Facile One-Pot Synthesis and Optical Properties of Quinary Wurtzite Cu3ZnInSnS6 Nanocrystals
Nearly monodisperse bullet-like Cu3ZnInSnS6 (CZITS) nanocrystals with wurtzite structure were successfully synthesized through optimized noninjection method. The structure, composition, morphology and optical properties of CZITS nanocrystals were characterized by X-ray diffraction, energy dispersive spectrometry, transmission electron microscopy and UV-Vis–NIR absorption. Their suitable bandgap and photoresponsive behavior indicate a high potential application in the field of solar cells. The growth mechanism of the as-synthesized CZITS nanocrystals was preliminarily discussed. It was found that the formation of CZITS could be separated into two steps: nucleation of Cu7S4 and growth of the CZITS main body.
2019 ◽
Vol 17
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2006 ◽
Vol 6
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pp. 162-167
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2008 ◽
Vol 8
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pp. 572-576
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1982 ◽
Vol 40
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pp. 722-723
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