ELECTROKINETIC CHARACTERISTICS OF CALCINED KAOLINITE IN AQUEOUS ELECTROLYTIC SOLUTIONS

2015 ◽  
Vol 22 (03) ◽  
pp. 1550041
Author(s):  
TIANXING CHEN ◽  
YUNLIANG ZHAO ◽  
HONGLIANG LI ◽  
JIA LIU ◽  
SHAOXIAN SONG

In this work, the electrokinetic characteristics of calcined kaolinite in aqueous solutions has been studied in the presence of the electrolytes of NaCl , KCl , NH 4 Cl , NaNO 3, MgCl 2, CaCl 2 and AlCl 3, through electrophoretic measurement. The experimental results have shown that the zeta potential was closely dependent on the valence and concentration of the electrolytic cations, but not on the type of the cations. The higher the valence and the concentration were, the stronger the impact to the zeta potential was. Al 3+ could reverse the potential sign from negative to positive. In addition, it was found that the monovalent anions of Cl - and [Formula: see text] made a big difference to the zeta potential at the same dosage.

2009 ◽  
Vol 16 (01) ◽  
pp. 65-71 ◽  
Author(s):  
FENG RAO ◽  
SHAOXIAN SONG ◽  
ALEJANDRO LOPEZ-VALDIVIESO

Electrokinetic property of various minerals in aqueous solutions has been studied through electroacoustic measurement in the present work. This study was carried out on the particles of calcite ( CaCO 3), magnetite ( Fe 3 O 4), quartz ( SiO 2), and galena ( PbS ) in an aqueous NaCl solution. Electrophoretic measurement was also applied to magnetite and quartz particles for the comparison of the two methods. The experimental results have shown that the point of zero charges (PZCs) of calcite, magnetite, and galena were at pH 12.5, 3.8 and 2.8, respectively, while no PZC for quartz appeared in the pH range of 1.5–11. The electroacoustic and electrophoretic measurements have obtained the same PZC and similar curves of zeta potential vs pH for magnetite and quartz particles in aqueous solutions. In addition, it has been found that a specific adsorption of Na + cation was applied to magnetite surfaces in aqueous solutions if the electrolyte ( NaCl ) concentration in the solution is high enough, leading the isoelectric point to shift rightward. This observation might be more remarkable in electroacoustic measurement than electrophoretic measurement.


2016 ◽  
Author(s):  
Leonardo Becchetti ◽  
Maurizio Fiaschetti ◽  
Francesco Salustri

2019 ◽  
Vol 6 (6) ◽  
pp. 181902 ◽  
Author(s):  
Junchen Lv ◽  
Yuan Chi ◽  
Changzhong Zhao ◽  
Yi Zhang ◽  
Hailin Mu

Reliable measurement of the CO 2 diffusion coefficient in consolidated oil-saturated porous media is critical for the design and performance of CO 2 -enhanced oil recovery (EOR) and carbon capture and storage (CCS) projects. A thorough experimental investigation of the supercritical CO 2 diffusion in n -decane-saturated Berea cores with permeabilities of 50 and 100 mD was conducted in this study at elevated pressure (10–25 MPa) and temperature (333.15–373.15 K), which simulated actual reservoir conditions. The supercritical CO 2 diffusion coefficients in the Berea cores were calculated by a model appropriate for diffusion in porous media based on Fick's Law. The results show that the supercritical CO 2 diffusion coefficient increases as the pressure, temperature and permeability increase. The supercritical CO 2 diffusion coefficient first increases slowly at 10 MPa and then grows significantly with increasing pressure. The impact of the pressure decreases at elevated temperature. The effect of permeability remains steady despite the temperature change during the experiments. The effect of gas state and porous media on the supercritical CO 2 diffusion coefficient was further discussed by comparing the results of this study with previous study. Based on the experimental results, an empirical correlation for supercritical CO 2 diffusion coefficient in n -decane-saturated porous media was developed. The experimental results contribute to the study of supercritical CO 2 diffusion in compact porous media.


Author(s):  
Zuhair AlYousef ◽  
Subhash Ayirala ◽  
Majed Almubarak ◽  
Dongkyu Cha

AbstractGenerating strong and stable foam is necessary to achieve in-depth conformance control in the reservoir. Besides other parameters, the chemistry of injection water can significantly impact foam generation and stabilization. The tailored water chemistry was found to have good potential to improve foam stability. The objective of this study is to extensively evaluate the effect of different aqueous ions in the selected tailored water chemistry formulations on foam stabilization. Bulk and dynamic foam experiments were used to evaluate the impact of different tailored water chemistry aqueous ions on foam generation and stabilization. For bulk foam tests, the stability of foams generated using three surfactants and different aqueous ions was analyzed using bottle tests. For dynamic foam experiments, the tests were conducted using a microfluidic device. The results clearly demonstrated that the ionic content of aqueous solutions can significantly affect foam stabilization. The results revealed that the foam stabilization in bulk is different than that in porous media. Depending on the surfactant type, the divalent ions were found to have stronger influence on foam stabilization when compared to monovalent ions. The bulk foam results pointed out that the aqueous solutions containing calcium chloride salt (CaCl2) showed longer foam life with the anionic surfactant and very weak foam with the nonionic surfactant. The solutions with magnesium chloride (MgCl2) and CaCl2 salts displayed higher impact on foam stability in comparison with sodium chloride (NaCl) with the amphoteric alkyl amine surfactant. Less stable foams were generated with aqueous solutions comprising of both magnesium and calcium ions. In the microfluidic model, the solutions containing MgCl2 showed higher resistance to gas flow and subsequently higher mobility reduction factor for the injection gas when compared to those produced using NaCl and CaCl2 salts. This experimental study focusing about the role of different aqueous ions in the injection water on foam could help in better understanding the foam stabilization process. The new knowledge gained can also enable the selection and optimization of the right injection water chemistry and suitable chemicals for foam field applications.


Membranes ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 25
Author(s):  
Javed Alam ◽  
Arun Kumar Shukla ◽  
Mohammad Azam Ansari ◽  
Fekri Abdulraqeb Ahmed Ali ◽  
Mansour Alhoshan

We fabricated a nanofiltration membrane consisting of a polyaniline (PANI) film on a polyphenylsulfone (PPSU) substrate membrane. The PANI film acted as a potent separation enhancer and antimicrobial coating. The membrane was analyzed via scanning electron microscopy and atomic force microscopy to examine its morphology, topography, contact angle, and zeta potential. We aimed to investigate the impact of the PANI film on the surface properties of the membrane. Membrane performance was then evaluated in terms of water permeation and rejection of methylene blue (MB), an organic dye. Coating the PPSU membrane with a PANI film imparted significant advantages, including finely tuned nanometer-scale membrane pores and tailored surface properties, including increased hydrophilicity and zeta potential. The PANI film also significantly enhanced separation of the MB dye. The PANI-coated membrane rejected over 90% of MB with little compromise in membrane permeability. The PANI film also enhanced the antimicrobial activity of the membrane. The bacteriostasis (BR) values of PANI-coated PPSU membranes after six and sixteen hours of incubation with Escherichia coli were 63.5% and 95.2%, respectively. The BR values of PANI-coated PPSU membranes after six and sixteen hours of incubation with Staphylococcus aureus were 70.6% and 88.0%, respectively.


Author(s):  
Andrea Morone ◽  
Rocco Caferra ◽  
Alessia Casamassima ◽  
Alessandro Cascavilla ◽  
Paola Tiranzoni

AbstractThis work aims to identify and quantify the biases behind the anomalous behavior of people when they deal with the Three Doors dilemma, which is a really simple but counterintuitive game. Carrying out an artefactual field experiment and proposing eight different treatments to isolate the anomalies, we provide new interesting experimental evidence on the reasons why subjects fail to take the optimal decision. According to the experimental results, we are able to quantify the size and the impact of three main biases that explain the anomalous behavior of participants: Bayesian updating, illusion of control and status quo bias.


2004 ◽  
Vol 20 (3) ◽  
pp. 256-280 ◽  
Author(s):  
Xosé Rosales Sequeiros

This article explores second language (L2) learners’ interpretation of reflexive anaphora in VP-Ellipsis by critiquing the work of Ying (2003), who applies Relevance Theory to explain elliptical anaphora. It argues against four claims made in his analysis: that L2 learners apply maximal relevance in anaphoric interpretation; that a procedural account of the impact of referential sentences on VP-ellipsis disambiguation is appropriate; that an account of anaphoric interpretation preferences should be based on processing cost; and that differences in experimental results between intermediate and advanced L2 learners are due to the use of different comprehension strategies (see Sperber, 1994). Instead, it argues: that it is not maximal but rather optimal relevance that is at work; that the key in disambiguating anaphora in VP-elliptical sentences is the achievement of an optimally relevant interpretation; that the role of contextual assumptions in anaphora resolution is to enable L2 learners to derive enough contextual effects to make it worth their effort and, in doing so, identifying (as a side effect) what they take to have been the intended referent; and that what is crucial in the use of comprehension strategies is not processing effort, but rather consistency with the second principle of relevance. Overall, all these factors provide the basis for an alternative and more comprehensive explanation of the experimental results discussed by Ying.


2011 ◽  
Vol 332-334 ◽  
pp. 27-30 ◽  
Author(s):  
Mei Niu ◽  
Zi Lu Wu ◽  
Jin Ming Dai ◽  
Wen Sheng Hou ◽  
Sheng Shi ◽  
...  

Wool fiber was firstly pretreated by nano-SiO2/Ag antibacterial agent, and then dyed with an acid dyes at low temperature by ultrasonic dyeing. Many factors had an important influence on the dye ability and the antibacterial behavior during the dyeing process of antibacterial wool fiber. The experimental results indicate that the dye-takeup rates of antibacterial wool fiber were enhanced with the increase of the concentration of nano-SiO2/Ag, the dyeing temperature, the dyeing time and the ultrasonic frequency (less than 60Hz). However, the antibacterial ratios of wool fiber were declined in the impact of these factors other than the concentration of antibacterial agent.


2013 ◽  
Vol 281 ◽  
pp. 47-50
Author(s):  
Zhi Hong Chen

In this paper we propose a new steganographic method, which based on wet paper codes and wavelet transformation. The method is designed to embed secret messages in images' wavelet coefficients and depends on images' texture characters in local neighborhood. The receivers can extract secret bits from carrier images only by some matrix multiplications without knowing the formulas written by senders, which further improves steganographic security and minimizes the impact of embedding changes. The experimental results show that our proposed method has good robust and visual concealment performance and proves out it's a practical steganographic algorithm.


2016 ◽  
Vol 28 (12) ◽  
pp. 1614-1626 ◽  
Author(s):  
Wan-Li Song ◽  
Dong-Heng Li ◽  
Yan Tao ◽  
Na Wang ◽  
Shi-Chao Xiu

The aim of this work is to investigate the effect of the small magnetorheological fluid gap on the braking performance of the magnetorheological brake. In this article, theoretical analyses of the output torque are given first, and then the operating principle and design details of the magnetorheological brake whose magnetorheological fluid gap can be altered are presented and discussed. Next, the magnetic circuit of the proposed magnetorheological brake is conducted and further followed by a magnetostatic simulation of the magnetorheological brakes with different sizes of fluid gap. A prototype of the magnetorheological brake is fabricated and a series of tests are carried out to evaluate the braking performance and torque stability, as well as the verification of the simulation results. Experimental results show that the braking torque increases with the increase in the current, and the difference for the impact of the fluid gap on braking performance is huge under different currents. The rules, which the experimental results show, have an important significance on both the improvement of structure design for magnetorheological brake and the investigation of the wear property under different fluid gaps.


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