Techno-Economic Analysis of Fast Pyrolysis of Date Palm Waste for Adoption in Saudi Arabia

Date palm trees, being an important source of nutrition, are grown at a large scale in Saudi Arabia. The biomass waste of date palm, discarded of in a non-environmentally-friendly manner at present, can be used for biofuel generation through the fast pyrolysis technique. This technique is considered viable for thermochemical conversion of solid biomass into biofuels in terms of the initial investment, production cost, and operational cost, as well as power consumption and thermal application cost. In this study, a techno-economic analysis has been performed to assess the feasibility of converting date palm waste into bio-oil, char, and burnable gases by defining the optimum reactor design and thermal profile. Previous studies concluded that at an optimum temperature of 525 °C, the maximum bio-oil, char and gases obtained from pyrolysis of date palm waste contributed 38.8, 37.2 and 24% of the used feed stock material (on weight basis), respectively, while fluidized bed reactor exhibited high suitability for fast pyrolysis. Based on the pyrolysis product percentage, the economic analysis estimated the net saving of USD 556.8 per ton of the date palm waste processed in the pyrolysis unit. It was further estimated that Saudi Arabia could earn USD 44.77 million per annum, approximately, if 50% of the total date palm waste were processed through fast pyrolysis, with a payback time of 2.57 years. Besides that, this intervention will reduce 2029 tons of greenhouse gas emissions annually, contributing towards a lower carbon footprint.

The Integral Utilization of Date Palm Waste to Produce Plastic Composites

In this work, date palm waste (DPW) stemming from the annual pruning of date palm was used as a reinforcing filler in polypropylene matrix at 20–60 wt.%. Only a grinding process of the DPW has been performed to ensure no residue generation and full utilization. The present work investigates how the DPW use affects mechanical properties and water absorption of the ensuing composite. The effect of the addition of maleated polypropylene (MAPP) as a coupling agent on the composite properties was also studied. It was shown that the reinforcing potential of DPW was strongly dependent on aspect ratio and interface quality. The MAPP addition resulted in a composite with higher strength and stiffness than the neat PP, meaning that DPW behaves as reinforcement. The difference in the reinforcing effect was explained by the change in the quality of the interface between date palm waste and the polypropylene polymeric chain.

Valorization of Date Palm Waste for Plastic Reinforcement: Macro and Micromechanics of Flexural Strength

Date palm waste is an abundant agricultural residue in Tunisia and can be used for plastic reinforcement. Moreover, its use in plastic composites can help to reduce dependence on fossil resources for material production. In this work, the valorization of date palm residues was studied by employing high-yield processes following mechanical, chemical, and enzymatical treatments. Fibers obtained by soft chemical treatment with sodium hydroxide and enzymatic treatment with xylanases and pectinases were evaluated for their use in the reinforcement of plastic materials. The flexural strength property, truly relevant for structural, construction, automotive, or other market sectors, was adopted to assess the reinforcing potential of the fibers. Polypropylene was effectively reinforced with date palm fibers (60 wt.%), exhibiting a flexural strength increases of 80% (73.1 MPa), 93% (78.5 MPa), and 106% (83.9 MPa) for mechanical, chemical, and enzymatic fibers, respectively. The different treatments had an impact on the chemical composition of the fibers, and by extension on the final properties of the composites. The holocellulose content could provide good interfacial adhesion using a coupling agent, whereas the lignin content improved the dispersion of the phases. Two interesting outcomes were that the flexural performance of enzymatic fibers was like that of wood composites, whereas the specific flexural strength was comparable to that of glass fiber composites. Overall, the present work has shown the potential behind date palm waste in the composite sector when a specific property or application is desired. Novel treatments have been used for greater fiber compatibility, increasing the sustainability of the process, and improving the applicability of the palm residue.

Application of pyrolysis acid from date palm waste as wood preservative

Matched sets of clear specimens of poplar and pine wood were treated with 3, 5, and 8% (v/v) aqueous solutions of slow pyrolysis acid (PA) derived from date palm waste, to evaluate the effectiveness of PA in controlling mold growth on species of wood. Chemical compounds available in PA were identified by gas chromatography-mass spectrometry analysis. Treated and control specimens were contaminated with Aspergillus sp., then incubated in accordance to AWPA E24 (2017). Percentages of occupied surface by mold on each of control and treated specimen with respect to its total surface were evaluated by Image-J software. Comparisons of mean values of these determined ratios and physical examinations showed that, depending on species, the 5 and 8% water solutions of PA prohibited Aspergillus growth on tested woods. Experiments were also conducted on a matched set of small clear specimens of beech wood, impregnated by 3, 5, and 8% water solutions (v/v) of PA, using full-cell process and contaminated with decay fungus (Trametes versicolor), then incubated. Specifications of the EN 113 (1996) standard were followed. Weight loss was applied for comparing control and treated specimens. Average values of weight losses indicated that the 5% solution was effective, but 8% solution presented a better result.