Abstract
In this report the expected rate of buildup of 244Cm in a CANDU neutron flux is evaluated and used to explain cases of high 244Cm in alpha-active samples from Bruce and Pickering Units. It is demonstrated that 244Cm is enriched on the surface of irradiated pressure tubes where it is associated with Zr/Nb activation products. It is further shown, using 94Nb as a fluence monitor, that the 244Cm/(239Pu + 240Pu) ratio for Bruce and Pickering irradiated pressure tube deposits exhibits a power law = 0.0042 (Fluence)3.1982. For non-pressure tube samples, such as feeder pipes, steam generator deposits and PHTS cruds, it is observed that Zr/Nb activation products are also associated with elevated 244Cm activities. Thus, based on the data presented in this report, the inference is that all CANDU Units may be expected to exhibit significant levels of 244Cm activity on PHTS surfaces, both in and out-of-core, with 244Cm/(239Pu + 240Pu) ratios significantly greater than one.