Single and competitive hydrodesulphurization of thiophene and benzo[b]thiophene on molybdenum catalysts

1981 ◽  
Vol 46 (9) ◽  
pp. 2185-2196 ◽  
Author(s):  
Pavel Pokorný ◽  
Miroslav Zdražil

The reactivity of benzo[b]thiophene and thiophene and the amount of 2,3-dihydrobenzo[b]thiophene and tetrahydrothiophene in the title reaction on sulphided Co-Mo-Al2O3 and MoS2 catalysts has been determined at the temperature range 543-623 K and hydrogen pressures 0.5-2.0 MPa in a tubular flow integral reactor. Under above conditions, benzo[b]thiophene was more reactive than thiophene and the difference in their reactivities in the competitive reaction was substantially greater than in the single reaction. The selectivity to the intermediate 2,3-dihydrobenzo[b]thiophene and tetrahydrothiophene in the reaction of benzo[b]thiophene and thiophene respectively, was measured in the whole region of total conversion. Based on these and reported data, the mechanism of hydrodesulphurization is discussed.

1980 ◽  
Vol 45 (3) ◽  
pp. 697-702 ◽  
Author(s):  
Vlastimil Vyskočil ◽  
Miroslav Zdražil

Kinetics of isomerisation of cyclohexene to methylcyclopentene proceeding as parallel reaction to hydrogenation of cyclohexene to cyclohexane on cobalt-molybdenum catalysts of different composition has been measured. The surface acidity of these catalysts was estimated from the difference in the adsorption of toluene and heptane which was measured by chromatographic method. In a series of catalysts containing molybdenum the acidity parallels isomerisation activity. Cobalt on alumina catalysts and alumina itself have greater acidity but exhibit lower isomerisation activity compared to the catalysts containing molybdenum.


1989 ◽  
Vol 54 (8) ◽  
pp. 2054-2063 ◽  
Author(s):  
Jiří Čejka ◽  
Ludmila Kubelková ◽  
Pavel Jírů

Acetone transformation catalyzed by HZSM-5 and NaZSM-5 zeolites and by zeolites modified with basic oxides was studied in an integral reactor at a temperature of 350 °C. Modification of acido-basic properties of ZSM-5 zeolites resulted both in the total conversion changes and in the essential changes in the product composition. Isobutene was found to be the main product over HZSM-5 zeolites exhibiting low activity, while aromatics prevailed when high conversion level was attained. Classical condensation of acetone yielding mesityloxide and phorones was observed over NaZSM-5 zeolites impregnated with CaO and ZnO.


1992 ◽  
Vol 57 (4) ◽  
pp. 869-881 ◽  
Author(s):  
Italo Ferino ◽  
Roberto Monaci ◽  
Vincenzo Solinas ◽  
Lucio Forni ◽  
Antonio Rivoldini ◽  
...  

The behaviour of several zeolites as catalysts for the title reaction has been investigated by means of a continuous flow microreactor. Runs performed at atmospheric pressure indicated that at 423 K the completely protonic forms of the zeolites catalyze just the isomerization reaction. In the case of Y zeolites, oligomerization occurs only over the partially decationated samples, in the temperature range between 373 and 423 K and W/F between 0.2 and 22 gcath/g1-but, to an extent which depends on the reaction conditions. Most of the catalysts were tested also under pressure (4.05 MPa) at 423 K. The protonic forms of Y and ZSM-5 zeolites seem promising catalysts in terms of both conversion and selectivity to oligomers. The 1-olefins account for 30% of the entire olefinic mixture. The octenes, which account for 70% of the liquid mixture, are mostly formed of dimethylhexenes. Trimers are also formed during the reaction and, in the very particular case of H[B]ZSM-5, tetramers are produced.


Materials ◽  
2019 ◽  
Vol 12 (8) ◽  
pp. 1201 ◽  
Author(s):  
Yan ◽  
Mao ◽  
Zhong ◽  
Zhang ◽  
Zhang

In this research, the durability of skid resistance during the ice melting process with temperature increasing from −5 °C to 10 °C was characterized by means of a British Pendulum Skid Tester. Four types of pavement surfaces were prepared and tested. The difference between two antiskid layers prepared with bitumen emulsion was the aggregate. The detailed angularity and form 2D index of fine aggregates used for antiskid surfaces, characterized by means of the Aggregate Image Measure System (AIMS) with micro image analysis methods, were then correlated with British Pendulum Number (BPN) values. Results indicate that skid resistance has the lowest value during the ice-melting process. The investigated antiskid layers can increase the surface friction during icy seasons. In icy conditions, the skid resistance behavior first worsens until reaches the lowest value, and then increases gradually with increasing temperature. Results from ice-melting conditions on four investigated pavement surfaces give the same temperature range where there will be lowest skid resistance. That temperature range is from 3 °C to 5 °C. A thicker ice layer will result in a lower skid resistance property and smaller “lowest BPN”.


Cellulose ◽  
2020 ◽  
Vol 27 (15) ◽  
pp. 8977-8987
Author(s):  
Floriana Coppola ◽  
Alberto Modelli

Abstract The degradation of paper-based materials involves several and complex mechanisms, such as hydrolysis and oxidation. The behaviour of different types of pulps can be very variable. In this study, the difference upon oxidation of contemporary non-recycled and recycled papers, which now constitute a considerable fibre source, is investigated. A 0.015 M potassium periodate solution is used to oxidise five types of paper, two non-recycled and three recycled, for 0.5, 1, 2 and 4 h. The effects of such oxidation treatments are evaluated in terms of carbonyl content and degree of polymerisation (DP). A modified procedure of the Szabolcs’s method and viscometry are used to measure the carbonyl content and DP, respectively. The carbonyl groups are found to increase more rapidly in the recycled papers than in the non-recycled ones. On the contrary, oxidation causes a larger decrease of the DP values in the non-recycled papers, the paper made of pure cellulose being the most sensitive in terms of depolymerisation. The DP values measured for pure cellulose paper are in line with previously reported data. Moreover, in accordance with the Ekenstam equation, the plots of the reciprocal of DP as a function of oxidation time show good linear correlations for all types of paper investigated. Pseudo rate constants are thus calculated from the slopes of these plots, those of the non-recycled papers being found to be higher than those of the recycled papers. Graphic abstract


2019 ◽  
Vol 8 (1) ◽  
pp. 61-76
Author(s):  
Heinz Herrmann

The clear majority of pre-existing work in the published domain of competitive bidding requires large sample sizes for reliable econometric, probabilistic or game-theoretic modelling techniques. Such unrealistic large data requirements have prevented the successful application of bid modelling in managerial practice. This article presents a new predictive analytics method for very small samples of historical bidding data. Requiring as few as nine competitive bid prices for a group of pooled/aggregated competitors over a 30-month period is the standout differentiator of this research from any previously published research. This minimizes the demands on competitive intelligence and, therefore, realistically enables its application in the real world of practice. Maximum likelihood estimations are used to evaluate two new, revolutionary bid strategies against a range of evaluation criteria, taking into account the pricing judgements made by competitors, including a degree of competitive reaction among them. Using off-the-shelf analytics software, a case study of a bidder from the telecommunications infrastructure sector demonstrates how commercial outcomes can be improved substantially: A 400 per cent improvement in win ratio, an 86 per cent increase in contribution margin and 76 per cent revenue growth. In addition, the difference between the submitted bids and the lowest-priced competing bids (which is an opportunity cost, sometimes referred to as the ‘spread’ or ‘money left on the table’), has been reduced to 2 per cent on a total revenue of US$210 million.


1973 ◽  
Vol 28 (6) ◽  
pp. 881-884 ◽  
Author(s):  
R. Lenke ◽  
W. Uebelhack ◽  
A. Klemm

Self-diffusion measurements on molten LiCl in the temperature range 610 °C ≦ ϑ ≦ 760 °C, obtained with a capillary-reservoir technique, result in the expressions D+ = [10.6 + 0.0307 ϑ - 610) ±0.81 × 10-5cm2/s,D_ = [ 5.8 + 0.0117 ϑ - 610) ±0.3] × 10-5cm2/s. These results fit well into the pattern of the other alkali halides. As with these, it is observed that (D + /R T) + (D_/R T) - (Λ/F2) >0, the difference increasing with rising temperature.


2005 ◽  
Vol 237-240 ◽  
pp. 346-351
Author(s):  
Yoshihiro Yamazaki ◽  
Takahiro Iida ◽  
Yoshiaki Iijima ◽  
Yuh Fukai

Self-diffusion coefficient of 95Nb in NbHx alloys (x=0.05,0.25 and 0.3) has been determined in the temperature range from 823 to 1323 K by using a serial sputter-microsectioning technique. The self-diffusion coefficient of Nb in the NbHx alloys are larger than that in Nb, suggesting that vacancies are formed by hydrogen dissolution, that is, the formation of hydrogen-induced vacancies. The value of the pre-exponential factor for the Nb diffusion in the NbH0.05 alloy is five times larger than that in Nb, while the difference in the activation energies between the NbH0.05 alloy and pure Nb is small. The self-diffusion enhancement in the NbH0.05 alloy is mainly caused by lowering in vibrational frequencies of atoms in the immediate neighborhood of hydrogen-induced vacancies.


1968 ◽  
Vol 41 (5) ◽  
pp. 1294-1299 ◽  
Author(s):  
A. N. Gent ◽  
H. Hirakawa

Abstract Rates of growth of single ozone cracks have been measured for vulcanizates of two butyl rubbers over the temperature range of 20-160° C. Over most of this range the rates are quantitatively related to the segmental mobility of the polymer and depend upon temperature in accord with the appropriate form of the WLF relation. The rates are also proportional to the concentration of ozone. It is therefore concluded that diffusion of ozone into the polymer before reaction is the rate-controlling step. This is contrasted with the behavior of butadiene styrene copolymers, for which rates of crack growth are also quantitatively related to the segmental mobility, but the rates are somewhat larger at equivalent mobilities and the dependence upon ozone concentration is smaller. The difference is attributed to different penetration distances before reaction in polymers containing low and high densities of reactive sites.


2018 ◽  
Vol 29 (06) ◽  
pp. 520-532 ◽  
Author(s):  
Jonathan M. Vaisberg ◽  
Paula Folkeard ◽  
John Pumford ◽  
Philipp Narten ◽  
Susan Scollie

AbstractThe real-ear-to-coupler difference (RECD) is an ANSI standardized method for estimating ear canal sound pressure level (SPL) thresholds and assisting in the prediction of real-ear aided responses. It measures the difference in dB between the SPL produced in the ear canal and the SPL produced in an HA-1 2-cc coupler by the same sound source. Recent evidence demonstrates that extended high-frequency bandwidth, beyond the hearing aid bandwidth typically measured, is capable of providing additional clinical benefit. The industry has, in turn, moved toward developing hearing aids and verification equipment capable of producing and measuring extended high-frequency audible output. As a result, a revised RECD procedure conducted using a smaller, 0.4-cc coupler, known as the wideband-RECD (wRECD), has been introduced to facilitate extended high-frequency coupler-based measurements up to 12.5 kHz.This study aimed to (1) compare test–retest repeatability between the RECD and wRECD and (2) measure absolute agreement between the RECD and wRECD when both are referenced to a common coupler.RECDs and wRECDs were measured bilaterally in adult ears by calculating the dB difference in SPL between the ear canal and coupler responses. Real-ear probe microphone measures were completed twice per ear per participant for both foam-tip and customized earmold couplings using the Audioscan Verifit 1 and Verifit 2 fitting systems, followed by measurements in the respective couplers.Twenty-one adults (mean age = 67 yr, range = 19–78) with typical aural anatomy (as determined by measures of impedance and otoscopy) participated in this study, leading to a sample size of 42 ears.Repeatability within RECD and wRECD was assessed for each coupling configuration using a repeated-measures analysis of variance (ANOVA) with test–retest and frequency as within-participants factors. Repeatability between the RECD and wRECD was assessed within each configuration using a repeated-measures ANOVA with test–retest, frequency, and coupler type as within-participants factors. Agreement between the RECD and wRECD was assessed for each coupling configuration using a repeated-measures ANOVA with RECD value, coupler type, and frequency as within-participants factors. Post hoc comparisons with Bonferroni corrections were used when appropriate to locate the frequencies at which differences occurred. A 3-dB criterion was defined to locate differences of clinical significance.Average absolute test–retest differences were within ±3 dB within each coupler and coupling configuration, and between the RECD and wRECD. The RECD and wRECD were in absolute agreement following HA-1-referenced transforms, with most frequencies agreeing within ±1 dB, except at 0.2 kHz for the earmold, and 0.2–0.25 kHz for the foam tip, where the average RECD exceeded the average wRECD by slightly >3 dB.Test–retest repeatability of the RECD (up to 8 kHz) and wRECD (up to 12.5 kHz) is acceptable and similar to previously reported data. The RECD and wRECD are referenced to different couplers, but can be rendered comparable with a simple transform, producing values that are in accordance with the ANSI S3.46-2013 standard.


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