Bipolar Membranes with Systematically Varied Interfacial Areas in the Junction Region

2021 ◽  
Vol MA2021-01 (45) ◽  
pp. 1826-1826
Author(s):  
Subarna Kole ◽  
Christopher G. Arges
Author(s):  
Subarna Kole ◽  
Gokul Venugopalan ◽  
Deepra Bhattacharya ◽  
Le Zhang ◽  
John Cheng ◽  
...  

Left image is the relationship for the overpotential for water dissociation as a function of bipolar junction electric field whereas the right image presents micrographs and the procedure to make bipolar membranes with micropatterned interfaces.


1983 ◽  
Vol 48 (3) ◽  
pp. 842-853
Author(s):  
Kurt Winkler ◽  
František Kaštánek ◽  
Jan Kratochvíl

Specific gas-liquid interfacial area in flow tubes 70 mm in diameter of the length 725 and 1 450 mm resp. containing various swirl bodies were measured for concurrent upward flow in the ranges of average gas (air) velocities 11 to 35 ms-1 and liquid flow rates 13 to 80 m3 m-2 h-1 using the method of CO2 absorption into NaOH solutions. Two different flow regimes were observed: slug flow swirled annular-mist flow. In the latter case the determination was carried out separately for the film and spray flow components, respectively. The obtained specific areas range between 500 to 20 000 m3 m-2. Correlation parameters are energy dissipation criteria, related to the geometrical reactor volume and to the static liquid volume in the reactor.


Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 2028
Author(s):  
Shin-ichi Sawada ◽  
Yasunari Maekawa

We prepared novel bipolar membranes (BPMs) consisting of cation and anion exchange layers (CEL and AEL) using radiation-induced asymmetric graft polymerization (RIAGP). In this technique, graft polymers containing cation and anion exchange groups were introduced into a base film from each side. To create a clear CEL/AEL boundary, grafting reactions were performed from each surface side using two graft monomer solutions, which are immiscible in each other. Sodium p-styrenesulfonate (SSS) and acrylic acid (AA) in water were co-grafted from one side of the base ethylene-co-tetrafluoroethylene film, and chloromethyl styrene (CMS) in xylene was simultaneously grafted from the other side, and then the CMS units were quaternized to afford a BPM. The distinct SSS + AA- and CMS-grafted layers were formed owing to the immiscibility of hydrophilic SSS + AA and hydrophobic CMS monomer solutions. This is the first BPM with a clear CEL/AEL boundary prepared by RIAGP. However, in this BPM, the CEL was considerably thinner than the AEL, which may be a problem in practical applications. Then, by using different starting times of the first SSS+AA and second CMS grafting reactions, the CEL and AEL thicknesses was found to be controlled in RIAGP.


1984 ◽  
Vol 39 (1) ◽  
pp. 179-183 ◽  
Author(s):  
G. Quicker ◽  
A. Schumpe ◽  
W.-D. Deckwer

Membranes ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 346 ◽  
Author(s):  
Stanislav Melnikov ◽  
Denis Bondarev ◽  
Elena Nosova ◽  
Ekaterina Melnikova ◽  
Victor Zabolotskiy

Bilayer ion-exchange membranes are mainly used for separating single and multiply charged ions. It is well known that in membranes in which the layers have different charges of the ionogenic groups of the matrix, the limiting current decreases, and the water splitting reaction accelerates in comparison with monolayer (isotropic) ion-exchange membranes. We study samples of bilayer ion-exchange membranes with very thin cation-exchange layers deposited on an anion-exchange membrane-substrate in this work. It was revealed that in bilayer membranes, the limiting current’s value is determined by the properties of a thin surface film (modifying layer). A linear regularity of the dependence of the non-equilibrium effective rate constant of the water-splitting reaction on the resistance of the bipolar region, which is valid for both bilayer and bipolar membranes, has been revealed. It is shown that the introduction of the catalyst significantly reduces the water-splitting voltage, but reduces the selectivity of the membrane. It is possible to regulate the fluxes of salt ions and water splitting products (hydrogen and hydroxyl ions) by changing the current density. Such an ability makes it possible to conduct a controlled process of desalting electrolytes with simultaneous pH adjustment.


1977 ◽  
Vol 55 (1) ◽  
pp. 13-18 ◽  
Author(s):  
J. Landau ◽  
J. Boyle ◽  
H. G. Gomaa ◽  
A. M. Al Taweel

2021 ◽  
Author(s):  
Marius Milatz ◽  
Nicole Hüsener ◽  
Edward Andò ◽  
Gioacchino Viggiani ◽  
Jürgen Grabe

AbstractGauging the mechanical effect of partial saturation in granular materials is experimentally challenging due to the very low suctions resulting from large pores. To this end, a uniaxial (zero radial stress) compression test may be preferable to a triaxial one where confining pressure and membrane effects may erase the contribution of this small suction; however, volume changes are challenging to measure. This work resolves this limitation by using X-ray imaging during in situ uniaxial compression tests on Hamburg Sand and glass beads at three different initial water contents, allowing a suction-dependent dilation to be brought to the light. The acquired tomography volumes also allow the development of air–water and solid–water interfacial areas, water clusters and local strain fields to be measured at the grain scale. These measurements are used to characterise pertinent micro-scale quantities during shearing and to relate them to the measured macroscopic response. The new and well-controlled data acquired during this experimental campaign are hopefully a useful contribution to the modelling efforts—to this end they are shared with the community.


1995 ◽  
Vol 85 (3) ◽  
pp. 716-735 ◽  
Author(s):  
John F. Cassidy ◽  
Garry C. Rogers

Abstract On 6 April 1992, a magnitude 6.8 (MS) earthquake occurred in the triple-junction region at the northern end of the Cascadia subduction zone. This was the largest earthquake in at least 75 yr to occur along the 110-km-long Revere-Dellwood-Wilson (RDW) transform fault and the first large earthquake in this region recorded by modern broadband digital seismic networks. It thus provides an opportunity to examine the rupture process along a young (<2 Ma) oceanic transform fault and to gain better insight into the tectonics of this triple-junction region. We have investigated the source parameters and the rupture process of this earthquake by modeling broadband body waves and long-period surface waves and by accurately locating the mainshock and the first 10 days of aftershocks using a well-located “calibration” event recorded during an ocean-bottom seismometer survey. Analysis of P and SH waveforms reveals that this was a complex rupture sequence consisting of three strike-slip subevents in 12 sec. The initial rupture occurred 5 to 6 km to the SW of the seafloor trace of the RDW fault at 50.55° N, 130.46° W. The dominant subevent occurred 2 to 3 sec later and 4.3 km beneath the seafloor trace of the RDW fault, and a third subevent occurred 5 sec later, 18 km to the NNW, suggesting a northwestward propagating rupture. The aftershock sequence extended along a 60- to 70-km-long segment of the RDW fault, with the bulk of the activity concentrated ∼30 to 40 km to the NNW of the epicenter, consistent with this interpretation. The well-constrained mechanism of the initial rupture (strike/dip/slip 339°/90°/−168°) and of the largest aftershock (165°/80°/170°) are rotated 15° to 20° clockwise relative to the seafloor trace of the RDW fault but are parallel to the Pacific/North America relative plate motion vector. In contrast, the mechanisms of the dominant subevent (326°/87°/−172°), and the long-period solution derived from surface waves aligns with the RDW fault. This suggests that small earthquakes (M < 6) in this area occur along faults that are optimally aligned with respect to the regional stress field, whereas large earthquakes, involving tens of kilometers of rupture, activate the RDW fault. For the mainshock, we estimate a seismic moment (from surface waves) of 1.0 × 1026 dyne-cm, a stress drop of 60 bars, and an average slip of 1.2 m. This represents only 21 yr of strain accumulation, implying that there is either a significant amount of aseismic slip along the RDW fault or that much of the strain accumulation manifests itself as deformation within the Dellwood and Winona blocks or along the continental margin.


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