Nanomechanical and Nanotribological Properties of Nano- and Micro-Particle Filled Polymer Composites Used for Dental Restorative Applications

Author(s):  
D. Devaprakasam ◽  
P. V. Hatton ◽  
G. Moebus ◽  
B. J. Inkson

The objective of this work is to quantify nanomechanical and nanotribological properties of nano- and micro-particles filled polymer composites used for the dental restorative applications. Nanotribological performances of the two polymer composites with different reinforcing particulates were investigated using advanced microscopy techniques. Both the polymer composites composed of same dimethacrylate based monomeric mixture, Bisphenol-A-glycidyldimethacrylate (Bis-GMA), triethylene glycoldimethacrylate (TEGDMA), urethane dimethacrylate (UDMA), as matrix. It was found that the elastic modulus, hardness, particle size, shape, distribution and agglomeration significantly influence the friction and wear characteristics of the polymer composites. The results show that nanotribological performance of nanoparticle reinforced polymer composites is better than the microparticle reinforced polymer composites.

2021 ◽  
Vol 9 (3A) ◽  
Author(s):  
M Sharan Chandran ◽  
◽  
Yashasvi Chebiyyam ◽  
K Padmanabhan ◽  
◽  
...  

Interfacial properties of composite materials play an important role in overall efficiency and reliability of these materials in structural applications. The objective of this study is to develop a multiple fiber microbond pull-out test to determine the interfacial properties of self-reinforced polymer composites (SRPC) and compare it with single fiber multiple fiber pull-out tests. SRPC possess better interfacial adhesion due to their similarity in chemical structure. The system used in this study is LDPE sheet reinforced with plain weave ultra-high molecular weight polyethylene (LDPE/ UHMWPE). The optimal operating temperature was estimated with DSC and TGA analysis. The micromechanical and meso-mechanical approaches were compared to validate the results. A fractographic study was performed to correlate lamina and meso-mechanical properties found in this study. It was observed that the multiple fiber pullout test explained in this study is on par with or better than the other conventional methods to evaluate interface properties.


Author(s):  
Sachin Tejyan ◽  
Divyesh Sharma ◽  
Brijesh Gangil ◽  
Amar Patnaik ◽  
Tej Singh

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 438
Author(s):  
Ching Hao Lee ◽  
Abdan Khalina ◽  
Seng Hua Lee

Plant fibers have become a highly sought-after material in the recent days as a result of raising environmental awareness and the realization of harmful effects imposed by synthetic fibers. Natural plant fibers have been widely used as fillers in fabricating plant-fibers-reinforced polymer composites. However, owing to the completely opposite nature of the plant fibers and polymer matrix, treatment is often required to enhance the compatibility between these two materials. Interfacial adhesion mechanisms are among the most influential yet seldom discussed factors that affect the physical, mechanical, and thermal properties of the plant-fibers-reinforced polymer composites. Therefore, this review paper expounds the importance of interfacial adhesion condition on the properties of plant-fiber-reinforced polymer composites. The advantages and disadvantages of natural plant fibers are discussed. Four important interface mechanism, namely interdiffusion, electrostatic adhesion, chemical adhesion, and mechanical interlocking are highlighted. In addition, quantifying and analysis techniques of interfacial adhesion condition is demonstrated. Lastly, the importance of interfacial adhesion condition on the performances of the plant fiber polymer composites performances is discussed. It can be seen that the physical and thermal properties as well as flexural strength of the composites are highly dependent on the interfacial adhesion condition.


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