Contact Angle Measurement of Liquid Hydrogen (LH2) in Stainless Steel and Aluminum Cells

2016 ◽  
Vol 138 (2) ◽  
Author(s):  
Kishan Bellur ◽  
Vinaykumar Konduru ◽  
Manan Kulshrestha ◽  
Daanish Tyrewala ◽  
Ezequiel Medici ◽  
...  
Keyword(s):  
Contact Angle ◽  
Phase Change ◽  
Saturation Temperature ◽  
Neutron Cross Section ◽  
Angle Measurement ◽  
Neutron Imaging ◽  
Space Environment ◽  
Change Models ◽  
Accommodation Coefficients

One of the key limitations to long-term space missions is to avoid propellant boil-off in a microgravity space environment. Even with the use of active and passive controls of propellants, boil off is inevitable. Long-term CFD simulations on propellant behaviors depend on evaporation/condensation coefficients (known as accommodation coefficients) which are in turn dependent upon the wetting characteristics. Phase change experiments were conducted in the BT-2 neutron imaging facility at the National Institute of Standards and Technology (NIST) by introducing vapor H2 in 10 mm Al6061 and SS316L test cells placed inside the 70mm ‘orange’ cryostat. Condensation is achieved by lowering the cryostat temperature below the saturation point and vice versa for evaporation. The high neutron cross-section of liquid H2 in comparison to both the vapor and the test cell materials allows for visualization of a distinct liquid-vapor interface. Multiple images are stacked to increase the signal-to-noise ratio and the meniscus edge is obtained by detecting the pixels with largest gradients in intensities at the liquid meniscus. The contact angle is obtained by curve fitting of the Young-Laplace equation to the detected meniscus. The contact angle for Al6061 and SS316 is found to be between 0° and 4°. The uncertainty arises from edge detection, magnification, and resolution limits of the neutron imaging setup. The test was conducted at a saturation temperature of 21K (1.215 bar). The results from the neutron experiments will be then used in conjunction with FEA thermal models and kinetic phase change models to extract accommodation coefficients.

Examining Liquid Hydrogen Wettability Using Neutron Imaging

2016 ◽  
Vol 138 (8) ◽  
Author(s):  
Vinaykumar Konduru ◽  
Kishan Bellur ◽  
Ezequiel F. Médici ◽  
Jeffrey S. Allen ◽  
Chang Kyoung Choi ◽  
...  
Keyword(s):  
Contact Angle ◽  
Cone Angle ◽  
Neutron Cross Section ◽  
Liquid Hydrogen ◽  
Contact Angles ◽  
Neutron Imaging ◽  
Test Cell ◽  
Clear Understanding ◽  
Vapor Interface ◽  
Liquid Vapor

The control of propellant boil-off is essential in long-term space missions. However, a clear understanding of propellant cryogenic condensation/evaporation in microgravity is lacking. One of the key factors in designing such systems is the location of liquid surfaces and the relation to wettability. The BT-2 Neutron Imaging Facility located at the National Institute of Standards and Technology (NIST), Gaithersburg, MD, is used to image evaporation and condensation of hydrogenated propellants inside of an aluminum 6061 container. Liquid hydrogen has larger neutron cross-section area than the aluminum, allowing the visualization of the liquid-vapor interface. The test cell has a conical section that enables determination of a contact angle with enhanced accuracy. If the contact angle is equal to the angle of the cone, a flat liquid-vapor interface is expected. The test cell has the cone angle of 10o and a flat interface was not observed. Using the Laplace-Young equation to fit the interface, the contact angle for hydrogen and aluminum was between 0° and 4°. The theoretical Laplace curves with contact angles of 2o and 10o are plotted on the liquid-vapor interface. The of 2o curve is a closer fit as compared to the 10o curve. The uncertainty arises from resolution limits of the neutron imaging setup and edge detection. More details on the neutron imaging mechanism and relevant physics can be found from the authors' other publication of Cryogenics, 74, pp131-137, 2016: doi:10.1016/j.cryogenics.2015.10.016.

Long-Term Stable Metal Organic Framework (MOF) Based Mixed Matrix Membranes for Ultrafiltration

2020 ◽  
Author(s):  
Muayad Al-shaeli ◽  
Stefan J. D. Smith ◽  
Shanxue Jiang ◽  
Huanting Wang ◽  
Kaisong Zhang ◽  
...  
Keyword(s):  
Contact Angle ◽  
Water Contact Angle ◽  
Mixed Matrix Membranes ◽  
Recovery Ratio ◽  
Mixed Matrix ◽  
Water Contact ◽  
Membrane Performance ◽  
Metal Organic ◽  
Matrix Membranes

<p>In this study, novel <a>mixed matrix polyethersulfone (PES) membranes</a> were synthesized by using two different kinds of metal organic frameworks (MOFs), namely UiO-66 and UiO-66-NH<sub>2</sub>. The composite membranes were characterised by SEM, EDX, FTIR, PXRD, water contact angle, porosity, pore size, etc. Membrane performance was investigated by water permeation flux, flux recovery ratio, fouling resistance and anti-fouling performance. The stability test was also conducted for the prepared mixed matrix membranes. A higher reduction in the water contact angle was observed after adding both MOFs to the PES and sulfonated PES membranes compared to pristine PES membranes. An enhancement in membrane performance was observed by embedding the MOF into PES membrane matrix, which may be attributed to the super-hydrophilic porous structure of UiO-66-NH<sub>2</sub> nanoparticles and hydrophilic structure of UiO-66 nanoparticles that could accelerate the exchange rate between solvent and non-solvent during the phase inversion process. By adding the MOFs into PES matrix, the flux recovery ratio was increased greatly (more than 99% for most mixed matrix membranes). The mixed matrix membranes showed higher resistance to protein adsorption compared to pristine PES membranes. After immersing the membranes in water for 3 months, 6 months and 12 months, both MOFs were stable and retained their structure. This study indicates that UiO-66 and UiO-66-NH<sub>2</sub> are great candidates for designing long-term stable mixed matrix membranes with higher anti-fouling performance.</p>

scholarly journals Impact of the COVID-19 pandemic: a perspective from industry

2020 ◽  
Vol 22 (Supplement_P) ◽  
pp. P56-P59
Author(s):  
Nick E J West ◽  
Wai-Fung Cheong ◽  
Els Boone ◽  
Neil E Moat
Keyword(s):  
Care Delivery ◽  
Models Of Care ◽  
Medium Term ◽  
Change Models ◽  
New Device ◽  
Supply Chain Logistics ◽  
Cardiovascular Patients ◽  
Medical Crisis ◽  
Device Industry

Abstract The global COVID-19 pandemic has led to unprecedented change throughout society.1 As the articles in this supplement outline, all segments of the broader cardiovascular community have been forced to adapt, to change models of care delivery, and to evolve and innovate in order to deliver optimal management for cardiovascular patients. The medtech/device industry has not been exempt from such change and has been forced to navigate direct and indirect COVID-associated disruption, with effects felt from supply chain logistics to the entire product lifecycle, from the running of clinical trials to new device approvals and managing training, proctoring and congresses in an increasingly-online world. This sea-change in circumstances itself has enforced the industry, in effect, to disrupt its own processes, models and activities. Whilst some of these changes may be temporary, many will endure for some time and some will doubtless become permanent; one thing is for sure: the healthcare ecosystem, including the medical device industry, will never look quite the same again. Although the pandemic has brought a short- to medium-term medical crisis to many countries, its role as a powerful disruptor cannot be underestimated, and may indeed prove to be a force for long-term good, given the accelerated innovation and rapid adaptation that it has cultivated.

scholarly journals Superhydrophobic functionalized cellulosic paper by copper hydroxide nanorods for oils purification

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ahmed S. Belal ◽  
Jehan El Nady ◽  
Azza Shokry ◽  
Shaker Ebrahim ◽  
Moataz Soliman ◽  
...  
Keyword(s):  
Contact Angle ◽  
Filter Paper ◽  
Separation Efficiency ◽  
Contact Angle Measurement ◽  
Angle Measurement ◽  
Absorption Capacity ◽  
Morphological Properties ◽  
Copper Hydroxide ◽  
Immersion Method ◽  
Water Contact

AbstractOily water contamination has been sighted as one of the most global environmental pollution. Herein, copper hydroxide nanorods layer was constructed onto cellulosic filter paper surface cured with polydopamine, Ag nanoparticles, and Cu NPs through immersion method. This work has been aimed to produce a superhydrophobic and superoleophilic cellulosic filter paper. The structure, crystalline, and morphological properties of these modified cellulosic filter paper were investigated. Scanning electron microscope images confirmed that the modified surface was rougher compared with the pristine surface. The contact angle measurement confirmed the hydrophobic nature of these modified surfaces with a water contact angle of 169.7°. The absorption capacity was 8.2 g/g for diesel oil and the separation efficiency was higher than 99%. It was noted that the flux in the case of low viscosity solvent as n-hexane was 9663.5 Lm−2 h−1, while for the viscous oil as diesel was 1452.7 Lm−2 h−1.

scholarly journals Guideline concordance and outcome in long-term naturalistic treatment of bipolar disorder - a one-year longitudinal study using latent change models

2020 ◽  
Author(s):  
Joannes W. Renes ◽  
Dominique F. Maciejewski ◽  
Eline J. Regeer ◽  
Adriaan W. Hoogendoorn ◽  
Willem A. Nolen ◽  
...  
Keyword(s):  
Bipolar Disorder ◽  
Longitudinal Study ◽  
Change Models ◽  
One Year

Preparation and the Blood Compatibility of Titanium Oxide Nanorod Arrays

2011 ◽  
Vol 306-307 ◽  
pp. 25-30 ◽  
Author(s):  
Ping Luo ◽  
Zhan Yun Huang ◽  
Di Hu Chen
Keyword(s):  
Contact Angle ◽  
Surface Morphology ◽  
Titanium Oxide ◽  
Tin Oxide ◽  
Growth Parameters ◽  
Blood Compatibility ◽  
Contact Angle Measurement ◽  
Angle Measurement ◽  
Nanorod Arrays ◽  
Wetting Properties

In this work, titanium oxide nanorod arrays were fabricated by using the hydrothermal method on fluorine-doped tin oxide (FTO) coated glass. The diameter of the nanorods could be controlled from 150 nm to 30 nm by changing the growth parameters. The surface morphology and the structure of the samples were characterized by SEM and XRD. The wetting properties were identified by contact angle measurement. Platelet attachment was investigated to evaluate the blood compatibility of the samples with different nanoscale topographies. Results show that the nanotopographical surfaces perform outstanding blood compatibility, and the adhering platelet decreased with the increasing diameter of the nanorods.

Methods for Separation of Copper Oxide Nanoparticles From Colloidal Suspension in Dodecane

2014 ◽  
Vol 5 (1) ◽  
Author(s):  
Mohammed H. Sheikh ◽  
Muhammad A. R. Sharif
Keyword(s):  
Energy Storage ◽  
Copper Oxide ◽  
Phase Change ◽  
Phase Change Materials ◽  
Research Work ◽  
Cuo Nanoparticles ◽  
Health Hazards ◽  
Suspension Stability ◽  
Reduced Pressure

Phase change materials (PCM) are used in many energy storage applications. Energy is stored (latent heat of fusion) by melting the PCM and is released during resolidification. Dispersing highly conductive nanoparticles into the PCM enhances the effective thermal conductivity of the PCM, which in turn significantly improves the energy storage capability of the PCM. The resulting colloidal mixture with the nanoparticles in suspension is referred to as nanostructure enhanced phase change materials (NEPCM). A commonly used PCM for energy storage application is the family of paraffin (CnH2n+2). Mixing copper oxide (CuO) nanoparticles in the paraffin produces an effective and highly efficient NEPCM for energy storage. However, after long term application cycles, the efficiency of the NEPCM may deteriorate and it may need replacement with fresh supply. Disposal of the used NEPCM containing the nanoparticles is a matter of concern. Used NEPCM containing nanoparticles cannot be discarded directly into the environment because of various short term health hazards for humans and all living beings and unidentified long term environmental and health hazards due to nanoparticles. This problem will be considerable when widespread use of NEPCM will be practiced. It is thus important to develop technologies to separate the nanoparticles before the disposal of the NEPCM. The primary objective of this research work is to develop methods for the separation and reclamation of the nanoparticles from the NEPCM before its disposal. The goal is to find, design, test, and evaluate separation methods which are simple, safe, and economical. The specific NEPCM considered in this study is a colloidal mixture of dodecane (C12H26) and CuO nanoparticles (1–5% mass fraction and 5–15 nm size distribution). The nanoparticles are coated with a surfactant or stabilizing ligands for suspension stability in the mixture for a long period of time. Various methods for separating the nanoparticles from the NEPCM are explored. The identified methods include: (i) distillation under atmospheric and reduced pressure, (ii) mixing with alcohol mixture solvent, and (iii) high speed centrifugation. These different nanoparticle separation methods have been pursued and tested, and the results are analyzed and presented in this article.

Measurement of wheel-terrain contact angle for WMRs on rough terrain using laser scanning sensor

2017 ◽  
Vol 44 (6) ◽  
pp. 798-807 ◽  
Author(s):  
He Xu ◽  
Yan Xu ◽  
Peiyuan Wang ◽  
Hongpeng Yu ◽  
Ozoemena Anthony Ani ◽  
...  
Keyword(s):  
Contact Angle ◽  
Laser Scanning ◽  
Contact Angle Measurement ◽  
Angle Measurement ◽  
Rough Terrain ◽  
Wheeled Mobile Robots ◽  
Wheel Slip ◽  
Content Type ◽  
Terrain Model ◽  
Measurement Approach

Purpose The purpose of this paper is to explore a novel measurement approach for wheel-terrain contact angle using laser scanning sensors based on near-terrain perception. Laser scanning sensors have rarely been applied to the measurement of wheel-terrain contact angle for wheeled mobile robots (WMRs) in previous studies; however, it is an effective way to measure wheel-terrain contact angle directly with the advantages of simple, fast and high accuracy. Design/methodology/approach First, kinematics model for a WMR moving on rough terrain was developed, taking into consideration wheel slip and wheel-terrain contact angle. Second, the measurement principles of wheel-terrain contact angle using laser scanning sensors was presented, including “rigid wheel - rigid terrain” model and “rigid wheel - deformable terrain” model. Findings In the proposed approach, the measurement of wheel-terrain contact angle using laser scanning sensors was successfully demonstrated. The rationality of the approach was verified by experiments on rigid and sandy terrains with satisfactory results. Originality/value This paper proposes a novel, fast and effective wheel-terrain contact angle measurement approach for WMRs moving on both rigid and deformable terrains, using laser scanning sensors.

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