ELECTRICAL RESISTIVITY, CRYSTALLIZATION AND MECHENICAL PROPERTIES OF POLYPROPYLENE/MULTI-WALLED CARBON NANOTUBE/CALCIUM CARBONATE COMPOSITES PREPARED BY MELT MIXING

2009 ◽  
Vol 27 (03) ◽  
pp. 393 ◽  
Author(s):  
Ha-da Bao ◽  
Zhao-xia Guo ◽  
Jian Yu
2015 ◽  
Vol 727-728 ◽  
pp. 137-140
Author(s):  
A Ying Zhang

This paper presents a systematic study of the nano-sized structure and temperature dependent electrical properties. A method of synthesizing the self-assembled multi-walled carbon nanotube (MWCNT) nanopaper on hydrophilic polycarbonate membrane was explored. The process is based on the very well-defined dispersion of nanotube and controlled pressure vacuum deposition procedure. The experiment results show that the ratio changes of MWCNT in the nanopaper could lead to the changes in the electrical conductivity efficiency of the nanopaper. Furthermore, the electrical resistivity of MWCNT nanopaper decreased as temperature increase.


Polymers ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 1685 ◽  
Author(s):  
Marta Zaccone ◽  
Ilaria Armentano ◽  
Federico Cesano ◽  
Domenica Scarano ◽  
Alberto Frache ◽  
...  

Polypropylene (PP) / multi-walled carbon nanotube (MWCNT) nanocomposites were prepared by melt-mixing and used to manufacture samples by injection molding. The effect of processing conditions on the crystallinity and electrical resistivity was studied. Accordingly, samples were produced varying the mold temperature and injection rate, and the DC electrical resistivity was measured. The morphology of MWCNT clusters was studied by optical and electron microscopy, while X-ray diffraction was used to study the role of the crystalline structure of PP. As a result, an anisotropic electrical behavior induced by the process was observed, which is further influenced by the injection molding processing condition. It was demonstrated that a reduction of electrical resistivity can be obtained by increasing mold temperature and injection rate, which was associated to the formation of the γ-phase and the related inter-cluster morphology of the MWCNT conductive network.


2014 ◽  
Vol 979 ◽  
pp. 107-110
Author(s):  
Samor Boonphan ◽  
Pisith Singjai

Step-heating (single-and four-step heating) was used in the melt-mixing preparation of linear low density polyethylene (LLDPE)/multi-walled carbon nanotube (MWNT) composites. The MWNT in the composites were used at volume fractions of 0, 1, 3, 5, and 10 vol% (four-step heating), and 0, 1, 3, and 5 vol% (single-step heating). The effects of the heating steps on the microstructure of the LLDPE/MWNT composites were studied. An ultimate tensile testing machine and an impact testing machine were used to characterize the mechanical properties of the composites. The sample prepared using four-step heating had a lower porosity than the sample prepared using single-step heating. The sample with 3 vol% MWNT that was prepared using four-step heating had tensile strength, elastic modulus, and impact strength values that were higher than those of the other samples.


2016 ◽  
Vol 699 ◽  
pp. 8-17
Author(s):  
Ionut Laurentiu Sandu ◽  
Razvan Rosculet ◽  
Catalin Fetecau

The objective of this research is to investigate the effect of the annealing process on the mechanical and electrical properties of thermoplastic polyurethane/multi-walled carbon nanotube (TPU/MWCNT) nanocomposites. The TPU/MWCNT nanocomposites were prepared by melt-mixing the TPU with 1, 3, and 5 wt.% MWCNT. The TPU/MWCNT injection-molded specimens were annealed at 110°C at different annealing time intervals. The mechanical properties of TPU/MWCNT nanocomposites (Young modulus, tensile strength at yield, stress at break and strain at break) were measured before and after the annealing at constant crosshead speed of 100 mm/min. Furthermore, the DC conductivity of the TPU/MWCNT injection molding specimens was measured before and after annealing, and the percolation thresholds were determined based on following the percolation theory.


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