Emplacement and differentiation of an Archean subvolcanic metapyroxenite–metagabbro sill in the Favourable Lake area, northwestern Ontario

1982 ◽  
Vol 19 (4) ◽  
pp. 837-858 ◽  
Author(s):  
M. Raudsepp ◽  
L. D. Ayres
Keyword(s):  
Titanium Oxide ◽  
Country Rock ◽  
Tholeiitic Basalt ◽  
Lake Area ◽  
Initial Composition ◽  
Northwestern Ontario ◽  
Volcanic Processes ◽  
Facies Metamorphism ◽  
Metasedimentary Sequence

A sequence of five fractionated, subvolcanic, pyroxenite–gabbro sills of tholeiitic basalt initial composition was intruded into the Archean Favourable Lake metavolcanic–metasedimentary sequence. Individual sills are up to 2.7 km long, range in thickness from 17 to 240 m, and are confined to a relatively thin lacustrine metachert and fine clastic unit. The sills were emplaced sequentially upward into water-rich, unlithified country rocks, with succeeding sills being emplaced prior to final consolidation of underlying sills. Sills are either in contact or separated by thin country-rock septa, but later sills did not intrude earlier sills.Greenschist facies metamorphism and pre-metamorphism alteration have destroyed primary mineralogy and have modified chemical variations, but primary textures are well preserved by pseudomorphs. Each sill comprises a lower ultramafic zone of clinopyroxene–olivine and clinopyroxene–orthopyroxene cumulates and an upper mafic zone of clinopyroxene–plagioclase – iron–titanium oxide and plagioclase – iron–titanium oxide cumulates. The upper part of the mafic zone is largely cumulus plagioclase that either accumulated in situ or floated upwards. The lower part of the ultramafic zone is relatively constant in composition and crystallization appears to have been largely in a closed system with only local magma flowage. In the mafic zone, crystallization was apparently in a more open system with surges of magma related to volcanic processes being derived either from elsewhere in the sills or externally. The most fractionated component is granophyric gabbro that is locally concentrated into large intrusive lenses.

In situ growth of SrTiO3 thin films prepared by AACVD from strontium and titanium oxide bisdipivaloylmethanates

1997 ◽  
Vol 101-103 (1-2) ◽  
pp. 183-190 ◽  
Author(s):  
J Peña
Keyword(s):  
Thin Films ◽  
Titanium Oxide ◽  
In Situ Growth

scholarly journals Rapid alteration of fractured volcanic conduits beneath Mt Unzen

2021 ◽  
Vol 83 (5) ◽  
Author(s):  
Tim I. Yilmaz ◽  
Fabian B. Wadsworth ◽  
H. Albert Gilg ◽  
Kai-Uwe Hess ◽  
Jackie E. Kendrick ◽  
...  
Keyword(s):  
Country Rock ◽  
Geophysical Methods ◽  
Hydrothermal Fluids ◽  
Deep Drilling ◽  
Stress Regime ◽  
Argillic Alteration ◽  
Carbon And Oxygen Isotope ◽  
Propylitic Alteration ◽  
Indirect Information

AbstractThe nature of sub-volcanic alteration is usually only observable after erosion and exhumation at old inactive volcanoes, via geochemical changes in hydrothermal fluids sampled at the surface, via relatively low-resolution geophysical methods or can be inferred from erupted products. These methods are spatially or temporally removed from the real subsurface and thus provide only indirect information. In contrast, the ICDP deep drilling of the Mt Unzen volcano subsurface affords a snapshot into the in situ interaction between the dacitic dykes that fed dome-forming eruptions and the sub-volcanic hydrothermal system, where the most recent lava dome eruption occurred between 1990 and 1995. Here, we analyse drill core samples from hole USDP-4, constraining their degree and type of alteration. We identify and characterize two clay alteration stages: (1) an unusual argillic alteration infill of fractured or partially dissolved plagioclase and hornblende phenocryst domains with kaolinite and Reichweite 1 illite (70)-smectite and (2) propylitic alteration of amphibole and biotite phenocrysts with the fracture-hosted precipitation of chlorite, sulfide and carbonate minerals. These observations imply that the early clay-forming fluid was acidic and probably had a magmatic component, which is indicated for the fluids related to the second chlorite-carbonate stage by our stable carbon and oxygen isotope data. The porosity in the dyke samples is dominantly fracture-hosted, and fracture-filling mineralization is common, suggesting that the dykes were fractured during magma transport, emplacement and cooling, and that subsequent permeable circulation of hydrothermal fluids led to pore clogging and potential partial sealing of the pore network on a timescale of ~ 9 years from cessation of the last eruption. These observations, in concert with evidence that intermediate, crystal-bearing magmas are susceptible to fracturing during ascent and emplacement, lead us to suggest that arc volcanoes enclosed in highly fractured country rock are susceptible to rapid hydrothermal circulation and alteration, with implications for the development of fluid flow, mineralization, stress regime and volcanic edifice structural stability. We explore these possibilities in the context of alteration at other similar volcanoes.

A flexible lead-free piezoelectric nanogenerator based on vertically aligned BaTiO3 nanotube arrays on a Ti-mesh substrate

RSC Advances ◽  
2016 ◽  
Vol 6 (84) ◽  
pp. 81426-81435 ◽  
Author(s):  
Ermias Libnedengel Tsege ◽  
Gyu Han Kim ◽  
Venkateswarlu Annapureddy ◽  
Beomkeun Kim ◽  
Hyung-Kook Kim ◽  
...  
Keyword(s):  
Low Temperature ◽  
Titanium Oxide ◽  
Hydrothermal Process ◽  
Lead Free ◽  
Nanotube Arrays ◽  
Titanium Oxide Nanotubes ◽  
Vertically Aligned ◽  
Ti Mesh

A novel, flexible lead-free piezoelectric nanogenerator was developed using a uniform BaTiO3 film; synthesized by in situ conversion of titanium oxide nanotubes in a low temperature hydrothermal process.

scholarly journals Temporal Variation of Chlorophyll-a Concentrations in Highly Dynamic Waters from Unattended Sensors and Remote Sensing Observations

Sensors ◽  
2018 ◽  
Vol 18 (8) ◽  
pp. 2699 ◽  
Author(s):  
Jian Li ◽  
Liqiao Tian ◽  
Qingjun Song ◽  
Zhaohua Sun ◽  
Hongjing Yu ◽  
...  
Keyword(s):  
Remote Sensing ◽  
Water Quality ◽  
Chlorophyll Fluorescence ◽  
Chlorophyll A ◽  
Temporal Variations ◽  
Lake Area ◽  
Short Term ◽  
Chl A ◽  
Spatio Temporal

Monitoring of water quality changes in highly dynamic inland lakes is frequently impeded by insufficient spatial and temporal coverage, for both field surveys and remote sensing methods. To track short-term variations of chlorophyll fluorescence and chlorophyll-a concentrations in Poyang Lake, the largest freshwater lake in China, high-frequency, in-situ, measurements were collected from two fixed stations. The K-mean clustering method was also applied to identify clusters with similar spatio-temporal variations, using remote sensing Chl-a data products from the MERIS satellite, taken from 2003 to 2012. Four lake area classes were obtained with distinct spatio-temporal patterns, two of which were selected for in situ measurement. Distinct daily periodic variations were observed, with peaks at approximately 3:00 PM and troughs at night or early morning. Short-term variations of chlorophyll fluorescence and Chl-a levels were revealed, with a maximum intra-diurnal ratio of 5.1 and inter-diurnal ratio of 7.4, respectively. Using geostatistical analysis, the temporal range of chlorophyll fluorescence and corresponding Chl-a variations was determined to be 9.6 h, which indicates that there is a temporal discrepancy between Chl-a variations and the sampling frequency of current satellite missions. An analysis of the optimal sampling strategies demonstrated that the influence of the sampling time on the mean Chl-a concentrations observed was higher than 25%, and the uncertainty of any single Terra/MODIS or Aqua/MODIS observation was approximately 15%. Therefore, sampling twice a day is essential to resolve Chl-a variations with a bias level of 10% or less. The results highlight short-term variations of critical water quality parameters in freshwater, and they help identify specific design requirements for geostationary earth observation missions, so that they can better address the challenges of monitoring complex coastal and inland environments around the world.

Ultra-high vacuum chemical vapor deposition and in situ characterization of titanium oxide thin films

1991 ◽  
Vol 6 (9) ◽  
pp. 1913-1918 ◽  
Author(s):  
Jiong-Ping Lu ◽  
Rishi Raj
Keyword(s):  
Thin Films ◽  
Chemical Vapor Deposition ◽  
Titanium Oxide ◽  
Vapor Deposition ◽  
Photoelectron Spectroscopy ◽  
High Vacuum ◽  
Chemical Vapor ◽  
Titanium Isopropoxide ◽  
Ultra High Vacuum

Chemical vapor deposition (CVD) of titanium oxide films has been performed for the first time under ultra-high vacuum (UHV) conditions. The films were deposited through the pyrolysis reaction of titanium isopropoxide, Ti(OPri)4, and in situ characterized by x-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES). A small amount of C incorporation was observed during the initial stages of deposition, through the interaction of precursor molecules with the bare Si substrate. Subsequent deposition produces pure and stoichiometric TiO2 films. Si–O bond formation was detected in the film-substrate interface. Deposition rate was found to increase with the substrate temperature. Ultra-high vacuum chemical vapor deposition (UHV-CVD) is especially useful to study the initial stages of the CVD processes, to prepare ultra-thin films, and to investigate the composition of deposited films without the interference from ambient impurities.

scholarly journals Timing of Paleozoic Exhumation and Deformation of the High-Pressure Vestgӧtabreen Complex at the Motalafjella Nunatak, Svalbard

Minerals ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 125 ◽  
Author(s):  
Christopher J. Barnes ◽  
Katarzyna Walczak ◽  
Emilie Janots ◽  
David Schneider ◽  
Jarosław Majka
Keyword(s):  
High Pressure ◽  
Tectonic Evolution ◽  
Shear Zones ◽  
White Mica ◽  
Strike Slip ◽  
Structural Studies ◽  
Metamorphic Overprint ◽  
Subaerial Exposure ◽  
Facies Metamorphism

The Vestgӧtabreen Complex exposed in the Southwestern Caledonian Basement Province of Svalbard comprises two Caledonian high-pressure units. In situ white mica 40Ar/39Ar and monazite Th-U-total Pb geochronology has resolved the timing of the tectonic evolution of the complex. Cooling of the Upper Unit during exhumation occurred at 476 ± 2 Ma, shortly after eclogite-facies metamorphism. The two units were juxtaposed at 454 ± 6 Ma. This was followed by subaerial exposure and deposition of Bullbreen Group sediments. A 430–400 Ma late Caledonian phase of thrusting associated with major sinistral shearing throughout Svalbard deformed both the complex and the overlying sediments. This phase of thrusting is prominently recorded in the Lower Unit, and is associated with a pervasive greenschist-facies metamorphic overprint of high-pressure lithologies. A c. 365–344 Ma geochronological record may represent an Ellesmerian tectonothermal overprint. Altogether, the geochronological evolution of the Vestgӧtabreen Complex, with previous petrological and structural studies, suggests that it may be a correlative to the high-pressure Tsäkkok Lens in the Scandinavian Caledonides. It is suggested that the Vestgӧtabreen Complex escaped to the periphery of the orogen along the sinistral strike-slip shear zones prior to, or during the initial stages of continental collision between Baltica and Laurentia.

Calciothermic reduction of titanium oxide and in-situ electrolysis in molten CaCl2

2003 ◽  
Vol 34 (3) ◽  
pp. 287-295 ◽  
Author(s):  
Ryosuke O. Suzuki ◽  
Katsutoshi Ono ◽  
Koh Teranuma
Keyword(s):  
Titanium Oxide ◽  
Calciothermic Reduction

Archean rocks from the eastern Lac Seul region of the English River Gneiss Belt, northwestern Ontario, part 1. Petrology, chemistry, and metamorphism

1976 ◽  
Vol 13 (9) ◽  
pp. 1201-1211 ◽  
Author(s):  
N. B. W. Harris ◽  
A. M. Goodwin
Keyword(s):  
Complex Structure ◽  
Granulite Facies ◽  
Metamorphic Grade ◽  
Amphibolite Facies ◽  
Northwestern Ontario ◽  
Southern Margin ◽  
Field Evidence ◽  
Facies Metamorphism

The eastern Lac Seul region of the English River Gneiss Belt is divided into two domains defined by contrasting petrology and structure. The northern domain is underlain by east-trending, steeply south-dipping, migmatized metasediments, intruded by occasional granite sills, and the southern domain by gneissic tonalite and trondhjemite, with abundant amphibolite inclusions, intruded by granite dykes and diapirs: this domain has a complex structure with gently east-plunging open folds of about 5 km wavelength. Field evidence suggests that metasediments of the northern domain have been deposited on the tonalite trondhjemite basement, which was subsequently mobilized, thereby producing the steeply dipping paragneiss belt of the northern domain.The grade of metamorphism throughout the region lies in the upper amphibolite facies, rising locally to the granulite facies. Within 15 km of the southern margin of the gneiss belt, the metamorphic grade decreases to the greenschist facies.U–Pb dating of zircons indicates that the tonalite gneiss was emplaced at least 3040 m.y. ago, and the granite plutons at 2660 m.y., coeval with migmatization and upper amphibolite facies metamorphism. Late pegmatites were emplaced at 2560 m.y.

Synthesis of Ultra-Thin Superhydrophilic Titanium Oxide Film and its Effects on the Capillary of Microchannels

2010 ◽  
Author(s):  
Min Zhang ◽  
Bo Zhang ◽  
Tianhong Cui
Keyword(s):  
Titanium Oxide ◽  
Sol Gel ◽  
Nitrogen Atmosphere ◽  
Tio2 Films ◽  
Titanium Tetraisopropoxide ◽  
X Ray Diffraction ◽  
Before And After ◽  
Potential Applications ◽  
Temperature Surface

Ultra-thin superhydrophilic titanium oxide films were fabricated on silicon microchannels by an in situ reaction sol-gel method using titanium tetraisopropoxide as a starting material.. By changing the concentration of water in ethanol and reaction time, the thickness of synthesized TiO2 films can be controlled from around 10 nm to 80 nm. The contact angle of as-synthesized TiO2 films on flat silicon is around 20° and can be further decreased to zero by calcination at 700 °C in nitrogen atmosphere. X-ray diffraction spectra show the microstructure of the TiO2 films changed gradually from amorphous to anatase with the increase of calcination temperature. Surface morphology of the film before and after calcination also shows that a smoother coating with crystal structure was obtained by heat treatment. The flow velocity in the TiO2 coated channel reached around 0.03 m/s, almost ten times of that in PDDA/PSS coated channel and 4 times of that in SiO2 coated one. The ultra-thin superhydrophilic TiO2 films fabricated by this method show the ability to strongly increase the wettability of microchannels without affecting the morphology of the sidewall of the channels, indicating potential applications to biomolecule analysis and surface tension driven microfluidic systems.

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