Nanoscience and Nanotechnology in Solar Cells

2013 ◽  
Vol 136 (1) ◽  
Author(s):  
Kaufui V. Wong ◽  
Nicholas Perilla ◽  
Andrew Paddon

Energy is a big challenge in the coming years. The global population is increasing. Not only are there more people in the world, but the human drive to increase living standards have increased individual energy demands. Growing energy needs were typically met by finding new sources of fossil fuels. People have fortunately begun to realize the adverse environmental impact of burning fossil fuels and that this practice cannot be maintained indefinitely, leading to renewed interest in photovoltaic technologies. The discovery of the photoelectric effect brought hope to the objective of helping to fill the world energy needs with an already continuously delivered source. The discovery of the photoelectric effect was the birth of the idea, but it was the development of the crystalline silicon cell that marked the beginning of the industry. The cost and inefficiency of these solar panels have prevented them from becoming an economically competitive form of everyday power generation. Cost was reduced with the introduction of amorphous silicon thin-film cells despite slightly lower efficiencies. Their lower manufacturing costs have allowed solar energy to be included in more applications; the costs have not been reduced enough to compete with current grid rates. The current trend in research suggests that the application of nanotechnology may be the awaited break needed to break this cost barrier. Nanotechnology promises to reduce cost because they require less controlled conditions, which will greatly reduce the cost per cell, and the initial cost of a new cell type. Nanoscience and nanotechnology are being researched and developed to help solve problems that have prevented the use of other promising technologies, and improving efficiencies of those technologies that have been developed. The addition of nanoparticles to the matrix is a possible way to improve electron transport, and nanotubes could be used in conjunction with nanoparticles. The science of interactions and addition of nanoparticles and their function in solar photovoltaic cells is known, but still developing. Nanoscience has produced proof-of-concept photovoltaic cells made of small perfect crystals, rather than large, perfect silicon crystals that are more expensive to produce. Nanowhiskers are being experimented as new antireflective coating. Sensitizing dyes are being used to increase the range and location of the wavelengths that can be absorbed to be more favorable to sunlight, allowing the use of materials that lack this key characteristic. Quantum dots could be an improvement to these dyes, as the smaller particles will have the added benefit of having multiple electrons created per photon without impeding electron transfer. Recent research has also shown a method to transform optical radiation into electrical current that could lead to self-powering molecular circuits and efficient data storage. The many possible applications of nanotechnology make photovoltaic cells a promising pursuit.

Author(s):  
Kaufui V. Wong ◽  
Nicholas Perilla ◽  
Andrew Paddon

Energy is a big challenge in the coming decades. The global population is increasing steadily. Not only are there more people in the world, but the worldwide drive to increase living standards have increased individual energy demands. Growing energy needs were typically met by finding new sources of fossil fuels. People have fortunately begun to realize the adverse environmental impact of burning fossil fuels and that this practice cannot be maintained indefinitely, leading to renewed interest in photovoltaic technologies. The discovery of the photoelectric effect brought hope to the objective of helping to fill the world energy needs with an already continuously delivered source. The discovery of the photoelectric effect was the birth of the idea, but it was the development of the crystalline silicon cell that marked the birth of the industry. The cost and inefficiency of these solar panels have prevented them from becoming an economically competitive form of everyday power generation. Cost was reduced with the introduction of amorphous silicon thin-film cells despite slightly lower efficiencies. Their lower manufacturing costs have allowed solar energy to be included in more applications; the costs have not been reduced enough to compete with current grid rates. The current trend in research suggests that the application of nanotechnology may be the awaited break needed to crack this cost barrier. Nanotechnology promises to reduce cost because they require less controlled conditions, which will greatly reduce the cost per cell, and the initial cost of a new cell type. Nanoscience and nanotechnology are being researched and developed to help solve problems that have prevented the use of other promising technologies, and improving efficiencies of those technologies that have been developed. The addition of nanoparticles to the matrix is a possible way to improve electron transport, and nanotubes could be used in conjunction with nanoparticles. The science of interactions and addition of nanoparticles and their function in solar photovoltaic cells is known, but still developing. Nanoscience has produced proof-of-concept photovoltaic cells made of small perfect crystals, rather than large, perfect silicon crystals that are more expensive to produce. However, the step-up to larger scale, practical photovoltaic cells have not been reproduced efficiently and at a reasonable cost for small, perfect crystals not made of silicon. Nano-whiskers are being experimented as new antireflective coating. Sensitizing dyes are being used to increase the range and location of the wavelengths that can be absorbed to be more favorable to sunlight, allowing the use of materials that lack this key characteristic. Quantum dots could be an improvement to these dyes, as the smaller particles will have the added benefit of having multiple electrons created per photon without impeding electron transfer. Recent research has also shown a method to transform optical radiation into electrical current that could lead to self-powering molecular circuits and efficient data storage. The many possible applications of nanotechnology make photovoltaic cells as promising pursuit.


2020 ◽  
Vol 53 (3-4) ◽  
pp. 742-747
Author(s):  
Abdur Rashid Sangi ◽  
Abdul Qayoom ◽  
Abdul Qadir ◽  
Ahmed N Abdalla ◽  
Rehan Ali

Solar energy exploitation through photovoltaic technology has demonstrated a sustainable way for curbing energy needs and cutting environmental issues happening due to emissions of carbon dioxide, CO2 from the usage of non-renewable energy resources. The purpose of this study was to reduce metallization by choosing optimal metallization on silicon photovoltaic wafer. Using numerical study, the effects of the number of busbars, fingers, and soldering/probe points were analyzed and also the study of the size of busbar and finger was carried out to find the optimal value for each which assures better performance. It is revealed that increasing the number and size of busbars, fingers, and probe points result in increasing fill factor, however, the efficiency of the device is limited to a number which provides the best optimal performance in terms of efficiency, whereas increasing the size (width) of the parameter result in a decrease in efficiency increasing shading factor. The optimal value of prescribed parameters was recorded as 4, 82, and 20 numbers of busbars, fingers, and probe points, respectively, while an optimal value of the width of busbar and finger is found as 0.5 mm and 60 µm, respectively. These values attained efficiency and fill factor above 20% and 80%, respectively. This study finds a realistic method to further diminish the metallization, improve the performance, and reduce the cost of often used industrial silicon photovoltaic cells.


Author(s):  
Zina Arabeche ◽  
Mohammed El Amine Abdelli

Since the emergence of the industrial revolution, the use of energy resources has increased considerably, particularly non renewable (coal, oil and gas), so these resources are no longer sufficient to cover the different energy needs, and this has become a challenge to the energy independance of many gouvernment now and in the future. This has caused the world to scramble for other ways to satisfy these needs in which the results of scientific research and development envolved from alternative uses of old energy sources and named green economy, and many think about the future of energy despite the barriers that still hinder the general application of this type of economy. Energy consumption in Algeria is focused almost entirely on fossil fuels, hydrocarbons, and gas in particular. In recent years, Algeria is deciding to move intro the green economy, the unique solution for meeting future energy requirements and helping reduce environmental risks.


Energy ◽  
2012 ◽  
Author(s):  
José Goldemberg

What are the fossil fuels? Fossil fuels—coal, petroleum, natural gas, and their by-products— account for approximately 85% of the world′s primary energy needs today. Use of these fuels drives industrialized economies and has become an integral part of every aspect of productive activity and...


2021 ◽  
Author(s):  
Manoj Kumar Singh ◽  
Pratik V. Shinde ◽  
Pratap Singh ◽  
Pawan Kumar Tyagi

Inorganic crystalline silicon solar cells account for more than 90% of the market despite a recent surge in research efforts to develop new architectures and materials such as organics and perovskites. The reason why most commercial solar cells are using crystalline silicon as the absorber layer include long-term stability, the abundance of silicone, relatively low manufacturing costs, ability for doping by other elements, and native oxide passivation layer. However, the indirect band gap nature of crystalline silicon makes it a poor light emitter, limiting its solar conversion efficiency. For instance, compared to the extraordinary high light absorption coefficient of perovskites, silicon requires 1000 times more material to absorb the same amount of sunlight. In order to reduce the cost per watt and improve watt per gram utilization of future generations of solar cells, reducing the active absorber thickness is a key design requirement. This is where novel two-dimensional (2d) materials like graphene, MoS2 come into play because they could lead to thinner, lightweight and flexible solar cells. In this chapter, we aim to follow up on the most important and novel developments that have been recently reported on solar cells. Section-2 is devoted to the properties, synthesis techniques of different 2d materials like graphene, TMDs, and perovskites. In the next section-3, various types of photovoltaic cells, 2d Schottky, 2d homojunction, and 2d heterojunction have been described. Systematic development to enhance the PCE with recent techniques has been discussed in section-4. Also, 2d Ruddlesden-Popper perovskite explained briefly. New developments in the field of the solar cell via upconversion and downconversion processes are illustrated and described in section-5. The next section is dedicated to the recent developments and challenges in the fabrication of 2d photovoltaic cells, additionally with various applications. Finally, we will also address future directions yet to be explored for enhancing the performance of solar cells.


Processes ◽  
2021 ◽  
Vol 9 (10) ◽  
pp. 1745
Author(s):  
Svetlana Zueva ◽  
Francesco Ferella ◽  
Valentina Corradini ◽  
Elena V. Baturina ◽  
Nicolò M. Ippolito ◽  
...  

The circular economy and maximization of environmental sustainability are increasingly becoming the vision and mission of companies competing in present-day global markets. In particular, in the energy sector, the transition from fossil fuels to renewable sources of energy has become the widespread mantra. One typical example is the deployment of devices which produce clean energy, such as solar photovoltaic panels and solar thermal panels, wind generators, tidal stream generators, wave power generators, etc. These are undoubtedly generating clean energy, but their manufacture creates hazardous by-products, the disposal of which results in increased environmental pollution. Chemical Vapor Deposition (CVD) is widely used in manufacturing of solar photovoltaic cells. In these processes, typically, crystalline silicon is precipitated from chlorosilanes, iodides, bromides and fluorides. Polluting by-products include deposition of a silicon film, formation of SiO2 powder and formation of toxic vapors of HF, SiH4 and PH3. Usually, these gaseous products are eliminated in a central scrubber, whose unwanted by-product consists in large quantities of hazardous fluorine-containing sludge. This article concerns an effective and inexpensive detoxification of fluorinated sludge, developed by the authors during research into the sludge collected from the scrubber of a PV cell manufacturing plant located in southern Italy.


2018 ◽  
Vol 3 (10) ◽  
pp. 66-69
Author(s):  
Chikwendu Ubani ◽  
Ubong Ikpaisong

Natural gas is a clean-burning, safe fuel that can save you money at the pump while benefitting the environment and reducing Nigeria’s dependence on petroleum. It is a naturally occurring mixture of gaseous hydrocarbon, non-gaseous non-hydrocarbons and gaseous non-hydrocarbons found in underground reservoir rocks either on its own (non-associated gas) or in association with crude oil (associated gas). Natural gas is today accepted as one of the best sources of energy for the world and for the future because of its environmentally-friendly nature compared to other kinds of fossil fuels. Nigeria is ranked as the seventh most natural gas endowed nation in the world and relaxes on number one spot in Africa as she seats on about one hundred and eighty-eight trillion cubic feet of natural gas deposits.Current opportunities to utilize gas in Nigeria include: Gas to reinjection schemes, Gas to power schemes, Gas to petrochemicals (as feedstock), LNG-Liquefied Natural Gas, LPG- Liquefied Petroleum Gas, and CNG- Compressed Natural Gas. The use of CNG as auto fuel in Nigeria presents so much benefits as have been highlighted in this paper with emphasis on the economic advantage. Compressed Natural Gas (CNG) is a product of compressing natural gas to one hundredth the volume it occupies at standard atmospheric pressure.A comprehensive economic analysis to determine the cost savings from driving a car on CNG against PMS considered the case of a motorist who covers an average of 100 km every day in the approximately thirty days that make a month was employed. Results established that running a car on CNG amounts to saving N1 143 daily and N34 284 monthly, the cost of converting the car from PMS - driven to CNG - driven is recovered before the end of the sixth month. From the sixth month to the end of the first year, savings of N211 402 is made. Savings of N411 408 is enjoyed each year after the first year.Running vehicles on CNG will greatly reduce the friction and troubles encountered in importing fuel into the country. This will also cut down largely the hardly available foreign exchange expended in bringing in PMS for fuelling vehicles. To this end, the Nigerian Government should as a matter of national development ensure legal and regulatory framework encompassing both technical and commercial aspects for natural gas utilization in Nigeria. Worthy of note is the aspect of gas gathering, gas transmission and distribution which will further encourage the planting of CNG refuelling stations that will serve the expected large fleet of natural gas vehicles. Currently, Green Gas Limited, a joint venture between Nigeria Gas Company (NGC) a Nigerian National Petroleum Corporation (NNPC) and NIPCO Plc. that has nine operational CNG refuelling stations and others under construction is the only company driving the CNG revolution in the country.


Author(s):  
H. Saadaoui ◽  
A. Ghennioui ◽  
B. Ikken ◽  
H. Rhinane ◽  
M. Maanan

<p><strong>Abstract.</strong> Renewable energy sources are at the forefront of political discussions around the world because of the scarcity of fossil fuels and climate change caused by the accumulation of greenhouse gases. By 2030, Morocco will cover 52% of these energy needs through renewable energies, in order to preserve the environment (COP 22). This paper aims to estimate the potential of photovoltaic solar energy from flat roofs in the city of Ben Guerir, Morocco using remote sensing and GIS data. To achieve this goal, vector orthophoto resulting from the photogrammetric restitution acquired in 2015 were used to generate a 3D model (DSM). The annual solar irradiation is calculated by the analyser of the solar tool. Each roof is calculated based on algorithms for the most common solar panel technologies (mono-si and poly-si). The applicability of this methodology has been demonstrated in the urban area of Benguerir, Morocco, and can be widespread in any other region of the world. The results obtained for a total roofing surface of 135&amp;thinsp;Ha, i.e. more than 345&amp;thinsp;Gwh of electricity annually generate. For an average roof of 60&amp;thinsp;m<sup>2</sup> that could supply 5 to 6 households; A planned investment between 118,218 and 167,296&amp;thinsp;DH, and an annual maintenance charge of 2%. This study may be an initial assessment of solar potential in the city, which can be used to support the management decision regarding investment in the urban solar system.</p>


TAPPI Journal ◽  
2012 ◽  
Vol 11 (2) ◽  
pp. 55-64 ◽  
Author(s):  
MILOUD OUADI ◽  
JOHN BRAMMER ◽  
ANDREAS HORNUNG ◽  
MARTIN KAY

There has been a growing trend towards the use of biomass as a primary energy source, which now contributes over 54% of the European pulp and paper industry energy needs [1]. The remaining part comes from natural gas, which to a large extent serves as the major source of energy for numerous recovered fiber paper mills located in regions with limited available forest resources. The cost of producing electricity to drive paper machinery and generate heat for steam is increasing as world demand for fossil fuels increases. Additionally, recovered fiber paper mills are also significant producers of fibrous sludge and reject waste material that can contain high amounts of useful energy. Currently, a majority of these waste fractions is disposed of by landspreading, incineration, or landfill. Paper mills must also pay a gate fee to process their waste streams in this way and the result of this is a further increase in operating costs. This work has developed methods to utilize the waste fractions produced at recovered fiber paper mills for the onsite production of combined heat and power (CHP) using advanced thermal conversion methods (pyrolysis and gasification) that are well suited to relatively small scales of throughput. The electrical power created would either be used onsite to power the paper making process or alternatively exported to the national grid, and the surplus heat created could also be used onsite or exported to a local customer. The focus of this paper is to give a general overview of the project progress so far and will present the experimental results of the most successful thermal conversion trials carried out by this work to date.


2012 ◽  
Vol 488-489 ◽  
pp. 175-181 ◽  
Author(s):  
Mohammadjavad Mahdavinejad ◽  
Mohammadhossein Ghasempourabadi ◽  
Hojat Ghaedi

Iran is recognized as one of the largest fossil fuels reserves resources in the world, but it is also suffer from mismanaged consumption. The consequences of this mismanagement have been considered in Iran during recent years and authorities have raised concerns about it. Identification of the optimized orientation and tilt angle for roofs in Tehran- The capital of Iran- in order to achieve the maximum daytime heat gain by photovoltaic cells and minimum energy loss at night in winter is the main purpose of this paper. So this paper makes a comparison in three shape of high-rise building in Tehran and their orientation. The results show that the appropriate direction for gaining more energy in Tehran are north-south and WE-NE direction and the cubic type of building in field of energy consumption is more economically for users


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