scholarly journals Effect of Supercritical CO2 on Steel Ductility at 450°-650°C

2021 ◽  
Author(s):  
Bruce A. Pint ◽  
Rishi Pillai ◽  
James R. Keiser
Keyword(s):  
Tensile Properties ◽  
Supercritical Co2 ◽  
Room Temperature ◽  
Reaction Rates ◽  
Significant Loss ◽  
Austenitic Steels ◽  
Maximum Temperature ◽  
Clear Correlation ◽  
Temperature Capability ◽  
Product Thickness

Abstract The compatibility of ferritic-martensitic (FM) and conventional and advanced austenitic steels with supercritical CO2 (sCO2) is being explored at 450°–650°C to determine their maximum temperature capability. In addition to measuring reaction kinetics and reaction product thickness, bulk carbon content and post-exposure room temperature tensile properties were assessed by exposing both alloy coupons and 25 mm long dogbone tensile specimens. After 1–2 kh exposures in 300 bar research grade (RG) sCO2, ∼9 and 12%Cr FM steels had similar behavior under these conditions. Consistent with the literature, higher Cr and Ni contents in alloy 316H provided lower reaction rates at 450° and 550°C, but limited benefit at 650°C with similar degradation of tensile properties and C ingress observed. An advanced austenitic Nb-modified 20Cr-25Ni alloy 709 provided the best compatibility even at 650°C with no C uptake detected after 1 kh and no significant loss in room temperature tensile properties after exposure. A clear correlation was observed under these conditions between the formation of a thin, protective Cr-rich oxide scale and the prevention of C ingress and tensile property degradation at 650°C.

Survival of mouse blastocysts after low-temperature preservation under high pressure

2004 ◽  
Vol 52 (4) ◽  
pp. 479-487 ◽  
Author(s):  
Cs. Pribenszky ◽  
M. Molnár ◽  
S. Cseh ◽  
L. Solti
Keyword(s):  
Phase Transition ◽  
Hydrostatic Pressure ◽  
Low Temperature ◽  
High Hydrostatic Pressure ◽  
Room Temperature ◽  
Freezing Point ◽  
Significant Loss ◽  
Embryo Cryopreservation ◽  
Subzero Temperatures ◽  
Survival Capacity

Cryoinjuries are almost inevitable during the freezing of embryos. The present study examines the possibility of using high hydrostatic pressure to reduce substantially the freezing point of the embryo-holding solution, in order to preserve embryos at subzero temperatures, thus avoiding all the disadvantages of freezing. The pressure of 210 MPa lowers the phase transition temperature of water to -21°C. According to the results of this study, embryos can survive in high hydrostatic pressure environment at room temperature; the time embryos spend under pressure without significant loss in their survival could be lengthened by gradual decompression. Pressurisation at 0°C significantly reduced the survival capacity of the embryos; gradual decompression had no beneficial effect on survival at that stage. Based on the findings, the use of the phenomena is not applicable in this form, since pressure and low temperature together proved to be lethal to the embryos in these experiments. The application of hydrostatic pressure in embryo cryopreservation requires more detailed research, although the experience gained in this study can be applied usefully in different circumstances.

A Reinvestigation of the Deceptively Simple Reaction of Toluene with ●OH, and the Fate of the Benzyl Radical. I. a Combined Thermodynamic and Kinetic Study on the Competition Between ●OH Addition and Hydrogen Abstraction Reactions.

2019 ◽  
Author(s):  
Zoi Salta ◽  
Agnie M. Kosmas ◽  
Marc E. Segovia ◽  
Martina Kieninger ◽  
Oscar Ventura ◽  
...  
Keyword(s):  
Density Functional ◽  
Room Temperature ◽  
Hydrogen Abstraction ◽  
Reaction Rates ◽  
Composite Model ◽  
Alternative Mechanism ◽  
Radical Intermediate ◽  
Experimental Conditions ◽  
Methyl Group ◽  
Benzyl Radical

This work reports density functional and composite model chemistry calculations performed on the reactions of toluene with the hydroxyl radical. Both experimentally observed H-abstraction from the methyl group and possible additions to the phenyl ring were investigated. Reaction enthalpies and heights of the barriers suggest that H-abstraction is more favorable than ●OH addition to the ring. The calculated reaction rates at room temperature and the radical-intermediate product fractions support this view. This is somehow contradictory with the fact that, under most experimental conditions, cresols are observed in a larger concentration than benzaldehyde. Since the accepted mechanism for benzaldehyde formation involves H-abstraction, a contradiction arises that begs for an explanation. In this first part of our work we give the evidences that support the preference of hydrogen abstraction over ●OH addition and suggest an alternative mechanism which shows that cresols can actually arise also from the former reaction and not only from the latter.

A Reinvestigation of the Deceptively Simple Reaction of Toluene with ●OH, and the Fate of the Benzyl Radical. I. a Combined Thermodynamic and Kinetic Study on the Competition Between ●OH Addition and Hydrogen Abstraction Reactions.

2019 ◽  
Author(s):  
Zoi Salta ◽  
Agnie M. Kosmas ◽  
Marc E. Segovia ◽  
Martina Kieninger ◽  
Oscar Ventura ◽  
...  
Keyword(s):  
Density Functional ◽  
Room Temperature ◽  
Hydrogen Abstraction ◽  
Reaction Rates ◽  
Composite Model ◽  
Alternative Mechanism ◽  
Radical Intermediate ◽  
Experimental Conditions ◽  
Methyl Group ◽  
Benzyl Radical

This work reports density functional and composite model chemistry calculations performed on the reactions of toluene with the hydroxyl radical. Both experimentally observed H-abstraction from the methyl group and possible additions to the phenyl ring were investigated. Reaction enthalpies and heights of the barriers suggest that H-abstraction is more favorable than ●OH addition to the ring. The calculated reaction rates at room temperature and the radical-intermediate product fractions support this view. This is somehow contradictory with the fact that, under most experimental conditions, cresols are observed in a larger concentration than benzaldehyde. Since the accepted mechanism for benzaldehyde formation involves H-abstraction, a contradiction arises that begs for an explanation. In this first part of our work we give the evidences that support the preference of hydrogen abstraction over ●OH addition and suggest an alternative mechanism which shows that cresols can actually arise also from the former reaction and not only from the latter.

MAGNESIUM ZK61A

Alloy Digest ◽  
1969 ◽  
Vol 18 (10) ◽  
Keyword(s):  
Corrosion Resistance ◽  
Physical Properties ◽  
Tensile Properties ◽  
Room Temperature ◽  
Heat Treating ◽  
Strength Properties ◽  
Casting Alloy ◽  
Chemical Company ◽  
Casting Alloys ◽  
Magnesium Casting

Abstract Magnesium ZK61A is a heat treatable sand casting alloy offering higher strength properties for room-temperature applications than other magnesium casting alloys. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on corrosion resistance as well as casting, heat treating, machining, and joining. Filing Code: Mg-67. Producer or source: The Dow Chemical Company.

NIROSTA 4305

Alloy Digest ◽  
2002 ◽  
Vol 51 (5) ◽  
Keyword(s):  
Corrosion Resistance ◽  
Physical Properties ◽  
Tungsten Carbide ◽  
Tensile Properties ◽  
High Speed ◽  
High Speed Steel ◽  
Heat Treating ◽  
Austenitic Steels ◽  
High Sulfur Content ◽  
Machined Parts

Abstract NIROSTA 4305 is an austenitic alloy with a high sulfur content. The alloy is typically used for machined parts. As with other austenitic steels, it is necessary to machine with good-quality high-speed steel or tungsten carbide tools. This datasheet provides information on composition, physical properties, elasticity, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: SS-854. Producer or source: ThyssenKrupp Nirosta GmbH.

DILLIDUR 450V

Alloy Digest ◽  
2011 ◽  
Vol 60 (12) ◽  
Keyword(s):  
Fracture Toughness ◽  
Wear Resistance ◽  
Physical Properties ◽  
Tensile Properties ◽  
Room Temperature ◽  
Surface Hardness ◽  
Heat Treating ◽  
Hot Working ◽  
Resistant Steel ◽  
Bend Strength

Abstract Dillidur 450V is a water hardened wear-resistant steel with surface hardness at room temperature of 420-480 HB. The steel is easy to weld and bend. Hot working is not recommended. This datasheet provides information on composition, physical properties, hardness, tensile properties, and bend strength as well as fracture toughness. It also includes information on wear resistance as well as forming, heat treating, machining, and joining. Filing Code: SA-638. Producer or source: Dillinger Hütte GTS.

XAR 500 Premium

Alloy Digest ◽  
2018 ◽  
Vol 67 (4) ◽  
Keyword(s):  
Structural Steel ◽  
Tensile Properties ◽  
Room Temperature ◽  
Heat Treating ◽  
Wear Resistant ◽  
Heavy Plate

Abstract XAR 500 Premium is a special wear-resistant structural steel. It is delivered as heavy plate 3–100 mm (0.118–3.937 in.) in the quenched or quenched and tempered condition with room temperature hardness between 470 and 530 HBW. The Premium grade contains 1.5 wt% nickel. This datasheet provides information on composition and tensile properties. It also includes information on heat treating and joining. Filing Code: SA-814. Producer or source: ThyssenKrupp Steel Europe AG.

ALLEGHENY LUDLUM TYPE 205

Alloy Digest ◽  
1997 ◽  
Vol 46 (10) ◽  
Keyword(s):  
Mechanical Properties ◽  
Stainless Steel ◽  
Corrosion Resistance ◽  
Physical Properties ◽  
Tensile Properties ◽  
Magnetic Permeability ◽  
Cold Working ◽  
High Strength ◽  
Heat Treating ◽  
Austenitic Steels

Abstract Allegheny Stainless Type 205 is a chromium-manganese nitrogen austenitic high strength stainless steel that maintains its low magnetic permeability even after large amounts of cold working. Annealed Type 205 has higher mechanical properties than any of the conventional austenitic steels-and for any given strength level, the ductility of Type 205 is comparable to that of Type 301. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fatigue. It also includes information on corrosion resistance as well as heat treating, machining, and joining. Filing Code: SS-640. Producer or source: Allegheny Ludlum Corporation. Originally published March 1996, revised October 1997.

Preparation and Characterization of a Novel Room Temperature Dicationic Ionic Liquid and its Application in the Synthesis of Xanthenediones Under Solvent-Free Conditions

2018 ◽  
Vol 21 (8) ◽  
pp. 602-608 ◽  
Author(s):  
Zainab Ehsani-Nasab ◽  
Ali Ezabadi
Keyword(s):  
Ionic Liquid ◽  
Room Temperature ◽  
Reaction Times ◽  
Significant Loss ◽  
Solvent Free ◽  
Acidity Function ◽  
Efficient Catalyst ◽  
Solvent Free Conditions ◽  
Hammett Acidity Function ◽  
Dicationic Ionic Liquid

Aim and Objective: In the present work, 1, 1’-sulfinyldiethylammonium bis (hydrogen sulfate) as a novel room temperature dicationic ionic liquid was synthesized and used as a catalyst for xanthenediones synthesis. Material and Method: The dicationic ionic liquid has been synthesized using ethylamine and thionyl chloride as precursors. Then, by the reaction of [(EtNH2)2SO]Cl2 with H2SO4, [(EtNH2)2SO][HSO4]2 was prepared and after that, it was characterized by FT-IR, 1H NMR, 13C NMR as well as Hammett acidity function. This dicationic ionic liquid was used as a catalyst for the synthesis of xanthenediones via condensation of structurally diverse aldehydes and dimedone under solvent-free conditions. The progress of the reaction was monitored by thin layer chromatography (ethyl acetate/n-hexane = 3/7). Results: An efficient solvent-free method for the synthesis of xanthenediones has been developed in the presence of [(EtNH2)2SO][HSO4]2 as a powerful catalyst with high to excellent yields, and short reaction times. Additionally, recycling studies have demonstrated that the dicationic ionic liquid can be readily recovered and reused at least four times without significant loss of its catalytic activity. Conclusion: This new dicationic ionic liquid can act as a highly efficient catalyst for xanthenediones synthesis under solvent-free conditions.

Nickel (II) and oxovanadium (IV) complexes supported on MCM-41 mesoporous and their application in catalytic selective sulfide and thiol oxidation

2020 ◽  
Vol 23 ◽  
Author(s):  
Mohsen Nikoorazm ◽  
Maryam Khanmoradi ◽  
Masoumeh Sayadian
Keyword(s):  
Catalytic Activity ◽  
Room Temperature ◽  
Sol Gel ◽  
Reaction Times ◽  
Significant Loss ◽  
Spectral Studies ◽  
High Catalytic Activity ◽  
Catalytic Systems ◽  
Solvent Free Conditions ◽  
Mcm 41

Introduction:: MCM-41 was synthesized using the sol-gel method. Then two new transition metal complexes of Nickel (II) and Vanadium (IV), were synthesized by immobilization of adenine (6-aminopurine) into MCM-41 mesoporous. The compounds have been characterized by XRD, TGA, SEM, AAS and FT-IR spectral studies. Using these catalysts provided an efficient and enantioselective procedure for oxidation of sulfides to sulfoxides and oxidative coupling of thiols to their corresponding disulfides using hydrogen peroxide at room temperature. Materials and Methods:: To a solution of sulfide or thiol (1 mmol) and H2O2 (5 mmol), a determined amount of the catalyst was added. The reaction mixture was stirred at room temperature for the specific time under solvent free conditions. The progress of the reaction was monitored by TLC using n-hexane: acetone (8:2). Afterwards, the catalyst was removed from the reaction mixture by centrifugation and, then, washed with dichloromethane in order to give the pure products. Results:: All the products were obtained in excellent yields and short reaction times indicating the high activity of the synthesized catalysts. Besides, the catalysts can be recovered and reused for several runs without significant loss in their catalytic activity. Conclusion:: These catalytic systems furnish the products very quickly with excellent yields and VO-6AP-MCM-41 shows high catalytic activity compared to Ni-6AP-MCM-41.

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