Les équations cinétiques pour les systèmes réactifs. Initiation photochimique et thermique. Les coefficients de vitesse

1982 ◽  
Vol 60 (16) ◽  
pp. 2151-2158 ◽  
Author(s):  
Juan Veguillas ◽  
Miguel Angel Diaz Armentia ◽  
Angel Maria Gutierrez Terron

In a previous publication a method was developed for obtaining kinetic equations for a reacting system. In this publication that method is applied to a system [Formula: see text] whose initiation is a photodissociation. The reactive Hamiltonian has been found through Tani's generalized transformation. The generalized kinetic equation has been used. The cluster expansion of the collision superoperator has been obtained from the cluster expansion of the resolvent superoperator, by assuming that collisions are instantaneous. The generalized Boltzmann equations have been obtained. From the kinetic equations we have found the master equations and from them the rate coefficients have been identified.


Fluids ◽  
2018 ◽  
Vol 4 (1) ◽  
pp. 2 ◽  
Author(s):  
David Andrade ◽  
Raphael Stuhlmeier ◽  
Michael Stiassnie

This article is concerned with the non-linear interaction of homogeneous random ocean surface waves. Under this umbrella, numerous kinetic equations have been derived to study the evolution of the spectral action density, each employing slightly different assumptions. Using analytical and numerical tools, and providing exact formulas, we demonstrate that the recently derived generalized kinetic equation exhibits blow up in finite time for certain degenerate quartets of waves. This is discussed in light of the assumptions made in the derivation, and this equation is contrasted with other kinetic equations for the spectral action density.



1974 ◽  
Vol 11 (3) ◽  
pp. 377-387 ◽  
Author(s):  
R. Balescu ◽  
J. H. Misguich

The general theory developed in part 1 is illustrated for a plasma described by the weak-coupling (Landau) approximation. The kinetic equation, valid for arbitrarily strong external fields, is written out explicitly.



2021 ◽  
Vol 10 (5) ◽  
pp. 2593-2610
Author(s):  
Wagdi F.S. Ahmed ◽  
D.D. Pawar ◽  
W.D. Patil

In this study, a new and further generalized form of the fractional kinetic equation involving the generalized V$-$function has been developed. We have discussed the manifold generality of the generalized V$-$function in terms of the solution of the fractional kinetic equation. Also, the graphical interpretation of the solutions by employing MATLAB is given. The results are very general in nature, and they can be used to generate a large number of known and novel results.



1967 ◽  
Vol 45 (11) ◽  
pp. 3555-3567 ◽  
Author(s):  
R. A. Elliott ◽  
Luis de Sobrino

A classical gas whose particles interact through a weak long-range attraction and a strong short-range repulsion is studied. The Liouville equation is solved as an infinite-order perturbation expansion. The terms in this series are classified by Prigogine-type diagrams according to their order in the ratio of the range of the interaction to the average interparticle distance. It is shown that, provided the range of the short-range force is much less than the average interparticle distance which, in turn, is much less than the range of the long-range force, the terms can be grouped into two classes. The one class, represented by chain diagrams, constitutes the significant contributions of the short-range interaction; the other, represented by ring diagrams, makes up, apart from a self-consistent field term, the significant contributions from the long-range force. These contributions are summed to yield a kinetic equation. The orders of magnitude of the terms in this equation are compared for various ranges of the parameters of the system. Retaining only the dominant terms then produces a set of eight kinetic equations, each of which is valid for a definite range of the parameters of the system.



2021 ◽  
Author(s):  
Sergei Annenkov ◽  
Victor Shrira ◽  
Leonel Romero ◽  
Ken Melville

<p>We consider the evolution of directional spectra of waves generated by constant and changing wind, modelling it by direct numerical simulation (DNS), based on the Zakharov equation. Results are compared with numerical simulations performed with the Hasselmann kinetic equation and the generalised kinetic equation, and with airborne measurements of waves generated by offshore wind, collected during the GOTEX experiment off the coast of Mexico. Modelling is performed with wind measured during the experiment, and the initial conditions are taken as the observed spectrum at the moment when wind waves prevail over swell after the initial part of the evolution.</p><p>Directional spreading is characterised by the second moment of the normalised angular distribution function, taken at selected wavenumbers relative to the spectral peak. We show that for scales longer than the spectral peak the angular spread predicted by the DNS is close to that predicted by both kinetic equations, but it underestimates the corresponding measured value, apparently due to the presence of swell. For the spectral peak and shorter waves, the DNS shows good agreement with the data. A notable feature is the steady growth of angular width at the spectral peak with time/fetch, in contrast to nearly constant width in the kinetic equations modelling. Dependence of angular width on wavenumber is shown to be much weaker than predicted by the kinetic equations. A more detailed consideration of the angular structure at the spectral peak at large fetches shows that the kinetic equations predict an angular distribution with a well-defined peak at the central angle, while the DNS reproduces the observed angular structure, with a flat peak over a range of angles.</p><p>In order to study in detail the differences between the predictions of the DNS and the kinetic equations modelling under idealised conditions, we also perform numerical simulations for the case of constant wind forcing. As in the previous case of forcing by real wind, the most striking difference between the kinetic equations and the DNS is the steady growth with time of angular width at the spectral peak, which is demonstrated by the DNS, but is not present in the modelling with the kinetic equations. We show that while the kinetic theory, both in the case of the Hasselmann equation and the generalised kinetic equation, predicts a relatively simple shape of the spectral peak, the DNS shows a more complicated structure, with a flat top and dependence of the peak position on angle. We discuss the approximations employed in the derivation of the kinetic theory and the possible causes of the found differences of directional structure.</p>



2020 ◽  
Vol 30 (10) ◽  
pp. 2023-2065 ◽  
Author(s):  
Mihaï Bostan ◽  
José Antonio Carrillo

We concentrate on kinetic models for swarming with individuals interacting through self-propelling and friction forces, alignment and noise. We assume that the velocity of each individual relaxes to the mean velocity. In our present case, the equilibria depend on the density and the orientation of the mean velocity, whereas the mean speed is not anymore a free parameter and a phase transition occurs in the homogeneous kinetic equation. We analyze the profile of equilibria for general potentials identifying a family of potentials leading to phase transitions. Finally, we derive the fluid equations when the interaction frequency becomes very large.



2002 ◽  
Vol 12 (11) ◽  
pp. 2599-2618 ◽  
Author(s):  
MARCEL O. VLAD ◽  
JOHN ROSS ◽  
FEDERICO MORAN ◽  
YOEL RODRIGUEZ

A delayed response tracer experiment is suggested, based on the following constraints: (1) The kinetics of the process can be expressed by local evolution equations without delays, for example by the mass action law. (2) The kinetic isotope effect can be neglected, that is, the rate coefficients for labeled and unlabeled chemicals are the same. (3) The total fluxes of the various chemicals are generally time dependent, but are not modified by the presence of the labeled compounds. (4) The experiment consists in the measurement of the time dependence of the fractions βu, u = 1, 2,… of labeled chemicals in the output fluxes as functionals of the time dependence of the fractions αu, u = 1, 2,… of labeled chemicals in the input fluxes, which are controlled by the researcher. We show that the output fluxes are related to the input fluxes by a linear delayed superposition theorem: βu(t) = ∑u′ ∫ χuu′(t,t′)αu′(t′)dt′, where χuu′(t,t′), is a delayed susceptibility function, which is related to the probability density of the transit time, that is, the time necessary for a molecular fragment to cross the system. This linear superposition law is not the result of a linearization procedure and holds even if the underlying kinetic equations are highly nonlinear. We establish a relationship between the transit time probability densities and the lifetime distributions of the various species in the system. The law permits extracting information about the mechanism and kinetics of chemical processes from response experiments.



2015 ◽  
Vol 24 (09) ◽  
pp. 1541009 ◽  
Author(s):  
Cristina Volpe

Neutrinos propagate in astrophysical and cosmological environments modifying their flavor in intriguing ways. The study of neutrino propagation in media is based on the mean-field, extended mean-field and Boltzmann equations. We summarize salient features of these evolution equations and the methods employed so far to derive them. We emphasize applications to situations of observational interest.



1986 ◽  
Vol 36 (3) ◽  
pp. 313-328 ◽  
Author(s):  
F. Cozzani ◽  
W. Horton

The transport theory of a high-energy ion species injected isotropically in a magnetized plasma is considered for arbitrary ratios of the high-energy ion cyclotron frequency to the collisional slowing down time. The assumptions of (i) low fractional density of the high-energy species and (ii) average ion speed faster than the thermal ions and slower than the electrons are used to decouple the kinetic equation for the high-energy species from the kinetic equations for background ions and electrons. The kinetic equation is solved by a Chapman–Enskog expansion in the strength of the gradients; an equation for the first correction to the lowest-order distribution function is obtained without scaling a priori the collision frequency with respect to the gyrofrequency. Various transport coefficients are explicitly calculated for the two cases of a weakly and a strongly magnetized plasma.



Author(s):  
Gerasim Vladimirovich Krivovichev

Stability analysis of lattice Boltzmann equations (LBEs) on initial conditions for one-dimensional diffusion is performed. Stability of the solution of the Cauchy problem for the system of linear Bhatnaghar–Gross–Krook kinetic equations is demonstrated for the cases of D1Q2 and D1Q3 lattices. Stability of the scheme for D1Q2 lattice is analytically analyzed by the method of differential approximation. Stability of parametrical scheme is numerically investigated by von Neumann method in parameter space. As a result of numerical analysis, the correction of the hypothesis on transfer of stability conditions of the scheme for macroequation to the system of LBEs is demonstrated.



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