Characterization of Groundwater with Complementary Age Tracers

<p>Groundwater age or residence time is the time water has resided in the subsurface since recharge. Depending on the application, this definition may or may not include travel through the unsaturated zone. The determination of groundwater age can aid understanding and characterization of groundwater resources, because it can provide information on e.g. groundwater mixing and flow, and volumes of groundwater and recharge. Groundwater age can be inferred from environmental tracers, such as SF₆ and tritium, that have a known input to groundwater and/or undergo known alteration processes in groundwater. The currently used age tracers face limitations regarding their application range and reliability. For example, some age tracers have local sources that can lead to contamination of groundwater. This contamination can result in misleading estimates of age. Other tracers have ambiguous inputs to groundwater, which can result in ambiguous age estimations. To reduce these limitations, it is now recognized that multiple tracers should be applied complementarily. There is also a need for new groundwater age tracers and/or new groundwater dating techniques to supplement the existing ones. Cost-effective and easily applicable tracers/techniques are preferred, since most established groundwater dating techniques are very costly and/or complex. Commonly measured hydrochemistry parameters , such as the concentrations of major ions and pH, have been suggested as cost-effective and easily determinable potential age tracers. To date, the use of commonly measured hydrochemistry parameters as independent age tracer has only been demonstrated for water recharged weeks to months ago relying on seasonal changes. Other studies applied commonly measured hydrochemistry complementarily to established age tracers to better constrain groundwater age and/or better understand and predict anthropogenic effects on groundwater quality. Further study is needed to assess the extent to which commonly measured hydrochemistry can be used to reduce uncertainty in tracer-inferred age as well as the extent to which commonly measured hydrochemistry can be used to extrapolate tracer-inferred age. In addition to tracer specific limitations, quantification of uncertainty and ambiguity is not standard in age modelling. Although a few studies have attempted to quantify uncertainty in age modelling with the aid of probabilistic approaches, their methods are often relatively complex and not transferrable to the many cases with little available data. Uncertainties in the tracer’s recharge estimate and identification of appropriate model components, such as the objective function, have not been considered. Studies in other areas of hydrological modelling, where probabilistic approaches are more commonly used, have highlighted the need for careful identification of model components.</p>

Characterization of Groundwater with Complementary Age Tracers

<p>Groundwater age or residence time is the time water has resided in the subsurface since recharge. Depending on the application, this definition may or may not include travel through the unsaturated zone. The determination of groundwater age can aid understanding and characterization of groundwater resources, because it can provide information on e.g. groundwater mixing and flow, and volumes of groundwater and recharge. Groundwater age can be inferred from environmental tracers, such as SF₆ and tritium, that have a known input to groundwater and/or undergo known alteration processes in groundwater. The currently used age tracers face limitations regarding their application range and reliability. For example, some age tracers have local sources that can lead to contamination of groundwater. This contamination can result in misleading estimates of age. Other tracers have ambiguous inputs to groundwater, which can result in ambiguous age estimations. To reduce these limitations, it is now recognized that multiple tracers should be applied complementarily. There is also a need for new groundwater age tracers and/or new groundwater dating techniques to supplement the existing ones. Cost-effective and easily applicable tracers/techniques are preferred, since most established groundwater dating techniques are very costly and/or complex. Commonly measured hydrochemistry parameters , such as the concentrations of major ions and pH, have been suggested as cost-effective and easily determinable potential age tracers. To date, the use of commonly measured hydrochemistry parameters as independent age tracer has only been demonstrated for water recharged weeks to months ago relying on seasonal changes. Other studies applied commonly measured hydrochemistry complementarily to established age tracers to better constrain groundwater age and/or better understand and predict anthropogenic effects on groundwater quality. Further study is needed to assess the extent to which commonly measured hydrochemistry can be used to reduce uncertainty in tracer-inferred age as well as the extent to which commonly measured hydrochemistry can be used to extrapolate tracer-inferred age. In addition to tracer specific limitations, quantification of uncertainty and ambiguity is not standard in age modelling. Although a few studies have attempted to quantify uncertainty in age modelling with the aid of probabilistic approaches, their methods are often relatively complex and not transferrable to the many cases with little available data. Uncertainties in the tracer’s recharge estimate and identification of appropriate model components, such as the objective function, have not been considered. Studies in other areas of hydrological modelling, where probabilistic approaches are more commonly used, have highlighted the need for careful identification of model components.</p>

Groundwater age in the Wairarapa

<p>This dissertation focuses on the catchment-scale evaluation of groundwater age as a function of space and time in the 270 km² Middle Wairarapa catchment. The simulation of the mean age and point distribution of ages, contributing to a regional age estimate, is a novel demonstration of the recently developed groundwater software, Cornaton (2012). The Wairarapa is in the southern North Island of New Zealand and is a dynamic water catchment exhibiting complex interactions between its rivers and shallow aquifers. Groundwater has been widely utilized since the 1980s for agriculture, horticulture and drinking water; increasing land use development (i.e. irrigation and nutrient application) requires effective regional management of both the quantity and quality of water resources. Groundwater age provides insights into groundwater flow and transport processes and thus enables better management of groundwater resources. Subsurface water age information enables the interpretation of recharge influence, zones of sensitivity for sustainable abstraction, as well as contamination risk from land-use intensification to drinking water supplies. It is accepted that groundwater is composed of a mixture of water with different ages, however, until very recently mean age has been the primary indicator for groundwater age assessment. Mean age alone can misrepresent the potential for contamination from young water; for example, a groundwater sample with an old mean age may still contain a significant fraction of young water; therefore, a fuller understanding of the age distribution in both time and space is important for groundwater management. The ability to simulate the full distribution of groundwater age within transient numerical groundwater models has only been very recently enabled, through implementation of the time-marching Laplace transform Galerkin technique (TMLTGT), and is demonstrated in this dissertation. A transient finite-element groundwater flow model originally developed by Greater Wellington Regional Council was converted to simulate transport of the age tracer tritium and groundwater age using the Ground Water (GW) software. Observed tritium concentrations were utilized in the calibration using the Monte Carlo and Gauss-Marquardt-Levenberg methods. Following the calibration of the transport model the GW software was then used to derive pumping well capture zones and directly simulate age throughout the Middle Wairarapa Valley catchment. The advective dispersive equation and the TMLTGT were used for transient mean-age and transient simulations of the full distribution of groundwater age. The results are presented as maps and graphs of both mean age and age distributions throughout the Middle Valley, covering a 15 year simulation period. The mean-age simulations indicated the groundwater age in the valley was strongly influenced by seasonal changes and extreme climatic events. Significant variations existed, from high rainfall recharge percolating young water throughout the domain, to dry extended droughts limiting recharge and increasing the age throughout large sections of the Middle Valley. Age distributions were shown to be strongly influenced by abstraction pressures, depth and geology. Abstractions were shown to skew the age distribution, creating both older and younger mean-ages depending on the location of the observation point, and several simulations indicated the potential misrepresentation of young (potentially contaminated) water quantified as old by mean-age assessment. These results show the dynamic nature of the Middle Valley groundwater system and its inherent vulnerabilities. The Wairarapa transient age distributions are one of the first such examples in New Zealand, and they demonstrate the potential of the information interpreted from age estimates to more effectively manage groundwater resources.</p>

Groundwater age in the Wairarapa

<p>This dissertation focuses on the catchment-scale evaluation of groundwater age as a function of space and time in the 270 km² Middle Wairarapa catchment. The simulation of the mean age and point distribution of ages, contributing to a regional age estimate, is a novel demonstration of the recently developed groundwater software, Cornaton (2012). The Wairarapa is in the southern North Island of New Zealand and is a dynamic water catchment exhibiting complex interactions between its rivers and shallow aquifers. Groundwater has been widely utilized since the 1980s for agriculture, horticulture and drinking water; increasing land use development (i.e. irrigation and nutrient application) requires effective regional management of both the quantity and quality of water resources. Groundwater age provides insights into groundwater flow and transport processes and thus enables better management of groundwater resources. Subsurface water age information enables the interpretation of recharge influence, zones of sensitivity for sustainable abstraction, as well as contamination risk from land-use intensification to drinking water supplies. It is accepted that groundwater is composed of a mixture of water with different ages, however, until very recently mean age has been the primary indicator for groundwater age assessment. Mean age alone can misrepresent the potential for contamination from young water; for example, a groundwater sample with an old mean age may still contain a significant fraction of young water; therefore, a fuller understanding of the age distribution in both time and space is important for groundwater management. The ability to simulate the full distribution of groundwater age within transient numerical groundwater models has only been very recently enabled, through implementation of the time-marching Laplace transform Galerkin technique (TMLTGT), and is demonstrated in this dissertation. A transient finite-element groundwater flow model originally developed by Greater Wellington Regional Council was converted to simulate transport of the age tracer tritium and groundwater age using the Ground Water (GW) software. Observed tritium concentrations were utilized in the calibration using the Monte Carlo and Gauss-Marquardt-Levenberg methods. Following the calibration of the transport model the GW software was then used to derive pumping well capture zones and directly simulate age throughout the Middle Wairarapa Valley catchment. The advective dispersive equation and the TMLTGT were used for transient mean-age and transient simulations of the full distribution of groundwater age. The results are presented as maps and graphs of both mean age and age distributions throughout the Middle Valley, covering a 15 year simulation period. The mean-age simulations indicated the groundwater age in the valley was strongly influenced by seasonal changes and extreme climatic events. Significant variations existed, from high rainfall recharge percolating young water throughout the domain, to dry extended droughts limiting recharge and increasing the age throughout large sections of the Middle Valley. Age distributions were shown to be strongly influenced by abstraction pressures, depth and geology. Abstractions were shown to skew the age distribution, creating both older and younger mean-ages depending on the location of the observation point, and several simulations indicated the potential misrepresentation of young (potentially contaminated) water quantified as old by mean-age assessment. These results show the dynamic nature of the Middle Valley groundwater system and its inherent vulnerabilities. The Wairarapa transient age distributions are one of the first such examples in New Zealand, and they demonstrate the potential of the information interpreted from age estimates to more effectively manage groundwater resources.</p>

The 3H/3He Groundwater Age-Dating Method And Applications

Groundwater age-dating is an important tool for quantifying and managing water resources. Groundwater age is the elapsed time between recharge (at the land surface or water table) and the time when groundwater is sampled. If groundwater is sampled at the point of discharge from an aquifer, then the age represents the groundwater transit time. Groundwater that has recharged in recent decades is considered young groundwater. In many areas, the quality and quantity of young groundwater has been impacted by human activities and groundwater age-dating is useful for quantifying current and historical water and contaminant fluxes into and through aquifers. This review is focused on the tritium-helium (3H/3He) method, which is a robust and widely applied age-dating technique for young groundwater. We present the development of the 3H/3He method and practical considerations for sampling groundwater in shallow unconfined aquifers. Along the way, we highlight available resources: (1) educational software for building intuition around groundwater age-dating and selection of sampling sites and (2) software that can be used to calculate 3H/3He age from noble gas and 3H data. We also highlight strengths and potential uncertainties associated with the method. For example, while other age-dating techniques require a known historical record of tracer concentration in the atmosphere, the 3H/3He age-dating technique does not require such historical records. However, the 3H/3He method requires measurement of two tracers to produce a groundwater age estimate (“apparent age” or “tracer age”). Precise measurement of 3H and noble gases, plus careful analysis of noble gas data to calculate the tritiogenic 3He (i.e., the portion of 3He derived from decay of 3H in the aquifer) is required to calculate the groundwater apparent age. Sampling for noble gases is sometimes challenging and requires specialized sample containers and technique. We also introduce basic sampling methods in this review but highlight how practitioners should work closely with a noble gas laboratory to obtain the correct containers and assess field conditions and/or the overall feasibility of projects. Lastly, the review highlights recent applications of the 3H/3He method, including recharge rate estimation, characterization of contaminant input histories for aquifers, quantifying groundwater transit times by sampling at aquifer discharge points, and the use of isotope data to constrain and inform numerical and statistical models of groundwater and contaminant movement in the subsurface.

Deciphering complex groundwater age distributions and recharge processes in a tropical and fractured volcanic aquifer system

Groundwater recharge in highly-fractured volcanic aquifers remains poorly understood in the humid tropics, whereby rapid demographic growth and unregulated land use change are resulting in extensive surface water pollution and a large dependency on groundwater extraction. Here we present a multi-tracer approach including δO-δH, H/He, and noble gases within the most prominent multi-aquifer system of central Costa Rica, with the objective to assess dominant groundwater recharge characteristics and age distributions. We sampled wells and large springs across an elevation gradient from 868 to 2,421 m asl. Our results suggest relatively young apparent ages ranging from 0.0±3.2 up to 76.6±9.9 years. Helium isotopes R/RA (0.99 to 5.4) indicate a dominant signal from the upper mantle across the aquifer. Potential recharge elevations ranged from ~1,400 to 2,650 m asl, with recharge temperatures varying from ~11°C to 19°C with a mean value of 14.5±1.9°C. Recharge estimates ranged from 129±78 to 1,605±196 mm/yr with a mean value of 642±117 mm/yr, representing 20.1±4.0% of the total mean annual rainfall as effective recharge. The shallow unconfined aquifer is characterised by young and rapidly infiltrating waters, whereas the deeper aquifer units have relatively older waters. These results are intended to guide the delineation and mapping of critical recharge areas in mountain headwaters to enhance water security and sustainability in the most important headwater dependent systems of Costa Rica.

A New Normalized Groundwater Age-Based Index for Quantitative Evaluation of the Vulnerability to Seawater Intrusion in Coastal Aquifers: Implications for Management and Risk Assessments

The vulnerability of coastal aquifers to seawater intrusion has been largely relying on data-driven indexing approaches despite their shortcomings to depict the complex processes of groundwater flow and mass transport under variable velocity conditions. This paper introduces a modelling-based alternative technique relying on a normalized saltwater age vulnerability index post-processed from results of a variable density flow simulation. This distributed index is obtained from the steady-state distribution of the salinity and a restriction of the mean groundwater age to a mean saltwater age distribution. This approach provides a novel way to shift from the concentration space into a vulnerability assessment space to evaluate the threats to coastal aquifers. The method requires only a sequential numerical solution of two steady state sets of equations. Several variants of the hypothetical Henry problem and a case study in Lebanon are selected for demonstration. Results highlight this approach ability to rank, compare, and validate different scenarios for coastal water resources management. A novel concept of zero-vulnerability line/surface delineating the coastal area threatened by seawater intrusion has shown to be relevant for optimal management of coastal aquifers and risk assessments. Hence, this work provides a new tool to sustainably manage and protect coastal groundwater resources.