties and pitting initiation of 2205 duplex stainless steel (DSS) passivation film. Design/methodology/approach In this work, the 2205 DSS is pre-hydrogenated and passivated. Then, the passivation film is tested by electrochemical impedance method, Mott–Schottky curve method and dynamic potential scanning method. The influences of hydrogen on the properties of the passivation film and the corrosion behavior of the matrix were studied by analyzing the curves obtained in the electrochemical test. The surface of the passivation film after pre-hydrogenation and anodic polarization was observed by using the ultra-depth three-dimensional microscopy and the scanning electron microscope. The integrity, density and corrosion morphology of the passivation film were studied and discussed. Findings With the increase of the hydrogen current density, the growth of the passivation film is hindered, the concentrations of donor and acceptor in the film are increased, the conductivity of the passivation film increases. In the anodic polarization, the dimensional passive current density increases with the increase of the hydrogen current density, and the pitting potential is reversed, the more likely the sample is pitting. In general, hydrogen hinders the formation of the passive film on duplex stainless steel, which increases the concentration of point defects in the passive film. Finally, the passive film is easy to crack and pitting. Originality/value The performance of passive film is an important condition to influence the corrosion behavior of stainless steel. However, little research has been done on the effects of hydrogen on the electrochemistry and pitting sensitivity of 2205 DSS passivation films. The effect of hydrogen on semiconductor properties and pitting initiation of 2205 DSS passivation film is needed to be investigated.


2022 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Juan Du ◽  
Mengyao Yu ◽  
Pingli Liu ◽  
Yongqiang Fu ◽  
Gang Xiong ◽  
...  

Purpose This paper aims to analyze the high temperature (200°C) corrosion behavior of 2205 duplex stainless steel in acidizing stimulation solution containing hydrochloric acid (HCl) and acetic acid. Design/methodology/approach The corrosion rate of 2205 duplex stainless steel in all kinds of acid solutions was calculated through immersion tests and electrochemical test. The corrosion product composition is analyzed by X-ray diffraction analysis. The element composition and element distribution before and after corrosion were analyzed by an X-ray energy spectrometer. The corrosion morphology of the steel surface was observed by a scanning electron microscope. Both static and dynamic corrosion experiments were carried out at 200°C. Findings The results show that 2205 duplex stainless steel has excellent corrosion resistance in low to high concentration acetic acid solutions, but increasing the concentration of Cl− in acetic acid solution will accelerate the corrosion rate. Low concentration HCl solution can cause serious corrosion to 2205 duplex stainless steel. The system of HCl and acetic acid will produce a synergistic effect on corrosion of 2205 duplex stainless steel and accelerate the corrosion. Sb2O3 is a good corrosion inhibitor synergist for high-temperature acidizing stimulation solution. Originality/value The amount of HCl that is used in acidizing stimulation is usually determined by the dissolution effect of the acid on the rocks, but for ultra-high-temperature reservoirs, the amount of HCl should be based on reducing the corrosion of oil and gas wells.


2019 ◽  
Vol 66 (1) ◽  
pp. 61-66 ◽  
Author(s):  
Byung-Hyun Shin ◽  
Dohyung Kim ◽  
Sanghyup Park ◽  
Myungwon Hwang ◽  
Junghyun Park ◽  
...  

Purpose The secondary phase decreased the corrosion resistance because of the segregation of Cr and Mo. Therefore, this paper aims to study the precipitation condition and the effect of secondary phase with volume fraction on corrosion behavior. Design/methodology/approach Secondary phase precipitated approximately from 375°C to 975°C because of saturated Cr and Mo at grain boundary by growth of austenite. Therefore, heat treatment from 800°C to 1,300°C was applied to start the precipitation of the secondary phase. Findings The secondary phase is precipitated at 1,020°C because of segregation by heterogeneous austenite. The growth of austenite at 1,000°C needs the time to saturate the Cr and Mo at grain boundary. When the volume fraction of austenite is 56 per cent (14 min at 1,000°C), the secondary phase is precipitated with grain boundary of austenite. The secondary phase increased the current density (corrosion rate) and decreased the passivation. That is checked to the critical pitting temperature (CPT) curves. The 1 per cent volume fraction of secondary phase decreased CPT to 60°C from 71°C. Research limitations/implications The precipitation of secondary phase not wants anyone. Casted super-duplex stainless steel (SDSS) of big size precipitates the secondary phase. This study worked the precipitation condition and the suppression conditions of secondary phase. Social implications Manufacturers need precipitation condition to make high-performance SDSS. Originality/value The corrosion resistance of SDSS is hard the optimization because SDSS is dual-phase stainless steel. The precipitation of the secondary phase must be controlled to optimize of the corrosion resistance of SDSS. Anyone not studied the precipitation condition of secondary phase and the effect of secondary phase with volume fraction on corrosion behavior of SDSS.


2012 ◽  
Vol 581-582 ◽  
pp. 1054-1057
Author(s):  
Yin Hui Yang ◽  
Shao Hong Li

Under strain rate of 0.5s-1, the effect of deformation temperature on flow stress, microstructure and corrosion resistance of 2205 duplex stainless steel (DSS) was investigated. The dynamic recrystallization (DRX) of austenite phase was enhanced with the deformation temperature increasing from 850°C to 1050°C, meanwhile, the leading deformation mechanism changed from work hardening to DRX. When the deformation temperature was further increased to 1250°C, the dynamic recovery (DRV) of ferrite phase played a leading role. The specimen after deformation at 1050°C exhibited better DRX behavior, which leads to more γ/γ grain boundaries and δ/γ boundaries formation, increasing the occurrence of pitting corrosion, and it presented best corrosion resistance at 950°C.


Alloy Digest ◽  
1993 ◽  
Vol 42 (11) ◽  

Abstract ZERON 100 is a super duplex stainless steel which is manufactured to give a guaranteed corrosion performance by using an equation to control the chemistry in those elements which will determine the corrosion resistance of the material. Major usages in seawater applications, particularly offshore oil gathering systems. This datasheet provides information on composition, hardness, and tensile properties as well as fracture toughness. It also includes information on low and high temperature performance as well as heat treating, machining, and joining. Filing Code: SS-555. Producer or source: Weir Material Services Ltd.


Alloy Digest ◽  
2015 ◽  
Vol 64 (5) ◽  

Abstract ATI 2102 is a lean austenitic/ferritic duplex stainless steel. This datasheet provides information on composition, physical properties, hardness, and tensile properties. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, and joining. Filing Code: SS-1207. Producer or source: Allegheny Ludlum.


Author(s):  
Changqing Ye ◽  
Weiguo Zhai ◽  
Guangyao Lu ◽  
Qingsong Liu ◽  
Liang Ni ◽  
...  

In this paper, shielded metal arc welding on the dissimilar joint between 2205 duplex stainless steel and composite bimetallic plates (304 L stainless steel/10CrNi3MoV steel) with a filler metal E2209 was performed. Furthermore, the microstructure, phase, mechanical properties and intergranular corrosion resistance of the joints were investigated and element distributions of the interfaces were characterized. The results show that austenite transformed to ferrite under the influence of welding thermal cycle, and then a large amount of ferrite appeared in heat affected zone (HAZ) of 2205 duplex stainless steel. Coarse bainite grains were formed in HAZ of the 10CrNi3MoV steel near the fusion line with high temperature welding thermal cycle. Fine granular bainite was also generated in HAZ of 10CrNi3MoV steel due to the relatively short exposure time to the active temperature of grain growth. Local peak temperature near the base 10CrNi3MoV steel was still high enough to recrystallize the 10CrNi3MoV steel to form partial-recrystallization HAZ due to phase change. The filler metal was compatible with the three kinds of base materials. The thickness of the elemental diffusion interfaces layers was about 100 µm. The maximum microhardness value was obtained in the HAZ of 2205 duplex stainless steel (287 ± 14 HV), and the minimum one appeared in HAZ of SS304L (213 ± 5 HV). The maximum tensile strength of the welded joint was about 670 ± 6 MPa, and the tensile specimens fractured in ductile at matrix of the composite bimetallic plates. The impact energy of the weld metal and HAZ of the 10CrNi3MoV steel tested at –20 °C were 274 ± 6 J and 308 ± 5 J, respectively. Moreover, the intergranular corrosion resistance of the weldment including 304 L stainless steel, weld metal, HAZs and 2205 duplex stainless steel was in good agreement with the functional design requirements of materials corrosion resistance.


Coatings ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1042
Author(s):  
Panneer Selvam Kevin ◽  
Abhishek Tiwari ◽  
Saravanan Seman ◽  
Syed Ali Beer Mohamed ◽  
Rengaswamy Jayaganthan

Cr3C2–NiCr coatings have been used extensively to combat the erosion corrosion of hydro power turbine blades made of stainless steel. Cr3C2–NiCr coatings are also used in aqueous corrosive environments due to the high corrosion resistance rendered by the NiCr binder. In this investigation, both erosion and corrosion environments are introduced to cermet coating to study corrosion behavior using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The cermet coatings are useful for reducing the risk of deterioration of mechanical properties of hydro power turbines due to the continuous exposure to the erosive and corrosive action of the corrosive environment containing silt. It was observed that Cr3C2–NiCr coating offered a reasonable improvement in corrosion resistance when compared to bare substrate. The corrosion behavior of the coating was studied in a 150 mL solution of 0.1 M NaCl with 2 gms of quartz particles (0.2–0.8 mm) at various rotation speeds (3000, 4500, 6000 rpm) of the solution over a 1 h immersion using potentiodynamic polarization and EIS studies in a specifically designed experimental set-up for erosion corrosion. When compared to the bare stainless steel samples at 3000 rpm and 6000 rpm, the coating showed the highest improvement at 6.57 times and the least improvement at 3.79 times, respectively.


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