Chain exchange kinetics of diblock copolymer micelles studied by nonradiative energy transfer. 1. Experimental design and theory

1995 ◽  
Vol 73 (11) ◽  
pp. 1995-2003 ◽  
Author(s):  
Guojun Liu

A fluorescence experiment involving mixing donor-labeled micelles with acceptor-labeled unimers has been designed and a kinetic scheme for describing such an experiment has been proposed. An approximate analytical solution was found for the decrease in the donor fluorescence intensity at time t after sample mixing relative to that at time zero, I(t)/I(0). Treating the data of this decrease in donor fluorescence intensity as a function of time using the derived equation allows the simultaneous determination of the rate constant kn for unimer incorporation into micelles and the quenching efficiency φ of donor fluorescence by an acceptor in a micelle. Keywords: polymer micelles, dynamics, chain exchange, energy transfer.


2021 ◽  
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Sangho Lee ◽  
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2010 ◽  
Vol 104 (4) ◽  
Author(s):  
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pp. 428-432 ◽  
Author(s):  
David Schaeffel ◽  
Andreas Kreyes ◽  
Yi Zhao ◽  
Katharina Landfester ◽  
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Author(s):  
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Isabelle Grillo ◽  
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2001 ◽  
Vol 55 (5) ◽  
pp. 667-673 ◽  
Author(s):  
L Willner ◽  
A Poppe ◽  
J Allgaier ◽  
M Monkenbusch ◽  
D Richter


2006 ◽  
Vol 39 (13) ◽  
pp. 4566-4575 ◽  
Author(s):  
Reidar Lund ◽  
Lutz Willner ◽  
Dieter Richter ◽  
Elena E. Dormidontova




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