Changes in the chemistry of soil solution and acetic-acid extractable P following different types of freeze/thaw episodes

1994 ◽  
Vol 45 (3) ◽  
pp. 353-359 ◽  
Author(s):  
M.D. RON VAZ ◽  
A.C. EDWARDS ◽  
C.A. SHAND ◽  
M.S. CRESSER
Author(s):  
Y. N. Hua ◽  
G. B. Ang ◽  
S. Redkar ◽  
Yogaspari ◽  
Wilma Richter

Abstract In failure analysis of wafer fabrication, currently, three different types of chemical methods including 6:6:1 (Acetic Acid/HNO3/HF), NaOH and Choline are used in removing polysilicon (poly) layer and exposing the gate/tunnel oxide underneath. However, usage is limited due to their disadvantages. For example, 6:6:1 is a relatively fast etchant, but it is difficult to control the etch time and keep the oxide layer intact. Also, while using NaOH to remove poly and expose the silicon oxide, the solution needs to be heated. It is also difficult to etch a poly layer with a WSix or a CoSix silicide using NaOH. In this paper, we will discuss these 3 etchants in terms of their advantages and disadvantages. We will then introduce a new poly etchant, called HB91. HB91 is useful for removing poly to expose the gate/tunnel oxide for identification of related defects. HB91 is actually a mixture of two chemicals namely nitric acid (HNO3) and buffer oxide etchant (BOE) in a 9:1 ratio. The experimental results show that it is highly selective in poly removal with respect to the gate/tunnel oxide and is a suitable poly etchant especially for removing polysilicon with/without WSix and CoSix in the large capacitor structure. Application results of this poly etchant (HB91) will be presented.


2019 ◽  
Vol 9 (20) ◽  
pp. 4350 ◽  
Author(s):  
Minh Hieu Ho ◽  
Thien Bui-Thuan Do ◽  
Nhi Ngoc-Thao Dang ◽  
An Nguyen-My Le ◽  
Hanh Thi-Kieu Ta ◽  
...  

Green electrospinning has attracted great interest since non-toxic solvents were shown to be applicable in the fabrication of fibrous materials while ensuring health safety and environmental protection. Less harmful reagents such as acetone (AC) and acetic acid (AA) have been employed in this field in recent years. However, research in this area is still rare, yielding only preliminary results. In this study, two different types of solvents (pure AC and an AA/AC mixture) were used to fabricate electrospun polycaprolactone (PCL) membranes. Sample morphology, wettability, tensile strength, and chemical composition were compared between two types of membranes. Cell–scaffold interaction was also examined by cell adhesion and proliferation assays. The results demonstrate that the two types of solvents had significant effects on membrane morphology, physical strength, and cell adherence behaviors, which should be considered for different application purposes.


Author(s):  
Aref Shafiei Dastgerdi ◽  
Kyle Riding ◽  
Robert J. Peterman ◽  
B. Terry Beck

As an important element in track, pre-stressed concrete railroad ties in the high-speed rail industry must meet the safety and performance specifications of high-speed trains. Systematic destructive and non-destructive evaluation of existing concrete ties can lead to a better understanding of the effect of prestressed concrete tie material design on performance and failure within their service life. It has been evident that environmental and climate conditions also have a significant impact on concrete railroad ties, causing various forms of deterioration such as abrasion and freeze-thaw damage. Understanding of the material characteristics that cause failure in different types of existing concrete railroad ties taken from different places is the main focus of this paper. Observing the current status and damages of railroad ties taken from track might give a correlation between the material characteristic and type of distress and cracking seen. Although it has been seen by previous works that effective factors such as air void system and material composition directly affect the performance of concrete ties such as freeze-thaw, material evaluation of existing ties after service life has not been addressed in previous publications. In this research, the authors have investigated the material characteristic such as aggregate and air-void system of existing pre-stressed concrete railroad ties taken from track. However, compressive and splitting tensile strength and fractured surface of samples cored from the ties were acquired. In order to obtain the strength of concrete materials of existing ties, six samples were cored from six different types of ties taken from tracks across the U.S., according to ASTM C42-16, and tested using ASTM C39 and ASTM C496 methods. However, the concrete air-void system (ASTM C457) was measured on saw-cut samples extracted from the ties to evaluate the influence air content and distribution on mechanical properties of the ties. Regarding the history and service life condition of the ties, it seems that material properties of the ties effectively alter the performance of the ties. Aggregate sources used at each location may have different properties such as texture, angularity, and mineralogy, contributing either propagation or resistance in splitting cracking in concrete. Furthermore, the polished surface of samples extracted from the ties show the uniformity and air void system in some ties which demonstrate their superiority in terms of resistance to freeze-thaw damage. Considering the results of this research, comprehensive evaluation of material characteristics might give a better view of existing concrete railroad ties situation, providing a worthwhile background for future tie design considerations.


2014 ◽  
Vol 1033-1034 ◽  
pp. 81-84
Author(s):  
He Ping Yan ◽  
Du Shu Huang ◽  
Ju Cheng Zhang ◽  
Rui Na Huang ◽  
You Wang Fu ◽  
...  

Three chalcone derivatives were synthesized by the reaction of acetophenone with dimethylamino benzaldehyde, vanillin, diphenyl formaldehyde, respectively. The results showed that: A yield of 80.4% was obtained by the reaction of acetophenone and dimethylamino benzaldehyde in ethanol as solvent, 10% NaOH solution as catalyst at room temperature. A yield of 25.0% was obtained by the reaction of acetophenone and vanillin in ethanol as solvent, a mixed glacial acetic acid and hydrochloric acid as the catalyst, adding 10% KOH solution for dehydration by heating after the reaction at room temperature. A yield of 76.3% was obtained by the reaction of acetophenone and diphenyl formaldehyde in ethanol as solvent, 10% NaOH solution as catalyst at room temperature. Acid was used as the appropriate catalyst when chalcone derivatives were synthesized by aldehyde with hydroxy.


2014 ◽  
Vol 1025-1026 ◽  
pp. 633-636 ◽  
Author(s):  
Michaela Kostelecká ◽  
Jiří Kolísko

The paper describes the series of tests of fiber – cement plates. The first part is focused on determining the values of tensile bending strength for plates subjected to freeze – thaw cycle. The second part is focused of the influence of putting the plates into hot water on bending strength. The third part is described the procedure of monitoring the saturation – desiccation on bending strength.


2021 ◽  
Vol IV (2) ◽  
pp. 128-138
Author(s):  
Alina Boistean ◽  

Vinegar is one of the oldest fermented products in the world and its production dates back to around 2000 BC. It is a liquid fermentation product that consists from 4% to 9% acetic acid, which is commonly used and consumed globally, either directly or as a condiment in food. It is produced by two-stage fermentation systems, i.e., the alcoholic fermentation of sugary substrates and subsequently, the acetous fermentation (oxidation) of the ethanol into acetic acid. There are numerous different types of vinegars produced worldwide based on the raw material and the production method used. Among all the vinegars available, the most common types of vinegar, produced in different parts of the world, and including some top-quality famous products, are “cider vinegar,” “balsamic vinegar,” “wine vinegar,” “rice vinegar,” and “malt vinegar.” Tropical fruit vinegars and vinegars made from any kind of agricultural surpluses are also available. The different raw materials and the methods used for the production of the different types of vinegars lead to a variety of products with distinctive characteristics. In this paper, definitions, local market and legislation and current trends in vinegar production are briefly highlighted and discussed.


2013 ◽  
Vol 70 (2) ◽  
pp. 264-269
Author(s):  
I.V. Kosakivska ◽  
◽  
L.V. Voytenko ◽  
R.V. Lichnevskiy ◽  
A.Yu. Ustinova ◽  
...  

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