Cycle-Wise Process-Zone Model for Prediction of Delayed Hydride Cracking Initiation Under Flaw-Tip Hydride Ratcheting Conditions

Author(s):  
Steven X. Xu ◽  
Jun Cui ◽  
Douglas A. Scarth ◽  
David Cho

Flaws found during in-service inspection of Zr-2.5Nb pressure tubes in CANDU(1) reactors include fuel bundle scratches, debris fretting flaws, fuel bundle bearing pad fretting flaws and crevice corrosion flaws. These flaws are volumetric and blunt in nature. A key structural integrity concern with in-service blunt flaws is their susceptibility to delayed hydride cracking (DHC) initiation, particularly for debris fretting flaws under flaw-tip hydride ratcheting conditions. Hydride ratcheting conditions refer to situations when flaw-tip hydrides do not completely dissolve at normal operating temperature, and accumulation of flaw-tip hydrides occurs with each reactor heat-up/cool-down cycle. A significant number of in-service flaws are expected to be under hydride ratcheting conditions at late life of pressure tubes. DHC initiation evaluation procedures based on process-zone methodology for flaws under hydride ratcheting conditions are provided in CSA (Canadian Standards Association) N285.8-15. The process-zone model in CSA N285.8-15 predicts whether DHC initiation occurs or not for given flaw geometry and operating conditions, regardless of the number of reactor heat-up and cool-down cycles. There has been recent new development. Specifically, a cycle-wise process-zone model has been developed as an extension to the process-zone model in CSA N285.8-15. The cycle-wise process-zone model is able to predict whether DHC initiation occurs or not during a specific reactor heat-up and cool-down cycle under applied load. The development of the cycle-wise process-zone model was driven by the need to include flaw-tip stress relaxation due to creep in evaluation of DHC initiation. The technical basis for the development of the cycle-wise process-zone model for prediction of DHC initiation under flaw-tip hydride ratcheting conditions is described in this paper.

Author(s):  
Steven X. Xu ◽  
Dennis Kawa ◽  
Jun Cui ◽  
Heather Chaput

In-service flaws in cold-worked Zr-2.5 Nb pressure tubes in CANDU(1) reactors are susceptible to a phenomenon known as delayed hydride cracking (DHC). The material is susceptible to DHC when there is diffusion of hydrogen atoms to a service-induced flaw, precipitation of hydrides on appropriately oriented crystallographic planes in the zirconium alloy matrix material, and development of a hydrided region at the flaw tip. The hydrided region could then fracture to the extent that a crack forms and DHC is said to have initiated. Examples of in-service flaws are fuel bundle scratches, crevice corrosion marks, fuel bundle bearing pad fretting flaws, and debris fretting flaws. These flaws are volumetric in nature. Evaluation of DHC initiation from the flaw is a requirement of Canadian Standards Association (CSA) Standard N285.8. This paper describes the validation of the weight function based process-zone model for evaluation of pressure tube flaws for DHC initiation. Validation was performed by comparing the predicted threshold load levels for DHC initiation with the results from DHC initiation experiments on small notched specimens. The notches in the specimens simulate axial in-service flaws in the pressure tube. The validation was performed for both un-irradiated and pre-irradiated pressure tube material.


2009 ◽  
Vol 131 (4) ◽  
Author(s):  
Jun Cui ◽  
Gordon K. Shek ◽  
D. A. Scarth ◽  
Zhirui Wang

Delayed hydride cracking (DHC) is an important crack initiation and growth mechanism in Zr-2.5Nb alloy pressure tubes of CANDU nuclear reactors. DHC is a repetitive process that involves hydrogen diffusion, hydride precipitation, growth, and fracture of a hydrided region at a flaw tip. In-service flaw evaluation requires analyses to demonstrate that DHC will not initiate from the flaw. The work presented in this paper examines DHC initiation behavior from V-notches with root radii of 15 μm, 30 μm, and 100 μm, which simulate service-induced debris fretting flaws. Groups of notched cantilever beam specimens were prepared from two unirradiated pressure tubes hydrided to a nominal hydrogen concentration of 57 wt. ppm. The specimens were loaded to different stress levels that straddled the threshold value predicted by an engineering process-zone (EPZ) model, and subjected to multiple thermal cycles representative of reactor operating conditions to form hydrides at the notch tip. Threshold conditions for DHC initiation were established for the notch geometries and thermal cycling conditions used in this program. Test results indicate that the resistance to DHC initiation is dependent on notch root radius, which is shown by optical metallography and scanning electron microscopy to have a significant effect on the distribution and morphology of the notch-tip reoriented hydrides. In addition, it is observed that one tube is less resistant to DHC initiation than the other tube, which may be attributed to the differences in their microstructure and texture. There is a reasonable agreement between the test results and the predictions from the EPZ model.


Author(s):  
Jun Cui ◽  
Gordon K. Shek ◽  
Douglas A. Scarth ◽  
Zhirui Wang

Flaws in Zr-2.5Nb alloy pressure tubes in CANDU nuclear reactors are susceptible to a crack initiation and growth mechanism known as Delayed Hydride Cracking (DHC), which is a repetitive process that involves hydrogen diffusion, hydride precipitation, growth and fracture of the hydrided region at the flaw-tip. In-service flaw evaluation requires an analysis to demonstrate DHC will not initiate from the flaw. The work presented in this paper examines DHC initiation behavior from simulated debris fretting flaws. Groups of cantilever beam specimens containing V-notches with root radii of 15, 30 and 100 μm were prepared from two unirradiated pressure tubes hydrided to a nominal hydrogen concentration of 57 wt. ppm. The specimens were loaded to different stress levels that straddled the threshold value predicted by an engineering model, and subjected to multiple thermal cycles relevant to reactor operating conditions to form hydrides at the flaw-tip. Threshold conditions for DHC initiation were established for the flaw geometries and thermal cycling conditions used in this program. Test results indicate that the susceptibility to DHC initiation was affected by material variability and notch root radius. The results are also compared with model predictions.


Author(s):  
Jun Cui ◽  
Gordon K. Shek ◽  
Douglas A. Scarth ◽  
William K. Lee

Flaws in Zr-2.5 Nb alloy pressure tubes of CANDU nuclear reactors are susceptible to a crack initiation and growth mechanism called Delayed Hydride Cracking (DHC), which is a repetitive process that involves hydrogen diffusion, hydride precipitation, growth of the hydrided region and fracture of the hydrided region at the flaw-tip. The presence of small surface irregularities, or secondary flaws, at the bottom of service-induced fretting flaws in pressure tubes requires an integrity assessment in terms of DHC initiation. Experimental data and analytical modeling are required to predict whether DHC initiation can occur from the secondary flaws. In the present work, an experimental program was carried out to examine the impact of small secondary flaws with sharp radii on DHC initiation from simulated fretting flaws. Groups of cantilever beam specimens containing blunt notches with and without secondary flaws were prepared from unirradiated pressure tube materials hydrided to a nominal concentration of 50 wt ppm hydrogen. The specimens were subjected to multiple thermal cycles to form hydrides at the flaw-tip at different applied stress levels, which straddled the threshold value for DHC initiation. The threshold conditions for DHC initiation were established for different simulated fretting and secondary flaws. The experimental results are compared with predictions from the engineering process-zone DHC initiation model.


Author(s):  
David Cho ◽  
Steven X. Xu ◽  
Douglas A. Scarth ◽  
Gordon K. Shek

Flaws found during in-service inspection of CANDU(1) Zr-2.5Nb pressure tubes include fuel bundle scratches, debris fretting flaws, fuel bundle bearing pad fretting flaws and crevice corrosion flaws. These flaws are volumetric and blunt in nature. Crack initiation from in-service flaws can be caused by the presence of hydrogen in operating pressure tubes and resultant formation of hydrided regions at the flaw tips during reactor heat-up and cool-down cycles. Zr-2.5Nb pressure tubes in the as-manufactured condition contain hydrogen as an impurity element. During operation, the pressure tube absorbs deuterium, which is a hydrogen isotope, from the corrosion reaction of the zirconium with the heavy water coolant. In addition, deuterium ingresses into the pressure tube in the rolled joint region. The level of hydrogen isotope in pressure tubes increases with operating time. Over the years, Canadian CANDU industry has carried out extensive experimental and analytical programs to develop evaluation procedures for crack initiation from in-service flaws in Zr-2.5Nb pressure tubes. Crack initiation experiments were performed on pressure tube specimens with machined notches to quantify resistance to crack initiation under various simulated flaw geometries and operating conditions such as operating load and hydrogen concentration. Predictive engineering models for crack initiation have been developed based on understandings of crack initiation and experimental data. A set of technical requirements, including engineering procedures and acceptance criteria, for evaluation of crack initiation from in-service flaws in operating pressure tubes has been developed and implemented in the CSA Standard N285.8. A high level review of the development of these flaw evaluation procedures is described in this paper. Operating experience with the application of the developed flaw evaluation procedure is also provided.


Author(s):  
Leonid Gutkin ◽  
Douglas A. Scarth

CANDU(1) Zr-2.5%Nb pressure tubes are susceptible to formation of hydrided regions at the locations of stress concentration, such as in-service flaws. Hydrided region overloads occur when the applied stress acting on a flaw with an existing hydrided region exceeds the stress at which the hydrided region has been formed. The overload events may potentially result in crack initiation and its subsequent growth by the mechanism of delayed hydride cracking. Therefore, evaluating the in-service flaws in the pressure tubes for crack initiation due to hydrided region overloads is required by the Canadian Nuclear Standards, and methodology is being developed to perform such evaluations. As part of this development, the resistance of pressure tube material to crack initiation due to hydrided region overloads was modeled statistically. In the proposed modeling framework, the overload resistance is expressed as a power-law function of the material resistance to initiation of delayed hydride cracking under constant loading. This approach fundamentally relies on the concept of a dual process zone introduced by E. Smith, as discussed in the paper. Both the overload crack initiation coefficient and the overload crack initiation exponent vary with the flaw geometry. The overload crack initiation coefficient also varies with the extent of stress reduction prior to hydride formation and with the number of non-ratcheting hydride formation thermal cycles. The developed model is suitable for use as a predictive model in probabilistic assessments of CANDU reactor core, and has been proposed for implementation into the scheduled revision (2015) of the Canadian Nuclear Standard CSA N285.8.


Author(s):  
E. Smith

The paper discusses the application of the process zone model to the problem of hydrided region formation and Delayed Hydride Cracking (DHC) in CANDU Zr-Nb pressure tube material. The special characteristics of the process zone approach, as used for the DHC problem, are highlighted, while making comparisons with the way in which it is more generally applied in other engineering situations.


Author(s):  
Cheng Liu ◽  
Douglas Scarth ◽  
Alain Douchant

Flaws found during in-service inspection of CANDU Zr-2.5Nb pressure tubes include fuel bundle scratches, debris fretting flaws, fuel bundle bearing pad fretting flaws, mechanical damage flaws and crevice corrosion marks. The CSA Standard N285.8 contains procedures and acceptance criteria for evaluation of the structural integrity of CANDU Zr-2.5Nb pressure tubes containing flaws. One of the requirements is to evaluate the flaws for fatigue crack initiation. There was a need to develop a statistical-based model of fatigue crack initiation at flaws for use in deterministic and probabilistic assessments of Zr-2.5Nb pressure tubes. A number of fatigue crack initiation experiments have been performed on notched specimens from irradiated and unirradiated Zr-2.5Nb pressure tube material with a range of hydrogen equivalent concentrations. These experiments were performed in an air environment and included temperature and load rise time as test parameters. The test data has been used to develop a statistical-based model of fatigue crack initiation at flaws that covers the effects of flaw root radius, load rise time and irradiation. This paper describes the development of the statistical-based model.


2003 ◽  
Vol 17 (08n09) ◽  
pp. 1587-1593 ◽  
Author(s):  
Sang Log Kwak ◽  
Joon Seong Lee ◽  
Young Jin Kim ◽  
Youn Won Park

In the CANDU nuclear reactor, pressure tubes of cold-worked Zr-2.5Nb material are used in the reactor core to contain the nuclear fuel bundles and heavy water coolant. Pressure tubes are major component of nuclear reactor, but only selected samples are periodically examined due to numerous numbers of tubes. Pressure tube material gradually pick up deuterium, as such are susceptible to a crack initiation and propagation process called delayed hydride cracking (DHC), which is the characteristic of pressure tube integrity evaluation. If cracks are not detected, such a cracking mechanism could lead to unstable rupture of the pressure tube. Up to this time, integrity evaluations are performed using conventional deterministic approaches. So it is expected that the results obtained are too conservative to perform a rational evaluation of lifetime. In this respect, a probabilistic safety assessment method is more appropriate for the assessment of overall pressure tube safety. This paper describes failure criteria for probabilistic analysis and fracture mechanics analyses of the pressure tubes in consideration of DHC. Major input parameters such as initial hydrogen concentration, the depth and aspect ratio of an initial surface crack, DHC velocity and fracture toughness are considered as probabilistic variables. Failure assessment diagram of pressure tube material is proposed and applied in the probabilistic analysis. In all the analyses, failure probabilities are calculated using the Monte Carlo simulation. As a result of analysis, conservatism of deterministic failure criteria is showed.


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