scholarly journals Effect of Injection Molding Conditions on Crystalline Structure and Electrical Resistivity of PP/MWCNT Nanocomposites

Polymers ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 1685 ◽  
Author(s):  
Marta Zaccone ◽  
Ilaria Armentano ◽  
Federico Cesano ◽  
Domenica Scarano ◽  
Alberto Frache ◽  
...  
Keyword(s):  
Electrical Resistivity ◽  
Injection Molding ◽  
Crystalline Structure ◽  
Processing Condition ◽  
Mold Temperature ◽  
Injection Rate ◽  
X Ray Diffraction ◽  
Melt Mixing ◽  
Cluster Morphology ◽  
Multi Walled Carbon Nanotube

Polypropylene (PP) / multi-walled carbon nanotube (MWCNT) nanocomposites were prepared by melt-mixing and used to manufacture samples by injection molding. The effect of processing conditions on the crystallinity and electrical resistivity was studied. Accordingly, samples were produced varying the mold temperature and injection rate, and the DC electrical resistivity was measured. The morphology of MWCNT clusters was studied by optical and electron microscopy, while X-ray diffraction was used to study the role of the crystalline structure of PP. As a result, an anisotropic electrical behavior induced by the process was observed, which is further influenced by the injection molding processing condition. It was demonstrated that a reduction of electrical resistivity can be obtained by increasing mold temperature and injection rate, which was associated to the formation of the γ-phase and the related inter-cluster morphology of the MWCNT conductive network.

scholarly journals Dielectric Spectroscopy of PP/MWCNT Nanocomposites: Relationship with Crystalline Structure and Injection Molding Condition

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 550
Author(s):  
Marco Monti ◽  
Marta Zaccone ◽  
Alberto Frache ◽  
Luigi Torre ◽  
Ilaria Armentano
Keyword(s):  
Injection Molding ◽  
Crystalline Structure ◽  
Processing Condition ◽  
Mold Temperature ◽  
Dielectric Behavior ◽  
Multi Walled Carbon Nanotube ◽  
Molding Condition ◽  
Frequency Independent ◽  
Injection Molded ◽  
Independent Behavior

In this paper, we study the correlation between the dielectric behavior of polypropylene/multi-walled carbon nanotube (PP/MWCNT) nanocomposites and the morphology with regard to the crystalline structure, nanofiller dispersion and injection molding conditions. As a result, in the range of the percolation threshold the dielectric behavior shifts to a more frequency-independent behavior, as the mold temperature increases. Moreover, the position further from the gate appears as the most conductive. This effect has been associated to a modification of the morphology of the MWCNT clusters induced by both the flow of the molten polymer during the processing phase and the variation of the crystalline structure, which is increasingly constituted by γ-phase as the mold temperature increases. The obtained results allow one to understand the effect of tuning the processing condition in the frequency-dependent electrical behavior of PP/MWCNT injection-molded nanocomposites, which can be successfully exploited for an advanced process/product design.

Fabrication of Supports for Solid Oxide Fuel Cells by Powder Injection Molding

2011 ◽  
Author(s):  
Ali Keshavarz Panahi ◽  
Hadi Miyanaji ◽  
Moein Taheri ◽  
Milad Janbakhsh
Keyword(s):  
Injection Molding ◽  
Weld Line ◽  
Injection Pressure ◽  
Mold Temperature ◽  
Injection Rate ◽  
Powder Injection ◽  
Pressure Injection ◽  
Packing Pressure ◽  
Molded Parts ◽  
Short Shot

In this paper the processing steps for producing SOFC (Solid Oxide Fuel Cell) supports by means of PIM (Powder Injection Molding) technique were investigated. Injection molding parameters in this study were divided into pressure-related (injection pressure and packing pressure), temperature-related (nozzle temperature and mold temperature), and time-related (injection rate and holding time) parameters. Keeping the other parameters (pressure-related, temperature-related and time-related parameters) constant at an optimized value, the effects of each of the molding parameters above were investigated. The results show that the short shot, warpage, weld line and void are the most common defects in molded parts. According to the results the short shot could be seen in low values of injection pressure, injection rate, nozzle and mold temperature. Also, warpage could be seen in high values of mold temperature, injection and packing pressure. Poor weld line was another defect that could be seen in low values of injection pressure, injection rate, nozzle and mold temperature. Also the void was one of the most common defects that could be seen in high values of injection rate and nozzle temperatures. Finally, using optimized molding parameters, the molded parts underwent debinding and sintering processes. Based on the results of thermal shock tests and the porosity measurements of the sintered parts, these molded parts possessed relatively desirable characteristics.

Injection Molding

2006 ◽  
Author(s):  
Chang Dae Han
Keyword(s):  
Injection Molding ◽  
Cooling Water ◽  
Polymer Melt ◽  
Mold Temperature ◽  
Mold Filling ◽  
Injection Rate ◽  
Mold Cavity ◽  
Complex Nature ◽  
Almost All ◽  
Cavity Cooling

Injection molding is one of the oldest polymer processing operations used to produce goods from thermoplastic polymers. Today, almost all commercial injection molding machines have a reciprocating single screw for softening (or melting) under heat a thermoplastic polymer, and polymer melt is then injected into an empty mold cavity, as schematically shown in Figure 8.1. In the injection molding operation, the mold is first closed and then a predetermined amount of polymer melt from the screw section is injected into an empty mold cavity. Pressure is maintained for some time after the mold cavity has been filled to permit the build-up of adequate pressure in the mold cavity. Cooling water is circulated through channels in the mold so as to keep the mold cavity walls at a temperature usually between room temperature and the softening (or melting) temperature of the polymer. Thus, the hot polymer begins to cool as it enters the mold cavity. When it is cooled to a state of sufficient rigidity, the mold is opened and the part is removed. Some of the important variables in the operation of an injection molding machine are: (1) pressure applied by the screw, (2) temperature profile of the screw section, (3) mold temperature, (4) the screw forward time, (5) the mold closed time, and (6) the mold open time. Relationships between these variables are very complicated. In general, one would like to know the pressure, temperature, and density of the polymer in the mold cavity as functions of time during and after the mold is filled. In principle, these quantities can be calculated, via a mathematical model, during the entire period of mold filling and subsequent cooling when information on the geometry of the mold cavity, the rheological properties of the polymer, the temperature at which the polymer enters the mold cavity, and the mold temperature is available. However, in practice it is not easy to develop a rigorous theory because of the geometrically complex shapes of mold cavities, the complex nature of mold filling patterns (i.e., jetting) at normal injection speeds of industrial practice, and the highly viscoelastic nature of polymer melts, which varies with temperature, pressure, and injection rate (i.e., shear rate in the runner).

Numerical Simulation Research of Micro-Injection Molding Simulation

2011 ◽  
Vol 55-57 ◽  
pp. 1511-1517
Author(s):  
Xiao Hua Wei ◽  
Bai Yang Lou
Keyword(s):  
Numerical Simulation ◽  
Injection Molding ◽  
Injection Pressure ◽  
Mold Temperature ◽  
Injection Rate ◽  
Thin Wall ◽  
Melt Temperature ◽  
Simulation Research ◽  
Injection Molding Simulation ◽  
Plastic Parts

According to the basic theory and process of conventional injection molding, using the CAE software, numerical simulation research of the injection molding characteristic for micro thin-wall plastic parts are put forward. The effects of process parameters (melt temperature, mold temperature, injection pressure, injection rate) on molding characteristic of micro thin-wall plastic parts are discussed by single factor method, compare the significance of each factors.The simulation results showed that volume could be improved with the increase of melt temperature ,molding temperature, injection pressure and injection rate.

scholarly journals Photoluminescent Properties of Hydroxyapatite and Hydroxyapatite/Multi-Walled Carbon Nanotube Composites

Crystals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 832
Author(s):  
Edna X. Figueroa-Rosales ◽  
Javier Martínez-Juárez ◽  
Esmeralda García-Díaz ◽  
Daniel Hernández-Cruz ◽  
Sergio A. Sabinas-Hernández ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Hexagonal Phase ◽  
Precipitation Method ◽  
X Ray Diffraction ◽  
X Ray ◽  
Multi Walled Carbon Nanotube ◽  
Nanotube Composites ◽  
Carbon Nanotube Composites ◽  
Co Precipitation ◽  
Functionalized Mwcnts

Hydroxyapatite (HAp) and hydroxyapatite/multi-walled carbon nanotube (MWCNT) composites were obtained by the co-precipitation method, followed by ultrasound-assisted and microwave radiation and thermal treatment at 250 °C. X-ray diffraction (XRD) confirmed the presence of a hexagonal phase in all the samples, while Fourier-transform infrared (FTIR) spectroscopy elucidated the interaction between HAp and MWCNTs. The photoluminescent technique revealed that HAp and the composite with non-functionalized MWCNTs present a blue luminescence, while the composite with functionalized MWCNTs, under UV-vis radiation shows an intense white emission. These findings allowed presentation of a proposal for the use of HAp and HAp with functionalized MWCNTs as potential materials for optoelectronic and medical applications.

Study of the multiplet nature in shpol'skii effect: Host n-heptane crystalline structure by X-ray diffraction and guest coronene position by ESR

1977 ◽  
Vol 22 (2) ◽  
pp. 207-214 ◽  
Author(s):  
A.M. Merle ◽  
M. Lamotte ◽  
S. Risemberg ◽  
C. Hauw ◽  
J. Gaultier ◽  
...  
Keyword(s):  
Crystalline Structure ◽  
X Ray Diffraction ◽  
X Ray

scholarly journals Study on External Gas-Assisted Mold Temperature Control with the Assistance of a Flow Focusing Device in the Injection Molding Process

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 965 ◽  
Author(s):  
Nguyen Truong Giang ◽  
Pham Son Minh ◽  
Tran Anh Son ◽  
Tran Minh The Uyen ◽  
Thanh-Hai Nguyen ◽  
...  
Keyword(s):  
Injection Molding ◽  
Temperature Control ◽  
Mold Temperature ◽  
Injection Molding Process ◽  
Melt Flow ◽  
Flow Focusing ◽  
Molding Process ◽  
Heating Efficiency ◽  
Flow Length ◽  
Insert Plate

In the injection molding field, the flow of plastic material is one of the most important issues, especially regarding the ability of melted plastic to fill the thin walls of products. To improve the melt flow length, a high mold temperature was applied with pre-heating of the cavity surface. In this paper, we present our research on the injection molding process with pre-heating by external gas-assisted mold temperature control. After this, we observed an improvement in the melt flow length into thin-walled products due to the high mold temperature during the filling step. In addition, to develop the heating efficiency, a flow focusing device (FFD) was applied and verified. The simulations and experiments were carried out within an air temperature of 400 °C and heating time of 20 s to investigate a flow focusing device to assist with external gas-assisted mold temperature control (Ex-GMTC), with the application of various FFD types for the temperature distribution of the insert plate. The heating process was applied for a simple insert model with dimensions of 50 mm × 50 mm × 2 mm, in order to verify the influence of the FFD geometry on the heating result. After that, Ex-GMTC with the assistance of FFD was carried out for a mold-reading process, and the FFD influence was estimated by the mold heating result and the improvement of the melt flow length using acrylonitrile butadiene styrene (ABS). The results show that the air sprue gap (h) significantly affects the temperature of the insert and an air sprue gap of 3 mm gives the best heating rate, with the highest temperature being 321.2 °C. Likewise, the actual results show that the height of the flow focusing device (V) also influences the temperature of the insert plate and that a 5 mm high FFD gives the best results with a maximum temperature of 332.3 °C. Moreover, the heating efficiency when using FFD is always higher than without FFD. After examining the effect of FFD, its application was considered, in order to improve the melt flow length in injection molding, which increased from 38.6 to 170 mm, while the balance of the melt filling was also clearly improved.

STUDY OF THE DEPENDENCE OF HIGH Tc ON VARIOUS SINTERING TEMPERATURES FOR Bi-Pb-Sr-Ca-Cu-O SUPERCONDUCTORS

1991 ◽  
Vol 05 (24n25) ◽  
pp. 1635-1638
Author(s):  
S.M. M.R. NAQVI ◽  
A.A. QIDWAI ◽  
S.M. ZIA-UL-HAQUE ◽  
FIROZ AHMAD ◽  
S.D.H. RIZVI ◽  
...  
Keyword(s):  
Electrical Resistivity ◽  
Liquid Nitrogen ◽  
X Ray Diffraction ◽  
High Tc ◽  
X Ray ◽  
Resistivity Measurements ◽  
Zero Resistance

Bi1.7-Pb0.3-Sr2-Ca2-Cu3-Ox superconducting samples were prepared at 855°C, 862 C, 870 C, and 882 C sintering temperatures respectively. All samples were sintered for 120 hours. The samples were then quenched in liquid nitrogen. The electrical resistivity measurements showed that the samples sintered at 870° C had the best Tc. For these samples the Tc onset was around 120 K and the zero resistance was obtained at 108 K. X-ray diffraction studies showed that the samples were multiphased.

Application of Taguchi Method for Parameters Optimization in Micro Metal Injection Molding

2011 ◽  
Vol 52-54 ◽  
pp. 244-248
Author(s):  
Haw Pei Li ◽  
Norhamidi Muhamad ◽  
Abu Bakar Sulong ◽  
Heng Shye Yunn ◽  
Hooman Abolhasani
Keyword(s):  
Injection Molding ◽  
Signal To Noise Ratio ◽  
Steel Powder ◽  
Mold Temperature ◽  
Parameters Optimization ◽  
Simultaneous Optimization ◽  
Metal Injection Molding ◽  
Surface Appearance ◽  
Optimal Injection ◽  
Acetate Butyrate

Optimization of injection parameters in Micro Metal Injection Molding (μMIM) was described in this study. Stainless steel powder was mixed with Polyethelena Glycol (PEG), Polymethyl Methacrilate (PMMA) and Cellulose Acetate Butyrate (CAB) to produce feedstock. Design of Experiments (DOE) of Taguchi L-27 (313) orthogonal array technique has been used to investigate the significance and optimal injection molding parameters. The signal-to-noise ratio and analysis of variance (ANOVA) are applied to study the optimum levels and effects of process parameters. Simultaneous optimization to obtain the highest green density and excellent surface appearance was discussed. The result concluded that the mold temperature (D) is the most statistically significant process parameter and its contribution to the best appearance and density is the highest.

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