scholarly journals Measurements of Density and Sound Speed in Mixtures Relevant to Supercritical CO2 Cycles

2020 ◽  
Vol 142 (10) ◽  
Author(s):  
Suhyeon Park ◽  
Justin Urso ◽  
K.R.V. (Raghu) Manikantachari ◽  
Ashvin Hosangadi ◽  
Andrea Zambon ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Sound Speed ◽  
Industrial Applications ◽  
Operating Conditions ◽  
Working Fluid ◽  
Power Cycles ◽  
Frequency Detection ◽  
Temperature And Pressure ◽  
Power Generation Systems ◽  
Piezoelectric Pressure Sensor

Abstract The objective of this research is to validate properties of mixtures relevant to supercritical carbon dioxide (sCO2) power cycles. Direct-fired sCO2 cycles are a promising technology for the future power generation systems. The working fluid of sCO2 cycles will be near and above critical point of CO2. One of the challenges is that the simulation of mixtures should consider real gas behavior. Expected operating conditions of Allam cycles reach up to 300 bar and 1000 °C. Characterizing the mixtures at the extreme conditions is an important issue in current researches and industrial applications. Thermophysical properties of mixtures may be beyond the valid range of the widely used database such as NIST REFPROP. Experimental data of mixture properties in the literature are limited which is necessary to develop high-fidelity design tools for sCO2 power cycles. We measured the density and sound speed of several multi-component mixtures. A temperature-controlled high-pressure test cell was used for the density measurements. Sound speed was measured by resonant frequency detection using an external speaker and a piezoelectric pressure sensor. Mixtures studied in this work include carbon dioxide, methane, oxygen, and water vapor. Properties of pure CO2 were measured to show the validity of our technique. Compositions were selected to be close to frozen mixtures at the inlet, mid-progress, and exhaust conditions of a model sCO2 combustor in the previous numerical simulation work. Corresponding reaction progress variables (RPV) were RPV = 0, 0.5, and 1. Temperature and pressure conditions of experiments are 310–450 K and 0–150 bar. In our study, density and sound speed from the NIST REFPROP database agree with experimental measurements within the range of our measurement uncertainties.

Measurements of Density and Sound Speed in Mixtures Relevant to sCO2 Power Cycles

2020 ◽  
Author(s):  
Suhyeon Park ◽  
Justin Urso ◽  
K. R. V. (Raghu) Manikantachari ◽  
Ashvin Hosangadi ◽  
Andrea Zambon ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Sound Speed ◽  
Industrial Applications ◽  
Operating Conditions ◽  
Working Fluid ◽  
Power Cycles ◽  
Frequency Detection ◽  
Temperature And Pressure ◽  
Power Generation Systems ◽  
Piezoelectric Pressure Sensor

Abstract The objective of this research is to validate properties of mixtures relevant to supercritical carbon dioxide (sCO2) power cycles. Direct fired sCO2 cycles are promising technology for the future power generation systems. The working fluid of sCO2 cycles will be near and above critical point of CO2. One of the challenges is that the simulation of mixtures should consider real gas behavior. Expected operating conditions of Allam cycles reach up to 300 bar and 1000 °C. Characterizing the mixtures at the extreme conditions is an important issue in current researches and industrial applications. Thermophysical properties of mixtures may be beyond the valid range of the widely used database such as NIST REFPROP. Experimental data of mixtures properties in the literature is limited which is necessary to develop high-fidelity design tools for sCO2 power cycles. We measured density and sound speed of several multi-component mixtures. A temperature-controlled high-pressure test cell was used for the density measurements. Sound speed was measured by resonant frequency detection using an external speaker and a piezoelectric pressure sensor. Mixtures studied in this work includes carbon dioxide, methane, oxygen and water vapor. Properties of pure CO2 were measured to show the validity of our technique. Compositions were selected to be close to frozen mixtures at the inlet, mid-progress and exhaust conditions of a model sCO2 combustor in the previous numerical simulation work. Corresponding reaction progress variables (RPV) were RPV = 0, 0.5, and 1. Temperature and pressure conditions of experiments are 310–450 K, and 0–150 bar. In our study, density and sound speed from NIST REFPROP database agree with experimental measurements within the range of our measurement uncertainties.

scholarly journals Corrosion and Erosion Behavior in Supercritical CO2 Power Cycles

2014 ◽  
Author(s):  
Darryn Fleming ◽  
Alan Kruizenga ◽  
James Pasch ◽  
Tom Conboy ◽  
Matt Carlson
Keyword(s):  
Carbon Dioxide ◽  
Stainless Steel ◽  
Intergranular Corrosion ◽  
Supercritical Co2 ◽  
Power Production ◽  
Operating Conditions ◽  
Working Fluid ◽  
Power Cycles ◽  
Power Cycle ◽  
Potential Issue

Supercritical Carbon Dioxide (S-CO2) is emerging as a potential working fluid in power-production Brayton cycles. As a result, concerns have been raised regarding fluid purity within the power cycle loops. Additionally, investigations into the longevity of the S-CO2 power cycle materials are being conducted to quantify the advantages of using S-CO2 versus other fluids, since S-CO2 promises substantially higher efficiencies. One potential issue with S-CO2 systems is intergranular corrosion [1]. At this time, Sandia National Laboratories (SNL) is establishing a materials baseline through the analysis of 1) “as received” stainless steel piping, and 2) piping exposed to S-CO2 under typical operating conditions with SNL’s Brayton systems. Results from ongoing investigations are presented. A second issue that SNL has discovered involves substantial erosion in the turbine blade and inlet nozzle. It is believed that this is caused by small particulates that originate from different materials around the loop that are entrained by the S-CO2 to the nozzle, where they impact the inlet nozzle vanes, causing erosion. We believe that, in some way, this is linked to the purity of the S-CO2, the corrosion contaminants, and the metal particulates that are present in the loop and its components.

scholarly journals Influence of the initial parameters on the thermodynamic efficiency of carbon dioxide power cycles

2022 ◽  
Vol 2150 (1) ◽  
pp. 012011
Author(s):  
P A Shchinnikov ◽  
I S Sadkin ◽  
A P Shchinnikov ◽  
N F Cheganova ◽  
N I Vorogushina
Keyword(s):  
Heat Transfer ◽  
Carbon Dioxide ◽  
Initial Temperature ◽  
Great Influence ◽  
Working Fluid ◽  
Thermodynamic Efficiency ◽  
Regenerative Heat ◽  
Power Cycles ◽  
Power Cycle ◽  
Temperature And Pressure

Abstract This paper considers the main CO2 power cycle configurations based on the Allam and JIHT cycles. In particular, the authors of the article have proposed new configurations of the power cycle. The efficiency of these cycles is studied as a function of the initial temperature and pressure of the working fluid. The thermodynamic efficiency can reach 65–66%. It is shown that the presence of regenerative heat transfer and the properties of supercritical carbon dioxide have a great influence on the thermal efficiency.

Computation of Thermodynamic Properties of Carbon Dioxide in the Range 0–750 Deg C

1970 ◽  
Vol 92 (3) ◽  
pp. 301-309 ◽  
Author(s):  
G. Angelino ◽  
E. Macchi
Keyword(s):  
Carbon Dioxide ◽  
Thermal Properties ◽  
High Temperature ◽  
Thermodynamic Properties ◽  
Thermodynamic Functions ◽  
Critical Region ◽  
Density Measurement ◽  
Working Fluid ◽  
Power Cycles ◽  
Wide Range

The computation of power cycles employing carbon dioxide as working fluid and extending down to the critical region requires the knowledge of the thermodynamic properties of CO2 within a wide range of pressures and temperatures. Available data are recognized to be insufficient or insufficiently accurate chiefly in the vicinity of the critical dome. Newly published density and specific heat measurements are employed to compute thermodynamic functions at temperatures between 0 and 50 deg C, where the need of better data is more urgent. Methods for the computation of thermal properties from density measurement in the low and in the high temperature range are presented and discussed. Results are reported of the computation of entropy and enthalpy of CO2 in the range 150–750 deg C and 40–600 atm. The probable precision of the tables is inferred from an error analysis based on the generation, by means of a computer program of a set of pseudoexperimental points which, treated as actual measurements, yield useful information about the accuracy of the calculation procedure.

Application of Supercritical Fluids in Thermal- and Nuclear-Power Engineering

2021 ◽  
pp. 601-658
Author(s):  
Igor L. Pioro
Keyword(s):  
Heat Transfer ◽  
Carbon Dioxide ◽  
Supercritical Fluids ◽  
Nuclear Power ◽  
Power Plants ◽  
Thermal Power ◽  
Rankine Cycle ◽  
Working Fluid ◽  
Thermal Power Plants ◽  
Power Cycles

Supercritical Fluids (SCFs) have unique thermophyscial properties and heat-transfer characteristics, which make them very attractive for use in power industry. In this chapter, specifics of thermophysical properties and heat transfer of SCFs such as water, carbon dioxide, and helium are considered and discussed. Also, particularities of heat transfer at Supercritical Pressures (SCPs) are presented, and the most accurate heat-transfer correlations are listed. Supercritical Water (SCW) is widely used as the working fluid in the SCP Rankine “steam”-turbine cycle in fossil-fuel thermal power plants. This increase in thermal efficiency is possible by application of high-temperature reactors and power cycles. Currently, six concepts of Generation-IV reactors are being developed, with coolant outlet temperatures of 500°C~1000°C. SCFs will be used as coolants (helium in GFRs and VHTRs, and SCW in SCWRs) and/or working fluids in power cycles (helium, mixture of nitrogen (80%) and helium (20%), nitrogen and carbon dioxide in Brayton gas-turbine cycles, and SCW/“steam” in Rankine cycle).

CFD Simulation of a Supersonic Steam Ejector for Refrigeration Application

2016 ◽  
Author(s):  
Liju Su ◽  
Ramesh K. Agarwal
Keyword(s):  
Flow Field ◽  
Cfd Simulation ◽  
Fluid Pressure ◽  
Turbulence Models ◽  
Industrial Applications ◽  
Operating Conditions ◽  
Working Fluid ◽  
Entrainment Ratio ◽  
Ansys Fluent ◽  
Entrainment Velocity

Supersonic steam ejectors are widely used in many industrial applications, for example for refrigeration and desalination. The experimental evaluation of the flow field inside the ejector is relatively difficult and costly due to the occurrence of shock after the velocity of the steam reaches over the sonic level in the ejector. In this paper, numerical simulations are conducted to investigate the detailed flow field inside a supersonic steam (water vapor being the working fluid) ejector. The commercial computational fluid dynamics (CFD) flow solver ANSYS-Fluent and the mesh generation software ANSYS-ICEM are used to predict the steam performance during the mixing inside the ejector by employing two turbulence models, the k-ω SST and the k-ε realizable models. The computed results are validated against the experimental data. The effects of operating conditions on the efficiency of the ejector such as the primary fluid pressure and condenser pressure are studied to obtain a better understanding of the mixing process and entrainment. Velocity contours, pressure plots and shock region analyses provide a good understanding for optimization of the ejector performance, in particular how to increase the entrainment ratio.

Modeling Off-Design and Part-Load Performance of Supercritical Carbon Dioxide Power Cycles

2013 ◽  
Author(s):  
John J. Dyreby ◽  
Sanford A. Klein ◽  
Gregory F. Nellis ◽  
Douglas T. Reindl
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Ambient Air ◽  
Working Fluid ◽  
Brayton Cycle ◽  
Heat Rejection ◽  
Power Cycles ◽  
Part Load ◽  
Dry Cooling ◽  
Supercritical Carbon

Continuing efforts to increase the efficiency of utility-scale electricity generation has resulted in considerable interest in Brayton cycles operating with supercritical carbon dioxide (S-CO2). One of the advantages of S-CO2 Brayton cycles, compared to the more traditional steam Rankine cycle, is that equal or greater thermal efficiencies can be realized using significantly smaller turbomachinery. Another advantage is that heat rejection is not limited by the saturation temperature of the working fluid, facilitating dry cooling of the cycle (i.e., the use of ambient air as the sole heat rejection medium). While dry cooling is especially advantageous for power generation in arid climates, the reduction in water consumption at any location is of growing interest due to likely tighter environmental regulations being enacted in the future. Daily and seasonal weather variations coupled with electric load variations means the plant will operate away from its design point the majority of the year. Models capable of predicting the off-design and part-load performance of S-CO2 power cycles are necessary for evaluating cycle configurations and turbomachinery designs. This paper presents a flexible modeling methodology capable of predicting the steady state performance of various S-CO2 cycle configurations for both design and off-design ambient conditions, including part-load plant operation. The models assume supercritical CO2 as the working fluid for both a simple recuperated Brayton cycle and a more complex recompression Brayton cycle.

scholarly journals Evaluation of Property Methods for Modeling Direct-Supercritical CO2 Power Cycles

2017 ◽  
Vol 140 (1) ◽  
Author(s):  
Charles W. White ◽  
Nathan T. Weiland
Keyword(s):  
Power Plants ◽  
Physical Property ◽  
Aspen Plus ◽  
Cost Effective ◽  
Operating Conditions ◽  
Working Fluid ◽  
Power Cycles ◽  
As Species ◽  
Cost Effective Method ◽  
Open Nature

Direct supercritical carbon dioxide (sCO2) power cycles are an efficient and potentially cost-effective method of capturing CO2 from fossil-fueled power plants. These cycles combust natural gas or syngas with oxygen in a high pressure (200–300 bar), heavily diluted sCO2 environment. The cycle thermal efficiency is significantly impacted by the proximity of the operating conditions to the CO2 critical point (31 °C, 73.7 bar) as well as to the level of working fluid dilution by minor components, thus it is crucial to correctly model the appropriate thermophysical properties of these sCO2 mixtures. These properties are also important for determining how water is removed from the cycle and for accurate modeling of the heat exchange within the recuperator. This paper presents a quantitative evaluation of ten different property methods that can be used for modeling direct sCO2 cycles in Aspen Plus®. Reference fluid thermodynamic and transport properties (REFPROP) is used as the de facto standard for analyzing high-purity indirect sCO2 systems, however, the addition of impurities due to the open nature of the direct sCO2 cycle introduces uncertainty to the REFPROP predictions as well as species that REFPROP cannot model. Consequently, a series of comparative analyses were performed to identify the best physical property method for use in Aspen Plus® for direct-fired sCO2 cycles. These property methods are assessed against several mixture property measurements and offer a relative comparison to the accuracy obtained with REFPROP. The Lee–Kessler–Plocker equation of state (EOS) is recommended if REFPROP cannot be used.

Analysis of Advanced Supercritical Carbon Dioxide Power Cycles With a Bottoming Cycle for Concentrating Solar Power Applications

2013 ◽  
Vol 136 (1) ◽  
Author(s):  
Saeb M. Besarati ◽  
D. Yogi Goswami
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Solar Power ◽  
Waste Heat ◽  
Operating Conditions ◽  
Working Fluid ◽  
Brayton Cycle ◽  
Concentrating Solar Power ◽  
Working Fluids ◽  
Supercritical Carbon

A number of studies have been performed to assess the potential of using supercritical carbon dioxide (S-CO2) in closed-loop Brayton cycles for power generation. Different configurations have been examined among which recompression and partial cooling configurations have been found very promising, especially for concentrating solar power (CSP) applications. It has been demonstrated that the S-CO2 Brayton cycle using these configurations is capable of achieving more than 50% efficiency at operating conditions that could be achieved in central receiver tower type CSP systems. Although this efficiency is high, it might be further improved by considering an appropriate bottoming cycle utilizing waste heat from the top S-CO2 Brayton cycle. The organic Rankine cycle (ORC) is one alternative proposed for this purpose; however, its performance is substantially affected by the selection of the working fluid. In this paper, a simple S-CO2 Brayton cycle, a recompression S-CO2 Brayton cycle, and a partial cooling S-CO2 Brayton cycle are first simulated and compared with the available data in the literature. Then, an ORC is added to each configuration for utilizing the waste heat. Different working fluids are examined for the bottoming cycles and the operating conditions are optimized. The combined cycle efficiencies and turbine expansion ratios are compared to find the appropriate working fluids for each configuration. It is also shown that combined recompression-ORC cycle achieves higher efficiency compared with other configurations.

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