scholarly journals Corrosion and Erosion Behavior in Supercritical CO2 Power Cycles

2014 ◽  
Author(s):  
Darryn Fleming ◽  
Alan Kruizenga ◽  
James Pasch ◽  
Tom Conboy ◽  
Matt Carlson
Keyword(s):  
Carbon Dioxide ◽  
Stainless Steel ◽  
Intergranular Corrosion ◽  
Supercritical Co2 ◽  
Power Production ◽  
Operating Conditions ◽  
Working Fluid ◽  
Power Cycles ◽  
Power Cycle ◽  
Potential Issue

Supercritical Carbon Dioxide (S-CO2) is emerging as a potential working fluid in power-production Brayton cycles. As a result, concerns have been raised regarding fluid purity within the power cycle loops. Additionally, investigations into the longevity of the S-CO2 power cycle materials are being conducted to quantify the advantages of using S-CO2 versus other fluids, since S-CO2 promises substantially higher efficiencies. One potential issue with S-CO2 systems is intergranular corrosion [1]. At this time, Sandia National Laboratories (SNL) is establishing a materials baseline through the analysis of 1) “as received” stainless steel piping, and 2) piping exposed to S-CO2 under typical operating conditions with SNL’s Brayton systems. Results from ongoing investigations are presented. A second issue that SNL has discovered involves substantial erosion in the turbine blade and inlet nozzle. It is believed that this is caused by small particulates that originate from different materials around the loop that are entrained by the S-CO2 to the nozzle, where they impact the inlet nozzle vanes, causing erosion. We believe that, in some way, this is linked to the purity of the S-CO2, the corrosion contaminants, and the metal particulates that are present in the loop and its components.

scholarly journals Supercritical CO2 Heat Exchanger Fouling and its Impact on RCBC Efficiency

2018 ◽  
Author(s):  
Darryn Fleming ◽  
Kirsten Norman ◽  
Salvador Rodriguez ◽  
James Pasch ◽  
Matthew Carlson ◽  
...  
Keyword(s):  
Heat Exchanger ◽  
Pressure Drop ◽  
Supercritical Co2 ◽  
Critical Factor ◽  
Power Production ◽  
Working Fluid ◽  
Power Cycles ◽  
Power Cycle ◽  
Printed Circuit ◽  
Overall Efficiency

As supercritical carbon dioxide (sCO2) is emerging as a potential working fluid in power production Brayton cycles, fluid purity within the power cycle loops has become an issue impacting commercialization. Sandia National Laboratories has been evaluating the longevity of sCO2 recompression closed Brayton power cycles to quantify the advantages of sCO2 over other fluids as utilizing sCO2 yields comparatively greater efficiencies. Hydrocarbon plugging has been observed in the small printed circuit heat exchanger channels of our high temperature recuperator, increasing pressure drop across the heat exchanger. As pressure drop is a critical factor in the overall efficiency of sCO2 recompression closed Brayton cycles, in this paper we report on our investigation into heat exchanger efficiency reduction from hydrocarbon plugging induced pressure drop.

Selecting the Optimum Supercritical CO2 Cycle for Indirect-Fired Applications

2019 ◽  
Author(s):  
Brittany Tom ◽  
January Smith ◽  
Aaron M. McClung
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Supercritical Co2 ◽  
Operating Conditions ◽  
Working Fluid ◽  
Performance Goals ◽  
Brayton Cycle ◽  
Power Cycle ◽  
And Performance ◽  
Supercritical Carbon

Abstract Existing research has demonstrated the viability of supercritical carbon dioxide as an efficient working fluid with numerous advantages over steam in power cycle applications. Selecting the appropriate power cycle configuration for a given application depends on expected operating conditions and performance goals. This paper presents a comparison for three indirect fired sCO2 cycles: recompression closed Brayton cycle, dual loop cascaded cycle, and partial condensation cycle. Each cycle was modeled in NPSS with an air side heater, given the same baseline assumptions and optimized over a range of conditions. Additionally, limitations on the heater system are discussed.

scholarly journals Measurements of Density and Sound Speed in Mixtures Relevant to Supercritical CO2 Cycles

2020 ◽  
Vol 142 (10) ◽  
Author(s):  
Suhyeon Park ◽  
Justin Urso ◽  
K.R.V. (Raghu) Manikantachari ◽  
Ashvin Hosangadi ◽  
Andrea Zambon ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Sound Speed ◽  
Industrial Applications ◽  
Operating Conditions ◽  
Working Fluid ◽  
Power Cycles ◽  
Frequency Detection ◽  
Temperature And Pressure ◽  
Power Generation Systems ◽  
Piezoelectric Pressure Sensor

Abstract The objective of this research is to validate properties of mixtures relevant to supercritical carbon dioxide (sCO2) power cycles. Direct-fired sCO2 cycles are a promising technology for the future power generation systems. The working fluid of sCO2 cycles will be near and above critical point of CO2. One of the challenges is that the simulation of mixtures should consider real gas behavior. Expected operating conditions of Allam cycles reach up to 300 bar and 1000 °C. Characterizing the mixtures at the extreme conditions is an important issue in current researches and industrial applications. Thermophysical properties of mixtures may be beyond the valid range of the widely used database such as NIST REFPROP. Experimental data of mixture properties in the literature are limited which is necessary to develop high-fidelity design tools for sCO2 power cycles. We measured the density and sound speed of several multi-component mixtures. A temperature-controlled high-pressure test cell was used for the density measurements. Sound speed was measured by resonant frequency detection using an external speaker and a piezoelectric pressure sensor. Mixtures studied in this work include carbon dioxide, methane, oxygen, and water vapor. Properties of pure CO2 were measured to show the validity of our technique. Compositions were selected to be close to frozen mixtures at the inlet, mid-progress, and exhaust conditions of a model sCO2 combustor in the previous numerical simulation work. Corresponding reaction progress variables (RPV) were RPV = 0, 0.5, and 1. Temperature and pressure conditions of experiments are 310–450 K and 0–150 bar. In our study, density and sound speed from the NIST REFPROP database agree with experimental measurements within the range of our measurement uncertainties.

Measurements of Density and Sound Speed in Mixtures Relevant to sCO2 Power Cycles

2020 ◽  
Author(s):  
Suhyeon Park ◽  
Justin Urso ◽  
K. R. V. (Raghu) Manikantachari ◽  
Ashvin Hosangadi ◽  
Andrea Zambon ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Sound Speed ◽  
Industrial Applications ◽  
Operating Conditions ◽  
Working Fluid ◽  
Power Cycles ◽  
Frequency Detection ◽  
Temperature And Pressure ◽  
Power Generation Systems ◽  
Piezoelectric Pressure Sensor

Abstract The objective of this research is to validate properties of mixtures relevant to supercritical carbon dioxide (sCO2) power cycles. Direct fired sCO2 cycles are promising technology for the future power generation systems. The working fluid of sCO2 cycles will be near and above critical point of CO2. One of the challenges is that the simulation of mixtures should consider real gas behavior. Expected operating conditions of Allam cycles reach up to 300 bar and 1000 °C. Characterizing the mixtures at the extreme conditions is an important issue in current researches and industrial applications. Thermophysical properties of mixtures may be beyond the valid range of the widely used database such as NIST REFPROP. Experimental data of mixtures properties in the literature is limited which is necessary to develop high-fidelity design tools for sCO2 power cycles. We measured density and sound speed of several multi-component mixtures. A temperature-controlled high-pressure test cell was used for the density measurements. Sound speed was measured by resonant frequency detection using an external speaker and a piezoelectric pressure sensor. Mixtures studied in this work includes carbon dioxide, methane, oxygen and water vapor. Properties of pure CO2 were measured to show the validity of our technique. Compositions were selected to be close to frozen mixtures at the inlet, mid-progress and exhaust conditions of a model sCO2 combustor in the previous numerical simulation work. Corresponding reaction progress variables (RPV) were RPV = 0, 0.5, and 1. Temperature and pressure conditions of experiments are 310–450 K, and 0–150 bar. In our study, density and sound speed from NIST REFPROP database agree with experimental measurements within the range of our measurement uncertainties.

Investigation of Magnetic Journal Bearing Instability Issues in Supercritical CO2 Turbomachinery

2019 ◽  
Author(s):  
Dokyu Kim ◽  
SeungJoon Baik ◽  
Jeong Ik Lee
Keyword(s):  
Supercritical Co2 ◽  
High Speed ◽  
Magnetic Bearing ◽  
Operating Conditions ◽  
Physical Contact ◽  
Analysis Model ◽  
Rotating Shaft ◽  
Power Cycles ◽  
Power Cycle ◽  
Lubrication Performance

Abstract With the increasing emphasis on reducing the CO2 emission while improving power generation efficiency, new power cycles are being developed. One of those promising power cycles is a supercritical CO2 (S-CO2) power cycle. To generate over 10MW electricity with S-CO2 power cycle, a magnetic bearing can be a good option for the hermetic type turbomachinery. However, from several studies on the magnetic bearing, the instability issues under high density fluid and high speed operating conditions were repeatedly mentioned. The instability in the magnetic bearing was observed to be related to the fluid conditions, mostly pressure and density. Because of this issue, the magnetic bearing sometimes cannot maintain enough clearance for the rotor leading to physical contact and consequently damaging the system. Thus, these instability issues should be thoroughly studied and be resolved for the successful and steady operation of the power system. The instability due to fluid force around the rotating shaft can be modeled with the Reynolds lubrication equation. The steady lubrication force analysis model is developed based on this equation. The model results imply that the lubrication performance is quite sensitive to the thermal condition of the CO2 especially density gradient around the shaft. Based on the modeling results, an experimental system is designed to investigate the issue. To study the instability issues experimentally, an impeller of the operating S-CO2 compressor is removed and the discharge line is blocked. Therefore, the main instability factor in this experiment will be the interaction between the rotor and the bearing only. The shaft position can be measured with inductive sensors. The forces exerted from the electromagnet is calculated from the electric current data which is applied by the controller. From these experimental data, the lubrication force is calculated. These results are compared with the analytical lubrication model to verify the model. From this study, it is expected that it will be possible to define the unstable operating conditions and suggest the required magnetic bearing performance for S-CO2 conditions.

High Efficiency SOFC Power Cycles With Indirect Natural Gas Reforming and CO2 Capture

2015 ◽  
Vol 12 (2) ◽  
Author(s):  
Stefano Campanari ◽  
Matteo Gazzani
Keyword(s):  
High Temperature ◽  
Natural Gas ◽  
Gas Turbine ◽  
Co2 Capture ◽  
Heat Exchangers ◽  
High Efficiency ◽  
Power Production ◽  
Operating Conditions ◽  
Power Cycles ◽  
Power Cycle

Driven by the search for the highest theoretical efficiency, several studies have investigated in the last years the adoption of fuel cells (FCs) in the field of power production from natural gas with CO2 capture. Most of the proposed power cycles rely on high temperature FCs, namely, solid oxide FCs (SOFCs) and molten carbonate FCs (MCFCs), based on the concept of hybrid FC plus gas turbine cycles. Accordingly, high temperature FCs are integrated with a simple or modified Brayton cycle. As far as SOFCs are concerned, CO2 can be separated downstream the FC via a range of available technologies, e.g., chemical or physical separation processes, oxy-combustion, and cryogenic methods. Following a literature review on promising plant configurations, this work investigates the potential of adopting an external natural gas conversion section with respect to the plant efficiency. As a reference plant, we considered a power cycle proposed by Adams and Barton (2010, “High-Efficiency Power Production From Natural Gas With Carbon Capture,” J. Power Sources, 195(7), pp. 1971–1983), whose performance is the highest found in literature for SOFC-based power cycles, with 82% LHV electrical efficiency. It is based on a prereforming concept where fuel is reformed ahead the SOFC, which thus works with a high hydrogen content fuel. After reproducing the power cycle with the ideal assumptions proposed by the original authors, as second step, the simulations were focused on revising the power cycle, implementing a complete set of assumptions about component losses and more conservative operating conditions about FC voltage, heat exchangers minimum temperature differences (which were previously neglected), maximum steam temperature (set according to heat recovery steam generator (HRSG) practice), turbomachinery efficiency, component pressure losses, and other adjustments. The simulation also required to design an appropriate heat exchangers network, which turned out to be very complex, instead of relying on the free allocation of heat transfer among all components. Considering the consequent modifications with respect to the original layout, the net electric efficiency changes to around 63% LHV with nearly complete (95%+) CO2 capture, a still remarkable but less attractive value. On the other hand, the power cycle requires a complicated and demanding heat exchangers network and heavily relies on the SOFC performances, not generating a positive power output from the gas turbine loop. Detailed results are presented in terms of energy and material balances of the proposed cycles. All simulations have been carried out with the proprietary code GS, developed by the GECOS group at Politecnico di Milano.

Evaluation of Property Methods for Modeling Direct-Supercritical CO2 Power Cycles

2017 ◽  
Author(s):  
Charles W. White ◽  
Nathan T. Weiland
Keyword(s):  
Oil Recovery ◽  
Supercritical Co2 ◽  
Power Plants ◽  
Physical Property ◽  
Aspen Plus ◽  
Cost Effective ◽  
Operating Conditions ◽  
Cycle Performance ◽  
Working Fluid ◽  
Power Cycles

Direct supercritical CO2 (sCO2) power cycles have received considerable attention in recent years as an efficient and potentially cost-effective method of capturing CO2 from fossil-fueled power plants. These cycles combust natural gas or syngas with oxygen in a high pressure (200–300 bar), heavily-diluted sCO2 environment, such that the fluid entering the turbine is 90–95% CO2, with the balance composed primarily of H2O, CO, O2, N2 and Ar. After recuperation of the turbine exhaust thermal energy, water is condensed from the cycle, and the remainder is recompressed for either return to the combustor or for enhanced oil recovery (EOR) or storage. The compression power requirements vary significantly, depending on the proximity of the operating conditions to the CO2 critical point (31 °C, 73.7 bar), as well as to the level of working fluid dilution by minor components. As this has a large impact on cycle and plant thermal efficiency, it is crucial to correctly capture the appropriate thermo-physical properties of these sCO2 mixtures when carrying out performance simulations of direct sCO2 power plants. These properties are also important to determining how water is removed from the cycle, and for accurate modeling of the heat exchange within the recuperator. This paper presents a quantitative evaluation of ten different property methods that can be used for modeling direct sCO2 cycles in Aspen Plus®. REFPROP is used as the de facto standard for analyzing indirect sCO2 systems, where the closed nature of the cycle leads to a high purity CO2 working fluid. The addition of impurities due to the open nature of the direct-sCO2 cycle, however, introduces uncertainty to the REFPROP predictions. There is a limited set of mixtures available for which REFPROP can be reliably used and there are a number of species present in a coal-fired direct-fired sCO2 cycle that REFPROP cannot accommodate. Even with a relatively simplified system in which the trace components are eliminated, simulations made using REFPROP require computation times that often preclude its use in parametric studies of these cycles. Consequently, a series of comparative analyses were performed to identify the best physical property method for use in Aspen Plus® for direct-fired sCO2 cycles. These property methods are assessed against several mixture property measurements, and offer a relative comparison to the accuracy obtained with REFPROP. This study also underscores the necessity of accurate property modeling, where cycle performance predictions are shown to vary significantly with the selection of the physical property method.

scholarly journals Influence of the initial parameters on the thermodynamic efficiency of carbon dioxide power cycles

2022 ◽  
Vol 2150 (1) ◽  
pp. 012011
Author(s):  
P A Shchinnikov ◽  
I S Sadkin ◽  
A P Shchinnikov ◽  
N F Cheganova ◽  
N I Vorogushina
Keyword(s):  
Heat Transfer ◽  
Carbon Dioxide ◽  
Initial Temperature ◽  
Great Influence ◽  
Working Fluid ◽  
Thermodynamic Efficiency ◽  
Regenerative Heat ◽  
Power Cycles ◽  
Power Cycle ◽  
Temperature And Pressure

Abstract This paper considers the main CO2 power cycle configurations based on the Allam and JIHT cycles. In particular, the authors of the article have proposed new configurations of the power cycle. The efficiency of these cycles is studied as a function of the initial temperature and pressure of the working fluid. The thermodynamic efficiency can reach 65–66%. It is shown that the presence of regenerative heat transfer and the properties of supercritical carbon dioxide have a great influence on the thermal efficiency.

Experimental and Numerical Study of Critical Flow Model Development for Supercritical CO2 Power Cycle Application

2018 ◽  
Author(s):  
Min Seok Kim ◽  
Bong Seong Oh ◽  
Hwa-Young Jung ◽  
Seong Jun Bae ◽  
Jeong Ik Lee
Keyword(s):  
Supercritical Co2 ◽  
Numerical Study ◽  
Operating Conditions ◽  
Working Fluid ◽  
Critical Flow ◽  
Phase System ◽  
Phase Flow ◽  
Two Phase ◽  
Gaseous State ◽  
Power Cycle

Supercritical CO2 (S-CO2) has the potential to be used as the working fluid in a power cycle since S-CO2 shows a density value high as its liquid phase while the viscosity value remains closer to its gaseous phase. Thus, it requires much less work to compress due to its low compressibility as well as relatively small flow resistance. However, the S-CO2 leakage flow from turbo-machinery via seal becomes one of the important issues since not only it influences the cycle efficiency due to parasitic loss but also it is important for evaluating the system safety under various operating conditions. In the previous turbo expo paper, the effect of the tooth length on the critical flow and comparing the results to the existing two phase system analysis code calculation were presented. In this paper, the gap effect, which is simulated by changing the diameter of a orifice and the number of tooth effect in a labyrinth seal geometry nozzle are presented by using the same experimental facility described in the previous paper. In addition, this paper includes the experimental results under various conditions including not only single phase flow such as supercritical, and gaseous state only but also two phase flow condition.

Performance Analysis and Comparison Study of Transcritical Power Cycles Using CO2-Based Mixtures as Working Fluids

2016 ◽  
Author(s):  
Jiaxi Xia ◽  
Jiangfeng Wang ◽  
Pan Zhao ◽  
Dai Yiping
Keyword(s):  
Critical Temperature ◽  
Parametric Optimization ◽  
Design Parameters ◽  
Working Fluid ◽  
Comparison Study ◽  
Software Environment ◽  
Working Fluids ◽  
Power Cycles ◽  
Power Cycle ◽  
Thermodynamic Performance

CO2 in a transcritical CO2 cycle can not easily be condensed due to its low critical temperature (304.15K). In order to increase the critical temperature of working fluid, an effective method is to blend CO2 with other refrigerants to achieve a higher critical temperature. In this study, a transcritical power cycle using CO2-based mixtures which blend CO2 with other refrigerants as working fluids is investigated under heat source. Mathematical models are established to simulate the transcritical power cycle using different CO2-based mixtures under MATLAB® software environment. A parametric analysis is conducted under steady-state conditions for different CO2-based mixtures. In addition, a parametric optimization is carried out to obtain the optimal design parameters, and the comparisons of the transcritical power cycle using different CO2-based mixtures and pure CO2 are conducted. The results show that a raise in critical temperature can be achieved by using CO2-based mixtures, and CO2-based mixtures with R32 and R22 can also obtain better thermodynamic performance than pure CO2 in transcritical power cycle. What’s more, the condenser area needed by CO2-based mixture is smaller than pure CO2.

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