Amphibole in a spinel lherzolite xenolith: evidence for volatiles and partial melting in the upper mantle beneath southern British Columbia

1984 ◽  
Vol 21 (9) ◽  
pp. 1067-1072 ◽  
Author(s):  
Mark Brearley ◽  
Christopher M. Scarfe
Keyword(s):  
British Columbia ◽  
Partial Melting ◽  
Upper Mantle ◽  
Stability Field ◽  
Spinel Lherzolite ◽  
Ultramafic Xenolith ◽  
Metasomatic Fluid ◽  
Small Grains ◽  
First Time

Pargasitic amphibole has been observed for the first time in an ultramafic xenolith from British Columbia. The xenolith is a chrome diopside-bearing spinel lherzolite trapped within an alkali basaltic lava flow at Lightning Peak, near Vernon, British Columbia. Amphibole (<5%) occurs within the xenolith as small grains, interstitial between other xenolith mineral phases, and always shows evidence of melting. Microprobe analyses of the amphibole reveal that it is a pargasite rich in MgO (MgO = 17.1–17.7 wt.%; Mg/(Mg + Fe2+) = 0.89) and CaO (10.4–10.7 wt.%). Textural and chemical evidence suggests that the pargasite is in equilibrium with the other phases in spinel lherzolite. The pargasite probably crystallized within the spinel stability field of the upper mantle from a volatile-rich metasomatic fluid that was produced by dehydration of subducted material. Melting in the amphibole may have been caused by one of three processes: superheating by the host alkali basalt, decompression as the magma ascended, or by in situ partial melting within the upper mantle. The partial melting of amphibole-bearing spinel lherzolite provides a possible mechanism for the generation of late Cenozoic alkalic magmas of the Intermontane Belt of British Columbia.

Petrology of ultramafic xenoliths from Rayfield River, south-central British Columbia

1987 ◽  
Vol 24 (8) ◽  
pp. 1679-1687 ◽  
Author(s):  
Dante Canil ◽  
Mark Brearley ◽  
Christopher M. Scarfe
Keyword(s):  
British Columbia ◽  
Phase Equilibrium ◽  
Partial Melting ◽  
Upper Mantle ◽  
Mantle Xenoliths ◽  
Spinel Lherzolite ◽  
Equilibrium Constraints ◽  
Host Magma ◽  
South Central ◽  
Ultramafic Xenoliths

One hundred mantle xenoliths were collected from a hawaiite flow of Miocene–Pliocene age near Rayfield River, south-central British Columbia. The massive host hawaiite contains subrounded xenoliths that range in size from 1 to 10 cm and show protogranular textures. Both Cr-diopside-bearing and Al-augite-bearing xenoliths are represented. The Cr-diopside-bearing xenolith suite consists of spinel lherzolite (64%), dunite (12%), websterite (12%), harzburgite (9%), and olivine websterite (3%). Banding and veining on a centimetre scale are present in four xenoliths. Partial melting at the grain boundaries of clinopyroxene is common and may be due to natural partial melting in the upper mantle, heating by the host magma during transport, or decompression during ascent.Microprobe analyses of the constituent minerals show that most of the xenoliths are well equilibrated. Olivine is Fo89 to Fo92, orthopyroxene is En90, and Cr diopside is Wo47En48Fs5. More Fe-rich pyroxene compositions are present in some of the websterite xenoliths. The Mg/(Mg + Fe2+) and Cr/(Cr + Al + Fe3+) ratios in spinel are uniform in individual xenoliths, but they vary from xenolith to xenolith. Equilibration temperatures for the xenoliths are 860–980 °C using the Wells geothermometer. The depth of equilibration estimated for the xenoliths using geophysical and phase equilibrium constraints is 30–40 km.

Geochemistry of ultramafic xenoliths and their host alkali basalts from Tallante, southern Spain

1986 ◽  
Vol 50 (356) ◽  
pp. 231-239 ◽  
Author(s):  
C. Dupuy ◽  
J. Dostal ◽  
P. A. Boivin
Keyword(s):  
Upper Mantle ◽  
Mantle Metasomatism ◽  
Southern Spain ◽  
Stability Field ◽  
Spinel Lherzolite ◽  
Alkali Basalts ◽  
Spinel Lherzolites ◽  
Ultramafic Xenoliths ◽  
Liquid Segregation ◽  
Garnet Stability Field

AbstractUltramafic xenoliths enclosed in Plio-Quaternary alkali basalts from Tallante near Cartagne (southern Spain) are composed mainly of spinel lherzolites which are probably upper mantle residues. In many xenoliths, the spinel lherzolite is cut by pyroxenite or gabbroic anorthosite veinlets generally 0.2–3 cm thick. The clinopyroxenite veinlets were formed by high-pressure crystal-liquid segregation from alkali basalt magmas formed earlier than the host basalts, whereas mantle metasomatism played a role in the genesis of gabbroic anorthosites. Close to the contact with the veinlets, the spinel lherzolites are enriched in Ca, Fe, and some incompatible elements including light REE due to the migration of a fluid from the veinlets into the surrounding lherzolites. The host alkali basalts were derived from a heterogeneous, incompatible element-enriched upper-mantle source probably similar in composition and nature to the composite xenoliths, but were formed in a garnet stability field.

Proterozoic mantle under Quesnellia: variably reset Rb–Sr mineral isochrons in ultramafic nodules carried up in Cenozoic volcanic vents of the southern Omineca Belt

1991 ◽  
Vol 28 (8) ◽  
pp. 1239-1253 ◽  
Author(s):  
Min Sun ◽  
Richard Lee Armstrong ◽  
R. J. Maxwell
Keyword(s):  
British Columbia ◽  
Upper Mantle ◽  
Isotopic Exchange ◽  
Mantle Lithosphere ◽  
Linear Arrays ◽  
Mid Ocean Ridge ◽  
Interstitial Material ◽  
Host Rocks ◽  
Ocean Ridge

Handpicked, acid-washed diopside, orthopyroxene, and olivine separates from 14 lherzolite nodules from four localities in southern British Columbia have been analyzed for 87Rb/86Sr and 87Sr/86Sr. The host lavas, of late Cenozoic to Pleistocene age, are nepheline-normative alkali basalt and basanite with Sr and Nd isotopic ratios (0.7025–0.7029; 0.51310–0.51326) close to those of mid-ocean ridge basalt. The present-day Sr isotopic compositions of nodule diopsides (9–239 ppm Sr) are 0.7021–0.7041, similar to those of the host rocks. Orthopyroxene and olivine, however, have 87Rb/86Sr ratios of 0.1 to > 1.0 and much more radiogenic Sr (87Sr/86Sr commonly 0.708–0.720), and in several cases the three minerals form linear arrays in 87Rb/86Sr versus 87Sr/86Sr plots. If interpreted as mineral isochrons, these give dates from 99 to 1989 Ma; many cluster around 440–770 Ma. Four nodules from two localities (West Kettle River and Big Timothy Mountain) give dates of 1201–1989 Ma. Maximum dates for the other localities (Jacques Lake and Lassie Lake) are 600–650 Ma.87Rb/86Sr ratios for acid leaches of crushed and sieved nodule material are generally < 0.706, and 87Sr/86Sr ratios for the host rocks are < 0.703, so radiogenic interstitial material or host contamination cannot explain the high ratios observed in the low-Sr minerals. The acid leaches lie both above and below mineral isochrons, virtually never exactly on the isochrons, indicating that secondary material, not cogenetic with the nodules, is present along grain boundaries. Discordant mineral points lie as expected for partially reset old isochrons, with olivine most easily reequilibrated by Sr isotopic exchange with less radiogenic minerals, orthopyroxene next in changeability, and clinopyroxene least modified.The nodules cannot be cognate or related in any way to recent magma genesis. The radiogenic Sr in low-Sr minerals is due to in situ decay of Rb and thus the nodules are Proterozoic upper mantle, some of an age similar to the 1.7–2.3 Ga granitic basement that tectonically underlies southwestern Quesnellia in the same region containing the nodule-bearing vents. The 440–770 Ma isochrons are speculatively correlated with Late Proterozoic to early Paleozoic craton-margin-forming rift event(s). Pre-Phanerozoic mantle lithosphere extends as far west as the Okanagan Valley in southern British Columbia.

Rare earth element contents and multiple mantle sources of the transform-related Mount Edgecumbe basalts, southeastern Alaska

1994 ◽  
Vol 31 (5) ◽  
pp. 852-864 ◽  
Author(s):  
J. R. Riehle ◽  
J. R. Budahn ◽  
M. A. Lanphere ◽  
D. A. Brew
Keyword(s):  
Rare Earth ◽  
Partial Melting ◽  
Rare Earth Element ◽  
Earth Element ◽  
Olivine Basalt ◽  
Volcanic Field ◽  
Stability Field ◽  
Spinel Lherzolite ◽  
Garnet Lherzolite ◽  
Element Contents

Pleistocene basalt of the Mount Edgecumbe volcanic field (MEF) is subdivided into a plagioclase type and an olivine type. Olivine basalt crops out farther inboard from the nearby Fairweather transform than plagioclase basalt. Th/La ratios of plagioclase basalt are similar to those of mid-ocean-ridge basalt (MORB), whereas those of olivine basalt are of continental affinity. The olivine basalt has higher 87Sr/86Sr ratios than the plagioclase basalt.We model rare earth element (REE) contents of the olivine basalt, which resemble those of transitional MORB, by 10–15% partial melting of fertile spinel–plagioclase lherzolite followed by removal of 8–13% olivine. Normative mineralogy indicates melting in the spinel stability field. REE contents of an undersaturated basalt (sample 5L005) resemble those of Mauna Loa tholeiite and are modelled by 5–10% partial melting of fertile garnet lherzolite followed by 10% olivine removal. Plagioclase basalt resembles sample 5L005 in REE contents but is lower in other incompatible-element contents and 87Sr/86Sr ratios. Plagioclase basalt either originated in depleted garnet lherzolite or is a mixture of sample 5L005 and normal MORB; complex zoning of plagioclase and colinear Sc and Th contents are consistent with magma mixing.We conclude that olivine basalt originated in subcontinental spinel lherzolite and that plagioclase basalt may have originated in suboceanic lithosphere of the Pacific plate. Lithospheric melting seemingly requires vertical flow of mantle material, although there is no direct evidence at the MEF for crustal extension that might provide a mechanism for mantle advection. In any case, most MEF magmas are subalkaline because of moderately high degrees of partial melting at shallow depth.

Magma generation in the upper mantle, field evidence from ophiolite suites, and application to the generation of oceanic lithosphere

1978 ◽  
Vol 288 (1355) ◽  
pp. 527-546 ◽  
Keyword(s):  
Partial Melting ◽  
Oceanic Crust ◽  
Upper Mantle ◽  
Oceanic Lithosphere ◽  
Single Parent ◽  
Spinel Lherzolite ◽  
Mantle Material ◽  
Magma Generation ◽  
Field Evidence ◽  
Lower Series

The Bay of Islands ophiolite may be divided into a lower series of ultramafic tectonites representing mantle material and a higher series of cumulate and extrusive rocks and sediments which may be correlated with oceanic crust. The tectonite series consists of a lower spinel—lherzolite member overlain by harzburgites. Both are cut by numerous olivine-pyroxene veins which represent early crystallization products from a picritic tholeiite magma derived at 18-22 kbar by approximately 23 % partial melting of the spinel lherzolite. The remainder of this magma crystallized as differentiated cumulate and extrusive rocks under crustal conditions. The petrogenetic model derived implies a rising diapiric body beneath an accreting centre and allows for the production of tholeiitic, transitional and mildly alkaline basalts from a single parent. The nature of the basalt erupted depends upon the rate of upwelling and crystallization in the diapir. The model suggests that crystallization takes place in the diapir at depths of less than 60 km.

Probing the Dynamic Self-Assembly Behaviour of Photoswitchable Wormlike Micelles in Real Time

2018 ◽  
Author(s):  
Elaine A. Kelly ◽  
Judith E. Houston ◽  
Rachel Evans
Keyword(s):  
Real Time ◽  
Absorption Spectroscopy ◽  
Self Assembly ◽  
Uv Light ◽  
Wormlike Micelles ◽  
Tetraethylene Glycol ◽  
Light Illumination ◽  
First Time ◽  
Dependent Processes

Understanding the dynamic self-assembly behaviour of azobenzene photosurfactants (AzoPS) is crucial to advance their use in controlled release applications such as<i></i>drug delivery and micellar catalysis. Currently, their behaviour in the equilibrium <i>cis-</i>and <i>trans</i>-photostationary states is more widely understood than during the photoisomerisation process itself. Here, we investigate the time-dependent self-assembly of the different photoisomers of a model neutral AzoPS, <a>tetraethylene glycol mono(4′,4-octyloxy,octyl-azobenzene) </a>(C<sub>8</sub>AzoOC<sub>8</sub>E<sub>4</sub>) using small-angle neutron scattering (SANS). We show that the incorporation of <i>in-situ</i>UV-Vis absorption spectroscopy with SANS allows the scattering profile, and hence micelle shape, to be correlated with the extent of photoisomerisation in real-time. It was observed that C<sub>8</sub>AzoOC<sub>8</sub>E<sub>4</sub>could switch between wormlike micelles (<i>trans</i>native state) and fractal aggregates (under UV light), with changes in the self-assembled structure arising concurrently with changes in the absorption spectrum. Wormlike micelles could be recovered within 60 seconds of blue light illumination. To the best of our knowledge, this is the first time the degree of AzoPS photoisomerisation has been tracked <i>in</i><i>-situ</i>through combined UV-Vis absorption spectroscopy-SANS measurements. This technique could be widely used to gain mechanistic and kinetic insights into light-dependent processes that are reliant on self-assembly.

The Total Synthesis of Rhabdastrellic Acid A

2018 ◽  
Author(s):  
Yaroslav Boyko ◽  
Christopher Huck ◽  
David Sarlah
Keyword(s):  
Total Synthesis ◽  
Late Stage ◽  
Cross Coupling ◽  
Side Chains ◽  
General Strategy ◽  
Modular Approach ◽  
Linear Sequence ◽  
Generating Sequence ◽  
First Time

<div>The first total synthesis of rhabdastrellic acid A, a highly cytotoxic isomalabaricane triterpenoid, has been accomplished in a linear sequence of 14 steps from commercial geranylacetone. The prominently strained <i>trans-syn-trans</i>-perhydrobenz[<i>e</i>]indene core characteristic of the isomalabaricanes is efficiently accessed in a selective manner for the first time through a rapid, complexity-generating sequence incorporating a reductive radical polyene cyclization, an unprecedented oxidative Rautenstrauch cycloisomerization, and umpolung 𝛼-substitution of a <i>p</i>-toluenesulfonylhydrazone with in situ reductive transposition. A late-stage cross-coupling in concert with a modular approach to polyunsaturated side chains renders this a general strategy for the synthesis of numerous family members of these synthetically challenging and hitherto inaccessible marine triterpenoids.</div>

In-situ reaction-replacement origin of hornblendites in the Early Cretaceous Laiyuan complex, North China Craton, and implications for its tectono-magmatic evolution

2021 ◽  
Author(s):  
Jia Chang ◽  
Andreas Audétat ◽  
Jian-Wei Li
Keyword(s):  
Partial Melting ◽  
North China Craton ◽  
Lithospheric Mantle ◽  
Lower Crust ◽  
North China ◽  
Ultramafic Rocks ◽  
Magmatic Evolution ◽  
Mafic Magmas ◽  
Felsic Rocks

Abstract Two suites of amphibole-rich mafic‒ultramafic rocks associated with the voluminous intermediate to felsic rocks in the Early Cretaceous Laiyuan intrusive-volcanic complex (North China Craton) are studied here by detailed petrography, mineral- and melt inclusion chemistry, and thermobarometry to demonstrate an in-situ reaction-replacement origin of the hornblendites. Moreover, a large set of compiled and newly obtained geochronological and whole-rock elemental and Sr-Nd isotopic data are used to constrain the tectono-magmatic evolution of the Laiyuan complex. Early mafic‒ultramafic rocks occur mainly as amphibole-rich mafic‒ultramafic intrusions situated at the edge of the Laiyuan complex. These intrusions comprise complex lithologies of olivine-, pyroxene- and phlogopite-bearing hornblendites and various types of gabbroic rocks, which largely formed by in-situ crystallization of hydrous mafic magmas that experienced gravitational settling of early-crystallized olivine and clinopyroxene at low pressures of 0.10‒0.20 GPa (∼4‒8 km crustal depth); the hornblendites formed in cumulate zones by cooling-driven crystallization of 55‒75 vol% hornblende, 10‒20 vol% orthopyroxene and 3‒10 vol% phlogopite at the expense of olivine and clinopyroxene. A later suite of mafic rocks occurs as mafic lamprophyre dikes throughout the Laiyuan complex. These dikes occasionally contain some pure hornblendite xenoliths, which formed by reaction-replacement of clinopyroxene at high pressures of up to 0.97‒1.25 GPa (∼37‒47 km crustal depth). Mass balance calculations suggest that the olivine-, pyroxene- and phlogopite-bearing hornblendites in the early mafic‒ultramafic intrusions formed almost without melt extraction, whereas the pure hornblendites brought up by lamprophyre dikes required extraction of ≥ 20‒30 wt% residual andesitic to dacitic melts. The latter suggests that fractionation of amphibole in the middle to lower crust through the formation of reaction-replacement hornblendites is a viable way to produce adakite-like magmas. New age constraints suggest that the early mafic-ultramafic intrusions formed during ∼132‒138 Ma, which overlaps with the timespan of ∼126‒145 Ma recorded by the much more voluminous intermediate to felsic rocks of the Laiyuan complex. By contrast, the late mafic and intermediate lamprophyre dikes were emplaced during ∼110‒125 Ma. Therefore, the voluminous early magmatism in the Laiyuan complex was likely triggered by the retreat of the flat-subducting Paleo-Pacific slab, whereas the minor later, mafic to intermediate magmas may have formed in response to further slab sinking-induced mantle thermal perturbations. Whole-rock geochemical data suggest that the early mafic magmas formed by partial melting of subduction-related metasomatized lithospheric mantle, and that the early intermediate to felsic magmas with adakite-like signatures formed from mafic magmas through strong amphibole fractionation without plagioclase in the lower crust. The late mafic magmas seem to be derived from a slightly different metasomatized lithospheric mantle by lower degrees of partial melting.

scholarly journals Engineered Phage Endolysin Eliminates Gardnerella Biofilm without Damaging Beneficial Bacteria in Bacterial Vaginosis Ex Vivo

Pathogens ◽  
2021 ◽  
Vol 10 (1) ◽  
pp. 54
Author(s):  
Christine Landlinger ◽  
Lenka Tisakova ◽  
Vera Oberbauer ◽  
Timo Schwebs ◽  
Abbas Muhammad ◽  
...  
Keyword(s):  
Bacterial Vaginosis ◽  
Bactericidal Activity ◽  
High Selectivity ◽  
Ex Vivo ◽  
Vaginal Microbiome ◽  
Wild Type ◽  
Wild Type Enzyme ◽  
Promising Alternative ◽  
First Time

Bacterial vaginosis is characterized by an imbalance of the vaginal microbiome and a characteristic biofilm formed on the vaginal epithelium, which is initiated and dominated by Gardnerella bacteria, and is frequently refractory to antibiotic treatment. We investigated endolysins of the type 1,4-beta-N-acetylmuramidase encoded on Gardnerella prophages as an alternative treatment. When recombinantly expressed, these proteins demonstrated strong bactericidal activity against four different Gardnerella species. By domain shuffling, we generated several engineered endolysins with 10-fold higher bactericidal activity than any wild-type enzyme. When tested against a panel of 20 Gardnerella strains, the most active endolysin, called PM-477, showed minimum inhibitory concentrations of 0.13–8 µg/mL. PM-477 had no effect on beneficial lactobacilli or other species of vaginal bacteria. Furthermore, the efficacy of PM-477 was tested by fluorescence in situ hybridization on vaginal samples of fifteen patients with either first time or recurring bacterial vaginosis. In thirteen cases, PM-477 killed the Gardnerella bacteria and physically dissolved the biofilms without affecting the remaining vaginal microbiome. The high selectivity and effectiveness in eliminating Gardnerella, both in cultures of isolated strains as well as in clinically derived samples of natural polymicrobial biofilms, makes PM-477 a promising alternative to antibiotics for the treatment of bacterial vaginosis, especially in patients with frequent recurrence.

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