scholarly journals On Applicability of a Miniaturised Laser Ablation Time of Flight Mass Spectrometer for Trace Elements Measurements

2012 ◽  
Vol 2012 ◽  
pp. 1-14 ◽  
Author(s):  
Marek Tulej ◽  
Andreas Riedo ◽  
Maria Iakovleva ◽  
Peter Wurz
Keyword(s):  
Trace Elements ◽  
Laser Ablation ◽  
Mass Spectrometer ◽  
Dynamic Range ◽  
Plasma Chemistry ◽  
Isotopic Analysis ◽  
Radiometric Dating ◽  
Spectrometric Analysis ◽  
Laser Irradiance ◽  
Depth Analysis

We present results from mass spectrometric analysis of NIST standard materials and meteoritic samples conducted by a miniaturised laser ablation mass spectrometer designed for space research. The mass analyser supports investigation with a mass resolution () ≈ 500–600 and dynamic range within seven decades. Nevertheless, to maintain an optimal spectral quality laser irradiances lower than ~1 GW/cm2 are applied so far which results in a spread of RSC values. To achieve the quantitative performance of mass analyser, various effects influencing RSC factors have to be investigated. In this paper we investigate influence of laser irradiance, sampling procedure and plasma chemistry on the quantitative elemental and isotopic analysis. The studies indicate necessity for accurate control of laser characteristics and acquisition procedure. A relatively low irradiance applied causes a negligible sample damage and allows for accumulation of large number of waveforms from one sample location. The procedure yields statistically well averaged data and allows a sensitive in-depth analysis. The quantitative analyses of isotopic composition can be performed with accuracy and precision better as 1% and 2%, for isotopic patterns of elements and clusters, respectively. The numerical integration methods would be preferred to achieve more accurate results. The measurements of Allende sample yield detection of Pb isotopic pattern, nevertheless cluster species are readily observed in spectrum and make the elemental analysis of other trace elements difficult due to isobaric interferences. These detections are of a considerable interest because of possible application of the instrument for in situ elemental and isotopic analysis and radiometric dating of solids.

Improved detection sensitivity for heavy trace elements using a miniature laser ablation ionisation mass spectrometer

2017 ◽  
Vol 32 (11) ◽  
pp. 2182-2188 ◽  
Author(s):  
R. Wiesendanger ◽  
M. Tulej ◽  
A. Riedo ◽  
S. Frey ◽  
H. Shea ◽  
...  
Keyword(s):  
Trace Elements ◽  
Laser Ablation ◽  
Mass Spectrometer ◽  
Detection Sensitivity ◽  
Laser Spectrometer ◽  
Lunar Meteorite ◽  
Ionisation Mass ◽  
Ionisation Mass Spectrometer

Detecting heavy trace elements with a miniature laser spectrometer on a lunar meteorite.

Laser ablation-miniature mass spectrometer for elemental and isotopic analysis of rocks

2011 ◽  
Vol 82 (9) ◽  
pp. 094102 ◽  
Author(s):  
M. P. Sinha ◽  
E. L. Neidholdt ◽  
J. Hurowitz ◽  
W. Sturhahn ◽  
B. Beard ◽  
...  
Keyword(s):  
Laser Ablation ◽  
Mass Spectrometer ◽  
Isotopic Analysis ◽  
Miniature Mass Spectrometer

Gamma-Ray Spectrometric Analysis of Some Trace Elements in the Human Articular Disc of the Mandible

1963 ◽  
Vol 03 (02) ◽  
pp. 175-182 ◽  
Author(s):  
Bo Bergman ◽  
Rune Söremark
Keyword(s):  
Trace Elements ◽  
Neutron Activation ◽  
Quantitative Data ◽  
Thermal Neutron Flux ◽  
Gamma Ray ◽  
Dry Weight ◽  
Gamma Ray Spectrometry ◽  
Spectrometric Analysis ◽  
Articular Disc ◽  
Group Separation

SummaryBy means of neutron activation and gamma-ray spectrometry the concentrations in the human mandibular articular disc of the following elements have been determined: Na, Mn, Cu, Zn, Rb, Sr, Cd, W, and Au. The discs were obtained at necropsy from seven men and nine women, ranging in age from 56 to 71 years.The activation was carried out in a thermal neutron flux of about 1.7 XlO12 neutrons × cm−2 × sec.−1 for about 20 hours. A chemical group separationwas performed before the gamma-ray spectrometry. Quantitative data based on the dry weight of the cartilage samples were obtained by comparing the photo-peak area of the identified elements with those of appropriate standards.

In-depth Analysis of the Impurities in GaN

1996 ◽  
Vol 1 ◽  
Author(s):  
A. P. Kovarsky ◽  
V. S. Strykanov
Keyword(s):  
Secondary Ion Mass Spectrometry ◽  
Dynamic Range ◽  
Detection Limits ◽  
Background Level ◽  
Epitaxial Films ◽  
Depth Analysis ◽  
Lower Detection ◽  
Minimum Detection Level ◽  
Ion Yields ◽  
Secondary Ion

GaN epitaxial films were analyzed by Secondary Ion Mass Spectrometry (SIMS). Standard implanted samples were used to determine the appropriate analytical conditions for analysis of impurities. The dose and energy of implantation for selected elements (Mg, Al, Si, Zn, Cd, H, C and O) were chosen so the maximum impurity concentration was not more than 1020 atoms/cm3. The optimum analysis conditions were ascertained from the standards for each element, and the detection limits were deduced from the background levels of the implantation profiles. We demonstate that lower detection limits of 1015 atoms/cm3 with a dynamic range 103 − 105 are possible. Zn and Cd have low ion yields, so the minimum detection level for these elements is the background level of the detector. The detection limits of the other elements are determined by the contamination of an initial GaN matrix.

scholarly journals Detectivity optimization to detect of ultraweak light fluxes with an EM-CCD as binary photon counter array

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ibtissame Khaoua ◽  
Guillaume Graciani ◽  
Andrey Kim ◽  
François Amblard
Keyword(s):  
Dynamic Range ◽  
Signal To Noise Ratio ◽  
Photon Counting ◽  
Detection Methods ◽  
Strong Nonlinearity ◽  
Wide Range ◽  
Depth Analysis ◽  
Spatially Extended ◽  
Extended Sources ◽  
Photon Counting Mode

AbstractFor a wide range of purposes, one faces the challenge to detect light from extremely faint and spatially extended sources. In such cases, detector noises dominate over the photon noise of the source, and quantum detectors in photon counting mode are generally the best option. Here, we combine a statistical model with an in-depth analysis of detector noises and calibration experiments, and we show that visible light can be detected with an electron-multiplying charge-coupled devices (EM-CCD) with a signal-to-noise ratio (SNR) of 3 for fluxes less than $$30\,{\text{photon}}\,{\text{s}}^{ - 1} \,{\text{cm}}^{ - 2}$$ 30 photon s - 1 cm - 2 . For green photons, this corresponds to 12 aW $${\text{cm}}^{ - 2}$$ cm - 2 ≈ $$9{ } \times 10^{ - 11}$$ 9 × 10 - 11 lux, i.e. 15 orders of magnitude less than typical daylight. The strong nonlinearity of the SNR with the sampling time leads to a dynamic range of detection of 4 orders of magnitude. To detect possibly varying light fluxes, we operate in conditions of maximal detectivity $${\mathcal{D}}$$ D rather than maximal SNR. Given the quantum efficiency $$QE\left( \lambda \right)$$ Q E λ of the detector, we find $${ \mathcal{D}} = 0.015\,{\text{photon}}^{ - 1} \,{\text{s}}^{1/2} \,{\text{cm}}$$ D = 0.015 photon - 1 s 1 / 2 cm , and a non-negligible sensitivity to blackbody radiation for T > 50 °C. This work should help design highly sensitive luminescence detection methods and develop experiments to explore dynamic phenomena involving ultra-weak luminescence in biology, chemistry, and material sciences.

scholarly journals Coulomb-actuated microbeams revisited: experimental and numerical modal decomposition of the saddle-node bifurcation

2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Anton Melnikov ◽  
Hermann A. G. Schenk ◽  
Jorge M. Monsalve ◽  
Franziska Wall ◽  
Michael Stolz ◽  
...  
Keyword(s):  
Finite Element ◽  
Microelectromechanical Systems ◽  
Dynamic Range ◽  
Dynamic Performance ◽  
Major Step ◽  
Element Analysis ◽  
Electrostatic Actuators ◽  
Voltage Range ◽  
Drive Voltage ◽  
Depth Analysis

AbstractElectrostatic micromechanical actuators have numerous applications in science and technology. In many applications, they are operated in a narrow frequency range close to resonance and at a drive voltage of low variation. Recently, new applications, such as microelectromechanical systems (MEMS) microspeakers (µSpeakers), have emerged that require operation over a wide frequency and dynamic range. Simulating the dynamic performance under such circumstances is still highly cumbersome. State-of-the-art finite element analysis struggles with pull-in instability and does not deliver the necessary information about unstable equilibrium states accordingly. Convincing lumped-parameter models amenable to direct physical interpretation are missing. This inhibits the indispensable in-depth analysis of the dynamic stability of such systems. In this paper, we take a major step towards mending the situation. By combining the finite element method (FEM) with an arc-length solver, we obtain the full bifurcation diagram for electrostatic actuators based on prismatic Euler-Bernoulli beams. A subsequent modal analysis then shows that within very narrow error margins, it is exclusively the lowest Euler-Bernoulli eigenmode that dominates the beam physics over the entire relevant drive voltage range. An experiment directly recording the deflection profile of a MEMS microbeam is performed and confirms the numerical findings with astonishing precision. This enables modeling the system using a single spatial degree of freedom.

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