In Situ Calorimetric Measurements of the Enthalpy of Oxidation of Methyl Orange in an Aqueous Solution over Titanium Dioxide Photocatalyst

2021 ◽  
Vol 95 (10) ◽  
pp. 2148-2153
Author(s):  
R. R. Mansurov ◽  
S. D. Chernyuk ◽  
A. P. Safronov
Author(s):  
Syed Shahabuddin ◽  
Norazilawati Muhamad Sarih ◽  
Muhammad Afzal Kamboh ◽  
Hamid Rashidi Nodeh ◽  
Sharifah Mohamad

The present investigation highlights the synthesis of polyaniline (PANI) coated graphene oxide doped with SrTiO3 nanocube nanocomposites through facile in-situ oxidative polymerization method for the efficient removal of carcinogenic dyes, namely, the cationic dye methylene blue (MB) and the anionic dye methyl orange (MO). The synthesised nanocomposites were characterised by field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR). The adsorption efficiencies of graphene oxide (GO), PANI homopolymer and SrTiO3 nanocubes-doped nanocomposites were assessed by monitoring the adsorption of methylene blue and methyl orange dyes from aqueous solution. The adsorption efficiency of nanocomposites doped with SrTiO3 nanocubes were found to be of higher magnitude as compared with undoped nanocomposite. Moreover, the nanocomposite with 2 wt% SrTiO3 with respect to graphene oxide demonstrated excellent adsorption behaviour with 99% and 91% removal of MB and MO respectively, in a very short duration of time.


2014 ◽  
Vol 28 (1) ◽  
pp. 9-13 ◽  
Author(s):  
Seema Singh ◽  
Aniket Chaki ◽  
Devesh Pratap Chand ◽  
Avinash Raghuwanshi ◽  
Pramod Kumar Singh ◽  
...  

The commercialization of titanium dioxide-based heterogeneous photocatalysis continues to suffer from various limitations, the major shortcoming being the costly and time consuming post-treatment separation of very fine titanium dioxide particles. In order to eliminate this major hindrance, immobilization of titanium dioxide particles on various substrates continues to be an active area of research. In this work, polystyrene-supported titanium dioxide photocatalyst was prepared using a facile method. The photocatalytic activity of the developed photocatalysts was investigated by photodegradation of aqueous solutions of methylene blue andmethyl orange dyes under UV light for 24 h under non-stirred conditions. The recovery and reuse of the prepared photocatalysts was also investigated. The maximum percentage degradation of methyl orange and methylene blue dyes by the developed photocatalysts was found to be around 60 % and 66 % respectively. The ease of separation after use in addition to a facile, low cost-based method of fabrication and appreciable photocatalytic activity of the developed photocatalyst makes it a promising candidate to be explored further for large scale applications.DOI: http://dx.doi.org/10.3329/jce.v28i1.18103 Journal of Chemical Engineering, Vol. 28, No. 1, December 2013: 9-13 


Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 208
Author(s):  
Ramona B. J. Ihlenburg ◽  
Anne-Catherine Lehnen ◽  
Joachim Koetz ◽  
Andreas Taubert

New cryogels for selective dye removal from aqueous solution were prepared by free radical polymerization from the highly water-soluble crosslinker N,N,N’,N’-tetramethyl-N,N’-bis(2-ethylmethacrylate)-propyl-1,3-diammonium dibromide and the sulfobetaine monomer 2-(N-3-sulfopropyl-N,N-dimethyl ammonium)ethyl methacrylate. The resulting white and opaque cryogels have micrometer sized pores with a smaller substructure. They adsorb methyl orange (MO) but not methylene blue (MB) from aqueous solution. Mixtures of MO and MB can be separated through selective adsorption of the MO to the cryogels while the MB remains in solution. The resulting cryogels are thus candidates for the removal of hazardous organic substances, as exemplified by MO and MB, from water. Clearly, it is possible that the cryogels are also potentially interesting for removal of other compounds such as pharmaceuticals or pesticides, but this must be investigated further.


1995 ◽  
Vol 66 (21) ◽  
pp. 2912-2913 ◽  
Author(s):  
M. Davison ◽  
K. P. O’Donnell ◽  
U. M. Noor ◽  
D. Uttamchandani ◽  
L. E. A. Berlouis

RSC Advances ◽  
2021 ◽  
Vol 11 (33) ◽  
pp. 20486-20497
Author(s):  
Zhiyan Liu ◽  
Rui Ma ◽  
Wenjie Du ◽  
Gang Yang ◽  
Tao Chen

Chitosan hydrogel is regenerated from alkali/urea aqueous solution and the lithium sulfonate second network is introduced by electron beam radiation-initiated in situ free radical polymerization. The freeze-dried aerogel has CO2 capture capacity.


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