COMPETITIVE REDUCTION OF FERRIHYDRITE AND NONTRONITE AND IMPLICATIONS FOR LACUSTRINE SEDIMENTS

2019 ◽  
Author(s):  
David M. Davis ◽  
◽  
Joshua Malidzo Chidzugwe ◽  
Daniel M. Deocampo
2016 ◽  
Author(s):  
Pål Ringkjøb Nielsen ◽  
◽  
Svein Olaf Dahl ◽  
Henrik Løseth Jansen ◽  
Eivind W.N. Støren

1983 ◽  
Vol 29 (103) ◽  
pp. 515-520
Author(s):  
J. N. J. Visser

Abstract The upper part of a Permo-Carboniferous glacial valley fill along the northern margin of the Karoo Basin includes glacio-lacustrine sediments. During the last glacier advance into the lake, a bedded heterogeneous diamictite facies was deposited and, on glacier retreat, a sequence of deformed siltstones with diamictite lenses and sandstone beds, varved shale and rhythmite shale was laid down. Black carbonaceous mud was deposited during the subsequent marine transgression. According to varve counts, the glacier receded from the valley over a period of 500 to 1 000 years and it is concluded that the overall ice-retreat rate during the Permo-Carboniferous deglaciation was relatively high.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Tetsuichi Takagi ◽  
Ki-Cheol Shin ◽  
Mayumi Jige ◽  
Mihoko Hoshino ◽  
Katsuhiro Tsukimura

AbstractKaolin deposits in the Seto-Tono district, central Japan, were formed by intense kaolinization of lacustrine arkose sediments deposited in small and shallow inland lakes in the late Miocene. Based on mineralogical and stable isotopic (Fe, C, N) studies of Motoyama kaolin deposit in the Seto area, we concluded that it was formed by microbial nitrification and acidification of lacustrine sediments underneath an inland lake. Small amounts of Fe–Ti oxides and Fe-hydroxide in the kaolin clay indicated that iron was oxidized and leached during the kaolinization. The field occurrences indicate that leached ferric iron precipitated on the bottom of the kaolin deposit as limonite crusts, and their significantly fractionated Fe isotope compositions suggest the involvement of microbial activity. The C/N ratios of most of the kaolin clay are distinctly higher than those of modern lacustrine sediment. Although, the possibility of a low-temperature hydrothermal origin of the kaolin deposit cannot be completely ruled out, it is more likely that acidification by dilute nitric acid formed from plant-derived ammonia could have caused the kaolinization, Fe oxidation and leaching. The nitrate-dependent microbial Fe oxidation is consistent with dilute nitric acid being the predominant oxidant.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jeremy McCormack ◽  
Ola Kwiecien

AbstractLakes are sensitive to climate change and their sediments play a pivotal role as environmental recorders. The oxygen and carbon isotope composition (δ18O and δ13C) of carbonates from alkaline lakes is featured in numerous studies attempting a quantitative reconstruction of rainfall, temperature and precipitation-evaporation changes. An often-overlooked challenge consists in the mineralogically mixed nature of carbonates themselves. We document a large variability of carbonate components and their respective distinct δ18O and δ13C values from sediments of Lake Van (Turkey) covering the last 150 kyr. The carbonate inventory consists of primary (1) inorganic calcite and aragonite precipitating in the surface-water, (2) biogenic calcite ostracod valves; and post-depositional phases: (3) dolomite forming in the sediment, and previously overlooked, (4) aragonite encrustations formed rapidly around decaying organic matter. We find a systematic relation between the lithology and the dominant deep-water carbonate phase formed recurrently under specific hydrological conditions. The presence of the different carbonates is never mutually exclusive, and the isotopic composition of each phase forms a distinctive cluster characteristic for the depth and timing of their formation. Our findings stretch the envelope of mechanisms forming lacustrine carbonates and highlight the urge to identify and separate carbonate components prior to geochemical analyses.


1980 ◽  
Vol 17 (11) ◽  
pp. 1454-1461 ◽  
Author(s):  
Rolf W. Mathewes ◽  
John A. Westgate

Ash-grade Bridge River tephra, identified as such on the basis of shard habit, modal mineralogy, and composition of ilmenite, occurs in sedimentary cores from three lakes located to the south of the previously documented plume and necessitates a significant enlargement of the fallout area of that tephra in southwestern British Columbia.These new, more southerly occurrences are probably equivalent to the ~2350 year old Bridge River tephra, although it can be argued from the evidence at hand that the 14C dates and biotite-rich nature support relationship to a slightly earlier Bridge River event.Large differences exist in the 14C age of sediments immediately adjacent to the Bridge River tephra at these three lake sites; maximum ages of 3950 ± 170 years BP (GX-5549) and 3750 ± 210 years BP (I-10041) were obtained at Phair and Fishblue lakes, respectively, whereas the corresponding age at Horseshoe Lake is only 2685 ± 180 years BP (GX-5757). The two older dates are considered to be significantly affected by old carbon contamination for the bedrock locally consists of calcareous sedimentary rocks and the lacustrine sediments are very calcareous. The 14C date from Horseshoe Lake, which occurs in an area of igneous rocks, appears to be only slightly too old relative to the ~2350 year old Bridge River tephra.Well-dated tephra beds, therefore, can be very useful in assessing the magnitude of old carbon errors associated with radiocarbon dates based on limnic sediments. Calcareous gyttja deposits beneath Bridge River tephra within the study area exhibit old carbon errors of the order of 1350–1550 years.


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