Microtube flowing coulometry

1994 ◽  
Vol 72 (3) ◽  
pp. 836-849 ◽  
Author(s):  
Lifeng Chen ◽  
Christa L. Colyer ◽  
Muthoni G. Kamau ◽  
Jan C. Myland ◽  
Keith B. Oldham ◽  
...  

An aqueous solution containing supporting electrolyte and a small concentration of an electroactive analyte is allowed to flow, under a gravitational head, through a polarized platinum tube. The tube is narrow enough that, during their few seconds of residence time within the tube, virtually all the analyte molecules are able to diffuse to the tube wall and be electrolytically destroyed. The analyte concentration is accurately calculable, when the applied voltage and head are optimized, from the measured flow rate of the solution and the steady-state electric current, the latter being background-corrected by subtracting the current under no-flow conditions. Though the detailed theory is complicated, the principles of the method and its experimental realization are straightforward.

1980 ◽  
Vol 47 (4) ◽  
pp. 736-740 ◽  
Author(s):  
D. Durban

The process of the tube drawing between two rough conical walls is analyzed within the framework of continuum plasticity. Material behavior is modeled as rigid/linear-hardening along with the von-Mises flow rule. Assuming a radial flow pattern and steady state flow conditions it becomes possible to obtain an exact solution for the stresses and velocity. Useful relations are derived for practical cases where the nonuniformity induced by wall friction is small. A few restrictions on the validity of the results are discussed.


Author(s):  
Kevin Reid ◽  
John Denton ◽  
Graham Pullan ◽  
Eric Curtis ◽  
John Longley

An investigation into the effect of stator-rotor hub gap sealing flow on turbine performance is presented. Efficiency measurements and rotor exit area traverse data from a low speed research turbine are reported. Tests carried out over a range of sealing flow conditions show that the turbine efficiency decreases with increasing sealant flow rate but that this penalty is reduced by swirling the sealant flow. Results from time-accurate and steady-state simulations using a three-dimensional multi-block RANS solver are presented with particular emphasis paid to the mechanisms of loss production. The contributions toward entropy generation of the mixing of the sealant fluid with the mainstream flow and of the perturbed rotor secondary flows are assessed. The importance of unsteady stator wake/sealant flow interactions is also highlighted.


Author(s):  
Yoram Rubin

Many applications require primary information such as average fluxes as a prelude to more complex calculations. In water balance calculations one may be interested only in the average fluxes. For both cases the concept of effective conductivity is useful. The effective hydraulic conductivity is defined by where the angled brackets denote the expected value operator. The local flux fluctuation is defined by the difference qi(x) — (qi(x)). Its statistical properties as well as those of the velocity will be investigated in chapter 6. To qualify as an effective property in the strict physical sense, Kef must be a function of the aquifer’s material properties and not be influenced by flow conditions such as the head gradient and boundary conditions (Landauer, 1978). Our goal in this chapter is to explore the concept of the effective conductivity Kef and to relate it to the medium’s properties under as general conditions as possible. Additionally, we shall explore the conditions where this concept is irrelevant and applicable, the important issue being that Kef is defined in an ensemble sense, but for applications we need spatial averages. Several methods for deriving Kef will be described below. The general approach for defining Kef includes the following steps. First, H is defined as an SRF and is expressed with the aid of the flow equation in terms of the hydro-geological SRFs (conductivity, mostly) and the boundary conditions. The H SRF is then substituted in Darcy’s law and an expression in the form equivalent to (5.1) is sought. If and only if the coefficient in front of the mean head gradient is not a function of the flow conditions will it qualify as Kef. The derivation of the effective conductivity employs the flow equation. In steady-state incompressible flow, for example, Laplace’s equation is employed. Solutions derived under Laplace’s equation are applicable, under appropriate conditions, for other physical phenomena governed by the same mathematical model. For example, the electrical field in steady state is also described by Laplace’s equation.


2011 ◽  
Vol 343-344 ◽  
pp. 469-475
Author(s):  
Wen Yan Shi ◽  
Jian Zhong Gu ◽  
Zheng Jiao ◽  
Wen Jing Wu ◽  
Gang Xu ◽  
...  

(+)-alpha-phenylglycine are significant contaminants at pharmaceutical intermediates production. To study processes for the destruction of contaminant L(+)-alpha-phenylglycine in acid aqueous solution we have investigated the transient species using both laser flash photolysis. The OH· reaction with L(+)-alpha-phenylglycine process was investigated and formed polymer. Furthermore, the results of steady-state analysis suggested that L(+)-alpha-phenylglycine removal was found to be more efficient with increasing applied dose. L(+)-alpha-phenylglycine, decreased by 44.50%, using a dose of 14kGy.


Processes ◽  
2020 ◽  
Vol 8 (11) ◽  
pp. 1338
Author(s):  
Woo-Yul Kim ◽  
Santhosh Senguttuvan ◽  
Sung-Min Kim

The aerodynamic performance of a counter-rotating ducted fan in hover mode is numerically analyzed for different rotor spacings and duct diffusion angles. The design of the counter-rotating fan is inspired by a custom-designed single rotor ducted fan used in a previous study. The numerical model to predict the aerodynamic performance of the counter-rotating ducted fan is developed by adopting the frozen rotor approach for steady-state incompressible flow conditions. The relative angle between the front and the rear rotor is examined due to the usage of the frozen rotor model. The results show that the variation of thrust for the different relative angles is extremely low. The aerodynamic performances are evaluated by comparing the thrust, thrust coefficient, power coefficient, and figure of merit (FOM). The thrust, thrust coefficient, and FOM slightly increase with increasing rotor spacing up to 200 mm, regardless of the duct diffusion angle, and reduce on further increase in the rotor spacing. The duct diffusion angle of 0° generates about 9% higher thrust and increases the FOM by 6.7%, compared with the 6° duct diffusion angle. The duct diffusion angle is highly effective in improving the thrust and FOM of the counter-rotating ducted fan, rather than the rotor spacing.


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