New corrosion inhibitor for 13Cr stainless steel in 20% HCl solution

2020 ◽  
Vol 67 (6) ◽  
pp. 557-564
Author(s):  
Pingli Liu ◽  
Yanhua Zhu ◽  
Liqiang Zhao
Keyword(s):  
Stainless Steel ◽  
Corrosion Inhibitor ◽  
Mannich Reaction ◽  
Corrosion Mechanism ◽  
Oil Well ◽  
Content Type ◽  
Layer Function ◽  
Corrosion Reaction ◽  
Hydrogen Evolution Reactions ◽  
Hcl Solution

Purpose A novel compound was synthesized by cyclohexylamine, acetophenone and cinnamaldehyde through Mannich reaction in laboratory to use as corrosion inhibitor for steel in acidification process. Design/methodology/approach The corrosion and inhibition of 13Cr stainless steel in conventional acidification solution were investigated by electrochemical measurements and soaking experiments. The corrosion appearance was observed with scanning electron microscope on the whole surface of 13Cr stainless steel in 20% HCl solution, and the protection film was confirmed on the surface in presence with inhibitor. Findings Results manifested that the inhibitor C23H27NO can effectively inhibit the corrosion reaction by forming an adsorption layer function as a barrier. Polarization curves indicated that the mixed inhibitor can reduce anodic dissolution and cathodic hydrogen evolution reactions simultaneously. The results of impedance measurements indicated that this inhibitor cannot change the corrosion mechanism of 13Cr stainless steel in 20% HCl solution. The results of the study can provide a theoretical basis for the application of 13Cr stainless steel in conventional acidification solutions during oil well acidification construction process. Originality/value A novel compound was synthesized by cyclohexylamine, acetophenone and cinnamaldehyde through Mannich reaction in laboratory to use as corrosion inhibitor for steel in acidification process. The corrosion and anti-corrosion mechanism of 13Cr steel in acid solution was proposed.

Corrosion and inhibition of N80 steel in 5% HCl solution by SA1-3

2017 ◽  
Vol 64 (6) ◽  
pp. 634-643 ◽  
Author(s):  
Liqiang Zhao ◽  
Yanhua Zhu ◽  
Pingli Liu ◽  
Jian Zhang ◽  
Yigang Liu
Keyword(s):  
Corrosion Inhibitor ◽  
Corrosion Behavior ◽  
Theoretical Basis ◽  
Inhibition Mechanism ◽  
Corrosion Mechanism ◽  
Protective Film ◽  
Content Type ◽  
N80 Steel ◽  
Weight Loss Method ◽  
Hcl Solution

Purpose This paper aims to describe the corrosion behavior and possibility of inhibition by corrosion inhibitor SA1-3 in acidizing solution (5 per cent hydrochloric acid [HCl] solution). The study aims to explain the mechanism of corrosion and inhibition of N80 steel in 5 per cent HCl solution to provide theoretical basis for expanding the range of application of N80 steel in acidification process. Design/methodology/approach This paper opted for a laboratory study using simulation of acidizing solution to do the experiments. The results of experiments including weight-loss method, electrochemical method and surface analysis were used to explain the mechanism of corrosion and inhibition so as to predict the dissolution progress of N80 steel in 5 per cent HCl solution with and without inhibitor SA1-3. Findings This paper provides theoretical insights about how to inhibit the corrosion behavior of N80 steel in 5 per cent HCl solution. It suggests that the corrosion inhibitor which can form a protective film on the steel surface should be used to expand the application of N80 steel in acidizing solution. The inhibitor SA1-3 is a kind of cathodic corrosion-controlling inhibitor which mainly inhibits cathode corrosion; it cannot change the corrosion mechanism of N80 steel. Originality/value This paper provides a theoretical basis for the corrosion behavior and inhibition mechanism of N80 steel in acidizing solution.

Investigation of diffusion alloying time on electrochemical behavior and conductivity of Nb-modified AISI 430 SS as PEMFC bipolar plate

2019 ◽  
Vol 66 (4) ◽  
pp. 520-526
Author(s):  
Fupeng Cheng ◽  
Jinglong Cui ◽  
Shuai Xu ◽  
Hongyu Wang ◽  
Pengchao Zhang ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Stainless Steel ◽  
Corrosion Resistance ◽  
Electrochemical Behavior ◽  
Surface Conductivity ◽  
Proton Exchange ◽  
Corrosion Mechanism ◽  
Content Type ◽  
Surface Electrical Conductivity ◽  
Aisi 430

Purpose The purpose of this paper is to improve the surface electrical conductivity and corrosion resistance of AISI 430 stainless steel (430 SS) as bipolar plates for proton exchange membrane fuel cells (PEMFCs), a protective Nb-modified layer is formed onto stainless steel via the plasma surface diffusion alloying method. The effect of diffusion alloying time on electrochemical behavior and surface conductivity is evaluated. Design/methodology/approach In this work, the surface electrical conductivity and corrosion resistance of modified specimen are evaluated by the potentiodynamic and potentionstatic polarization tests. Moreover, the hydrophobicity is also investigated by contact angle measurement. Findings The Nb-modified 430 SS treated by 1.5 h (1.5Nb) presented a lower passivation current density, lower interfacial contact resistance and a higher hydrophobicity than other modified specimens. Moreover, the 1.5 Nb specimen presents a smoother surface than other modified specimens after potentionstatic polarization tests. Originality/value The effect of diffusion alloying time on electrochemical behavior, surface conductivity and hydrophobicity of modified specimen is evaluated. The probable anti-corrosion mechanism of Nb-modified specimen in simulated acid PEMFC cathode environment is presented.

3-Thiophenemalonic acid as corrosion inhibitor of copper

2017 ◽  
Vol 64 (1) ◽  
pp. 52-60 ◽  
Author(s):  
A.B. Medrano-Solís ◽  
U. León-Silva ◽  
Maria Elena Nicho
Keyword(s):  
Sulfuric Acid ◽  
Sodium Chloride ◽  
Corrosion Inhibitor ◽  
Diffusion Processes ◽  
Copper Surface ◽  
Corrosion Mechanism ◽  
Cooling Systems ◽  
Content Type ◽  
Mixed Control ◽  
And Diffusion

Purpose The purpose of this study was to examine the copper protection against corrosion using 3-thiophenemalonic acid (3TMA). Design/methodology/approach The heterocyclic organic molecule was tested experimentally as a corrosion inhibitor of copper in two different concentrations (0.01 M and 0.001 M) in 0.5 M solutions of sodium chloride and sulfuric acid by AC electrochemical and DC techniques. Findings Results showed that the organic compound was adsorbed chemically on the copper surface, and the inhibitions mechanism was both anodic and cathodic. The corrosion mechanism was under mixed control: charge transfer from metal to the environment through the double electrochemical layer, and diffusion processes. Practical implications This inhibitor could have application in water cooling systems. Originality/value The results of this paper showed that 3TMA could be used for reducing corrosion rates of copper in solutions of sodium chloride and sulfuric acid.

Densification behavior of 316L-NiB stainless steel powder and surface morphology during selective laser melting process using pulsed Nd:YAG laser

2019 ◽  
Vol 25 (1) ◽  
pp. 47-54 ◽  
Author(s):  
Jelena Stašić ◽  
Dušan Božić
Keyword(s):  
Stainless Steel ◽  
Layer Thickness ◽  
Selective Laser Melting ◽  
Laser Power ◽  
Average Power ◽  
Favorable Effect ◽  
Powder Layer ◽  
Laser Melting ◽  
Content Type ◽  
Hcl Solution

Purpose This paper aims to report the production of 316L-1 Wt.% NiB cubes by using the selective laser melting (SLM) process. The laser used was pulsed, millisecond Nd:YAG system with maximum average power 100 W. Design/methodology/approach Densification under different processing conditions (pulse energy, average laser power, laser scan speed, powder layer thickness, pulse frequency) was investigated. Morphology, macro and microstructure of laser melted samples were characterized by digital camera images and by scanning electron microscope. Density of the cubes was determined by Archimedes method in water. Vickers microhardness of samples was determined under the load of 25 g. Corrosion behavior of 316L and 316L-NiB samples was conducted in 5 per cent HCl solution at the testing temperature of 20°C during 240 h. Findings Using laser power of ∼60-70 W, lower beam overlap and powder layer thickness of 200 µm, 3D cubical samples were obtained with significant balling in individual layers and an overall porosity being around 30 per cent. By increasing laser power to ∼80 W, with higher beam overlap and lower powder layer thickness of 100 µm, SLM parts with no balling and the presence of small pores of up to 4 per cent (20 Hz) and 9 per cent (40 Hz) were obtained. With further increase of laser power to 90 W, overall porosity rose to around 12 per cent. The addition of 1 Wt.% NiB to stainless steel negligibly lowered its corrosion resistance in 5 per cent HCl solution. Originality/value A part from 316L stainless steel with balling-free structure and good density was successfully obtained through pulsed-SLM process with the aid of 1 Wt.% of NiB addition. Aside from significant influence on the improved structure of cubes, NiB had a favorable effect on microhardness values while practically not affecting the corrosion resistivity of the base material in an aggressive surrounding.

A Mannich base 1-phenyl-3-(1-pyrrolidinyl)-1-propanone: synthesis and performance study on corrosion inhibition for N80 steel in 15% hydrochloric acid

2016 ◽  
Vol 63 (2) ◽  
pp. 153-159 ◽  
Author(s):  
Yuan Pan ◽  
Fengtao Zhan ◽  
Zhifeng Lu ◽  
Yan Lin ◽  
Zhen Yang ◽  
...  
Keyword(s):  
Hydrochloric Acid ◽  
Corrosion Inhibitor ◽  
Corrosion Inhibition ◽  
Mannich Base ◽  
Oil Well ◽  
Performance Study ◽  
Content Type ◽  
N80 Steel ◽  
Study Results ◽  
Inhibition Performance

Purpose – The purpose of this paper is to set out a study of a Mannich base, which was synthesized and used as an acidizing corrosion inhibitor first, and to the corrosion inhibitor mechanism. Design/methodology/approach – A Mannich base, 1-phenyl-3-(1-pyrrolidinyl)-propanone (PHPP), was synthesized with acetophenone, pyrrolidine and formaldehyde at pH = approximately 2-3. The structure of PHPP was characterized by elemental analysis and Fourier transform infrared spectroscopy (FTIR). The corrosion inhibition of PHPP on N80 steel in 15 per cent hydrochloric acid (HCl) was studied by weight loss method, scanning electron microscope (SEM) and energy dispersive X-ray analysis (EDAX), and the adsorption behavior of PHPP on the surface of N80 steel was discussed. Findings – The results showed that the inhibition efficiency reached to 99.8 per cent and corrosion rate was 2.65 g·m-2·h-1 at 0.6 per cent of PHPP concentration in 15 per cent HCl, which indicated that PHPP presented excellent corrosion inhibition performance. The results of SEM and EDAX analysis showed that PHPP could be absorbed on the surface of N80 steel. The adsorption process of PHPP on the surface of N80 steel was chemisorption. This process was spontaneous and obeyed Langmuir adsorption isotherm. Originality/value – It was found that PHPP presented excellent corrosion inhibition performance, and it is practicable to enhance oil production in oilfield development as a oil-well acidizing inhibitor. The study results can provide theoretical guidelines for the development of the inhibitor.

Date palm (Phoenix dactylifera) leaf extract as an eco-friendly corrosion inhibitor for carbon steel in 1M hydrochloric acid solution

2015 ◽  
Vol 62 (1) ◽  
pp. 19-28 ◽  
Author(s):  
S.A. Umoren ◽  
Z.M. Gasem ◽  
I.B. Obot
Keyword(s):  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Corrosion Inhibitor ◽  
Leaf Extract ◽  
Date Palm ◽  
Inhibition Efficiency ◽  
Phoenix Dactylifera ◽  
Content Type ◽  
Hcl Solution ◽  
Palm Leaf

Purpose – The purpose of the paper was to investigate the use of aqueous extract of date palm (Phoenix dactylifera) leaf as a green inhibitor for corrosion of carbon steel in 1M hydrochloric acid (HCl) solution. Design/methodology/approach – Extracts from the date palm were used as the main component of an environmentally friendly corrosion inhibitor for use in HCl pickling processes. Inhibition behavior on carbon steel in HCl was investigated using weight loss measurements, linear and potentiodynamic polarization curves, electrochemical impedance spectroscopy and scanning electron microscopy. Findings – The results show that the extract exhibited good inhibition performance in 1M HCl. The inhibition efficiency increased with increase in the concentration of the inhibitor but decreased with increase in temperature. Inhibition efficiency also was found to increase as immersion time increased. The inhibitive action was due to adsorption of the date palm leaf components on the steel, which was consistent with the Langmuir isotherm. Practical implications – Date palm leaf extract (DPLE) is an effective inhibitor at room temperature and can be used to protect plain carbon steel from corrosion in HCl solution. Originality/value – This study provides new information on the inhibiting characteristics of DPLE under specified conditions. The environmentally friendly inhibitor could find possible applications in metal surface anodizing and acid pickling processes.

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