Frequency Dependence of Electrorheological (ER) Effect and Its Relationship to Dielectric and Electrical Properties in Ba1-xSrxTiO3 Suspensions
Varying the electric field strength (E), the ER effect, the dielectric permittivity, and the electrical conductivity were simultaneously measured on the Ba 0.75 Sr 0.25 TiO 3 suspension. It was found that at high E the ER effect increased with the frequency (f), while at low E it once decreased and then increased with increase in f. At high E, the dielectric permittivity at low frequencies was much larger than that at high frequencies, indicating that an electrode polarization was formed as a result of accumulations of ions, which were dissociated from the liquid at high E, near the electrodes. This electrode polarization was further confirmed in the time dependence of the electrical conductivity after the electric field was switched on. From these results it is suggested that the E-dependent frequency dependence of the ER effect may be due to the electrode polarization, which causes larger shielding of the applied electric field at lower f while smaller shielding at higher f.