scholarly journals Geochemistry of the Neoarchaean Volcanic Rocks of the Kilimafedha Greenstone Belt, Northeastern Tanzania

2012 ◽  
Vol 2012 ◽  
pp. 1-18 ◽  
Author(s):  
Charles W. Messo ◽  
Shukrani Manya ◽  
Makenya A. H. Maboko
Keyword(s):  
Partial Melting ◽  
Greenstone Belt ◽  
Mantle Wedge ◽  
Spatial Association ◽  
Volcanic Rocks ◽  
Low Concentrations ◽  
Peridotite Mantle ◽  
Ree Patterns ◽  
Subducting Slab ◽  
Oceanic Slab

The Neoarchaean volcanic rocks of the Kilimafedha greenstone belt consist of three petrological types that are closely associated in space and time: the predominant intermediate volcanic rocks with intermediate calc-alkaline to tholeiitic affinities, the volumetrically minor tholeiitic basalts, and rhyolites. The tholeiitic basalts are characterized by slightly depleted LREE to nearly flat REE patterns with no Eu anomalies but have negative anomalies of Nb. The intermediate volcanic rocks exhibit very coherent, fractionated REE patterns, slightly negative to absent Eu anomalies, depletion in Nb, Ta, and Ti in multielement spidergrams, and enrichment of HFSE relative to MORB. Compared to the other two suites, the rhyolites are characterized by low concentrations of TiO2 and overall low abundances of total REE, as well as large negative Ti, Sr, and Eu anomalies. The three suites have a εNd (2.7 Ga) values in the range of −0.51 to +5.17. The geochemical features of the tholeiitic basalts are interpreted in terms of derivation from higher degrees of partial melting of a peridotite mantle wedge that has been variably metasomatized by aqueous fluids derived from dehydration of the subducting slab. The rocks showing intermediate affinities are interpreted to have been formed as differentiates of a primary magma formed later by lower degrees of partial melting of a garnet free mantle wedge that was strongly metasomatized by both fluid and melt derived from the subducting oceanic slab. The rhyolites are best interpreted as having been formed by shallow level fractional crystallization of the intermediate volcanic rocks involving plagioclase and Ti-rich phases like ilmenite and magnetite as well as REE-rich phases like apatite, zircon, monazite, and allanite. The close spatial association of the three petrological types in the Kilimafedha greenstone belt is interpreted as reflecting their formation in an evolving late Archaean island arc.

Petrogenesis of the Upper Cretaceous volcanism in the Kefken region, Western Pontides, NW Turkey

2021 ◽  
Author(s):  
Turgut Duzman ◽  
Ezgi Sağlam ◽  
Aral I. Okay
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Partial Melting ◽  
Upper Cretaceous ◽  
Volcanic Rocks ◽  
Early Eocene ◽  
Heavy Rare Earth ◽  
Heavy Rare Earth Elements ◽  
Cretaceous Volcanism ◽  
Oceanic Slab

<p>The Upper Cretaceous volcanic and volcaniclastic rocks crop out along the Black Sea coastline in Turkey. They are part of a magmatic arc that formed as a result of northward subduction of the Tethys ocean beneath the southern margin of Laurasia. The lower part of the Upper Cretaceous volcanism in the Kefken region, 100 km northeast of Istanbul, is represented by basaltic andesites, andesites, agglomerates and tuffs, which have yielded Late Cretaceous (Campanian, ca. 83 Ma) U-Pb zircon ages. The volcanic and volcanoclastic rocks are stratigraphically overlain by shallow to deep marine limestones, which range in age from Late Campanian to Early Eocene.  Geochemically, basaltic andesites and andesites display negative anomalies in Nb, Ta and Ti, enrichment in large ion lithophile elements (LILE) relative to high field strength elements (HFSE). Light rare earth elements (LREE) show slightly enrichment relative to heavy rare earth elements (La<sub>cn</sub>/Yb<sub>cn</sub> =2.51-3.63) and there are slight negative Eu anomalies (Eu/Eu* = 0.71-0.95) in basaltic andesite and andesite samples. The geochemical data indicate that Campanian volcanic rocks were derived from the partial melting of the mantle wedge induced by hydrous fluids released by dehydration of the subducted oceanic slab.</p><p>There is also a horizon of volcanic rocks, about 230 m thick, within the Late Campanian-Early Eocene limestone sequence.  This volcanic horizon, which consists of pillow basalts, porphyritic basalts,  andesites and dacites, is of Maastrichtian age based on paleontological data from the intra-pillow sediments and U-Pb zircon ages from the andesites and dacites (72-68 Ma).  The Maastrichtian andesites and dacites are geochemically distinct from the Campanian volcanic rocks. They show distinct adakite-like geochemical signatures with high ratios of Sr/Y (>85.5), high La<sub>cn</sub>/Yb<sub>cn </sub>(16.4-23.7) ratios, low content of Y (7.4-8.6 ppm) and low content of heavy rare-earth elements (HREE). The adakitic rocks most probably formed as a result of partial melting of the subducting oceanic slab under garnet and amphibole stable conditions.</p><p>The Upper Cretaceous arc sequence in the Kefken region shows a change from typical subduction-related magmas to adakitic ones, accompanied by decrease in the volcanism.</p><p> </p><p> </p>

Magmatic interaction between mantle and crust during the evolution of the Archean Lac Guyer greenstone belt, New Quebec

1988 ◽  
Vol 25 (5) ◽  
pp. 691-700 ◽  
Author(s):  
Karen St. Seymour ◽  
Don Francis
Keyword(s):  
Partial Melting ◽  
Greenstone Belt ◽  
Volcanic Rocks ◽  
Superior Province ◽  
James Bay ◽  
Volcanic Succession

The Lac Guyer greenstone belt was one of a series of volcanic troughs active during the Archean in the James Bay territory of the Superior Province of Quebec. The belt consists of a succession of isoclinally folded volcanic rocks comprising a lower sequence of basalts overlain by felsic tuffs and rhyodacites that are in turn succeeded by an upper sequence of basalt and komatiite. Plutons of granodioritic composition syntectonically intrude the volcanic succession. The development of this volcanic succession can be interpreted in terms of a model involving an intimate interaction between a differentiated crust and Mg-rich magmas rising from the mantle. Although some of these magmas reached the surface to erupt as komatiites, the majority were trapped at the base of the crust and fractionated towards basaltic compositions. This process caused partial melting of the base of the crust, which was probably mafic in composition, and produced granodioritic magmas whose derivative liquids erupted as rhyodacites.

scholarly journals Continental versus oceanic subduction zones

2016 ◽  
Vol 3 (4) ◽  
pp. 495-519 ◽  
Author(s):  
Yong-Fei Zheng ◽  
Yi-Xiang Chen
Keyword(s):  
Subduction Zones ◽  
Mantle Wedge ◽  
Ultrahigh Pressure ◽  
Metamorphic Rocks ◽  
Crustal Rocks ◽  
Incompatible Elements ◽  
Ultrahigh Temperature ◽  
Subducting Slab ◽  
Oceanic Slab ◽  
Metasomatized Mantle

Abstract Subduction zones are tectonic expressions of convergent plate margins, where crustal rocks descend into and interact with the overlying mantle wedge. They are the geodynamic system that produces mafic arc volcanics above oceanic subduction zones but high- to ultrahigh-pressure metamorphic rocks in continental subduction zones. While the metamorphic rocks provide petrological records of orogenic processes when descending crustal rocks undergo dehydration and anataxis at forearc to subarc depths beneath the mantle wedge, the arc volcanics provide geochemical records of the mass transfer from the subducting slab to the mantle wedge in this period though the mantle wedge becomes partially melted at a later time. Whereas the mantle wedge overlying the subducting oceanic slab is of asthenospheric origin, that overlying the descending continental slab is of lithospheric origin, being ancient beneath cratons but juvenile beneath marginal arcs. In either case, the mantle wedge base is cooled down during the slab–wedge coupled subduction. Metamorphic dehydration is prominent during subduction of crustal rocks, giving rise to aqueous solutions that are enriched in fluid-mobile incompatible elements. Once the subducting slab is decoupled from the mantle wedge, the slab–mantle interface is heated by lateral incursion of the asthenospheric mantle to allow dehydration melting of rocks in the descending slab surface and the metasomatized mantle wedge base, respectively. Therefore, the tectonic regime of subduction zones changes in both time and space with respect to their structures, inputs, processes and products. Ophiolites record the tectonic conversion from seafloor spreading to oceanic subduction beneath continental margin, whereas ultrahigh-temperature metamorphic events mark the tectonic conversion from compression to extension in orogens.

scholarly journals From Decompression Melting to Mantle-Wedge Refertilization and Metamorphism: Insights from Peridotites of the Alag Khadny Accretionary Complex (SW Mongolia)

Minerals ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 396 ◽  
Author(s):  
Marina Gornova ◽  
Anas Karimov ◽  
Sergei Skuzovatov ◽  
Vasiliy Belyaev
Keyword(s):  
Partial Melting ◽  
Mantle Wedge ◽  
Spreading Center ◽  
Accretionary Complex ◽  
Depleted Mantle ◽  
Basaltic Melt ◽  
Arc Setting ◽  
Late Neoproterozoic ◽  
Back Arc ◽  
Ree Patterns

This study reports on mineral and bulk rock compositions of metaperidotites from the Alag Khadny accretionary complex in SW Mongolia, to reveal their nature and relationships with associated eclogites. The peridotites preserved original porphyroclastic textures and are composed of olivine, orthopyroxene relics, Cr-spinel, interstitial (not residual) clinopyroxene, and secondary chlorite, tremolite, olivine, Cr-magnetite, clinopyroxene, and antigorite. Cr-spinel has Cr# of 0.3–0.5, and primary olivine shows Mg# of 0.90–0.92. The pyroxenes are high-magnesian with low Al2O3 and Cr2O3. The bulk rocks have U-shaped normalized trace-element patterns with enrichment in LILE, L-MREE relative to HREE, and weak Pb–Sr peaks and Nb–Zr–Hf minima. Interstitial clinopyroxene exhibits V- and U-shaped normalized REE patterns with (La/Yb)N > 1 (Yb = 1.2–3 of chondritic values) and enrichment in fluid-mobile elements and Zr. HREE abundances of clinopyroxene can be simulated by 23–26% partial melting of depleted mantle starting at garnet-facies (6–8%) depths, followed by hydrous or anhydrous melting at spinel-facies depths L-MREE characteristics of clinopyroxenes can be simulated by further interaction of harzburgites with an island-arc basaltic melt in a supra-subduction environment. The association of hydrous secondary minerals in the Alag Khadny peridotites suggests their retrograde metamorphism at 1.6–2.0 GPa and 640–720 °C, similar to P–T conditions reported earlier for the spatially associated eclogites. This supports metamorphism of the Alag Khadny peridotites in a mantle wedge, followed by joint exhumation of peridotites and eclogites. Given the findings above and implying the regional geological background, we advocate for a sequential Neoproterozoic evolution the Alag Khadny harzburgites from (1) their formation by decompression partial melting in an Early Neoproterozoic or older spreading center of a mid-ocean or back-arc setting, and (2) refertilization by supra-subduction melts, followed by (3) Late Neoproterozoic–Early Cambrian hydrous-fluid metamorphism and juxtaposition with eclogites.

Numerical simulation of subduction zone pressure-temperature-time paths: constraints on fluid production and arc magmatism

1991 ◽  
Vol 335 (1638) ◽  
pp. 341-353 ◽  
Keyword(s):  
Heat Transfer ◽  
Partial Melting ◽  
Subduction Zone ◽  
Subduction Zones ◽  
Mantle Wedge ◽  
Thermal Structure ◽  
Oceanic Lithosphere ◽  
Transfer Model ◽  
Temperature Time ◽  
Subducting Slab

The location and sequence of metamorphic devolatilization and partial melting reactions in subduction zones may be constrained by integrating fluid and rock pressure-temperature-time ( P-T-t ) paths predicted by numerical heat-transfer models with phase diagrams constructed for metasedimentary, metabasaltic, and ultramafic bulk compositions. Numerical experiments conducted using a two-dimensional heat transfer model demonstrate that the primary controls on subduction zone P-T-t paths are: (1) the initial thermal structure; (2) the amount of previously subducted lithosphere; (3) the location of the rock in the subduction zone; and (4) the vigour of mantle wedge convection induced by the subducting slab. Typical vertical fluid fluxes out of the subducting slab range from less than 0.1 to 1 (kg fluid) m -2 a -1 for a convergence rate of 3 cm a -1 . Partial melting of the subducting, amphibole-bearing oceanic crust is predicted to only occur during the early stages of subduction initiated in young (less than 50 Ma) oceanic lithosphere. In contrast, partial melting of the overlying mantle wedge occurs in many subduction zone experiments as a result of the infiltration of fluids derived from slab devolatilization reactions. Partial melting in the mantle wedge may occur by a twostage process in which amphibole is first formed by H 2 O infiltration and subsequently destroyed as the rock is dragged downward across the fluid-absent ‘hornblende-out’ partial melting reaction.

scholarly journals Mantle Evolution from Ocean to Arc: The Record in Spinel Peridotite Xenoliths in Mt. Pinatubo, Philippines

Minerals ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 515 ◽  
Author(s):  
Betchaida Payot ◽  
Shoji Arai ◽  
Masako Yoshikawa ◽  
Akihiro Tamura ◽  
Mitsuru Okuno ◽  
...  
Keyword(s):  
Partial Melting ◽  
Earth Element ◽  
Mantle Wedge ◽  
Chromian Spinel ◽  
Spinel Peridotite ◽  
Spinel Lherzolite ◽  
Mantle Evolution ◽  
Peridotite Xenoliths ◽  
Ree Patterns ◽  
Subsequent Modification

A suite of peridotite xenoliths were collected from lahar flow deposits located close to the summit of Mt. Pinatubo. Spinel harzburgite is the most dominant lithology among dunites, pyroxenites and websterites. A rare spinel lherzolite xenolith (P12-7) is also present in this suite. The spinel lherzolite has well-preserved protogranular texture with very minimal presence of secondary amphibole, low Cr# in the chromian spinel, and depleted and hump shaped patterns of chondrite-normalized rare earth element (REE) patterns for the clinopyroxenes. In contrast, the spinel harzburgites contain abundant secondary amphiboles and orthopyroxenes, higher Cr# in the spinel, and slightly elevated patterns for the chondrite-normalized REE patterns for the amphiboles. The spinel lherzolite also exhibits higher olivine Fo content for a given spinel Cr# compared to the spinel harzburgites. The spinel lherzolite is interpreted as a typical residue from partial melting of abyssal peridotites whereas the spinel harzburgites may have formed via partial melting with subsequent modification during the influx of fluids in the mantle wedge. Our results suggest that fragments of MOR-derived lithosphere exist in the mantle wedge beneath the Philippine island arc. This work provides evidence for the conversion of abyssal to arc peridotites in the mantle wedge.

Petrogenesis and tectonic implication of the lower Silurian high-Sr/Y subvolcanic rocks from the South Qilian suture zone in the Qilian Orogen, NW China

2021 ◽  
pp. 1-20
Author(s):  
Xiaohu He ◽  
Changlei Fu ◽  
Zhen Yan ◽  
Bingzhang Wang ◽  
Manlan Niu ◽  
...  
Keyword(s):  
Partial Melting ◽  
Volcanic Rocks ◽  
Foreland Basin ◽  
Late Ordovician ◽  
Suture Zone ◽  
The South ◽  
Lower Silurian ◽  
Peridotite Mantle ◽  
Spider Diagrams ◽  
Generation Mechanisms

Abstract As the remnant of the South Qilian Ocean, the South Qilian suture zone recorded abundant information on the Cambrian–Ordovician subduction history of the southern branch of the Proto-Tethyan Ocean. However, the closure timing of the South Qilian Ocean and subsequent collision are poorly constrained. In this study, we report early Silurian (433–435 Ma) U–Pb ages of felsic subvolcanic rocks from Lianhuashan, Ayishan and Shihuiyao of the Lajishan district within the South Qilian suture zone. They intruded the Late Ordovician – Silurian sedimentary or Late Ordovician volcanic rocks and have high SiO2 (61.43–73.06 wt%), Sr/Y ratios with significant different rare earth elements (REEs) and trace-element spider diagrams, and Sr–Nd isotopic compositions, probably implying that they were formed through distinctly different generation mechanisms. Geochemistry of the Lianhuashan dacites reveals compositions typical of adakitic rocks derived from partial melting of lower crust in a thickened setting. The Ayishan dacites were derived from partial melting of crustal materials with the involvement of minor peridotite mantle, and the Shihuiyao rhyolites were derived from partial melting of felsic crust. The similar geochemical characteristics of coeval post-collisional igneous rocks in the Central Qilian and South Qilian blocks indicates that the lower Silurian subvolcanic rocks were generated in a thickened crust of post-collisional setting. Considering their intrusive contacts with Late Ordovician – Silurian retro-foreland basin and Late Ordovician collisional volcanic rocks, we propose that the South Qilian suture zone was at a transitional stage from collisional to post-collisional during the early Silurian Period.

Early Cretaceous crust–mantle interaction linked to rollback of the Palaeo-Pacific flat-subducting slab: constraints from the intermediate–felsic volcanic rocks of the northern Great Xing’an Range, NE China

2021 ◽  
pp. 1-22
Author(s):  
Jia-Hao Jing ◽  
Hao Yang ◽  
Wen-Chun Ge ◽  
Yu Dong ◽  
Zheng Ji ◽  
...  
Keyword(s):  
Early Cretaceous ◽  
Volcanic Rocks ◽  
Geochemical Data ◽  
Calc Alkaline ◽  
Ne China ◽  
Asthenospheric Mantle ◽  
High K ◽  
Wide Range ◽  
Great Xing’An Range ◽  
Subducting Slab

Abstract Late Mesozoic igneous rocks are important for deciphering the Mesozoic tectonic setting of NE China. In this paper, we present whole-rock geochemical data, zircon U–Pb ages and Lu–Hf isotope data for Early Cretaceous volcanic rocks from the Tulihe area of the northern Great Xing’an Range (GXR), with the aim of evaluating the petrogenesis and genetic relationships of these rocks, inferring crust–mantle interactions and better constraining extension-related geodynamic processes in the GXR. Zircon U–Pb ages indicate that the rhyolites and trachytic volcanic rocks formed during late Early Cretaceous time (c. 130–126 Ma). Geochemically, the highly fractionated I-type rhyolites exhibit high-K calc-alkaline, metaluminous to weakly peraluminous characteristics. They are enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs) but depleted in high-field-strength elements (HFSEs), with their magmatic zircons ϵHf(t) values ranging from +4.1 to +9.0. These features suggest that the rhyolites were derived from the partial melting of a dominantly juvenile, K-rich basaltic lower crust. The trachytic volcanic rocks are high-K calc-alkaline series and exhibit metaluminous characteristics. They have a wide range of zircon ϵHf(t) values (−17.8 to +12.9), indicating that these trachytic volcanic rocks originated from a dominantly lithospheric-mantle source with the involvement of asthenospheric mantle materials, and subsequently underwent extensive assimilation and fractional crystallization processes. Combining our results and the spatiotemporal migration of the late Early Cretaceous magmatic events, we propose that intense Early Cretaceous crust–mantle interaction took place within the northern GXR, and possibly the whole of NE China, and that it was related to the upwelling of asthenospheric mantle induced by rollback of the Palaeo-Pacific flat-subducting slab.

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