scholarly journals The Development of a Mathematical Model for the Prediction of Corrosion Rate Behaviour for Mild Steel in 0.5 M Sulphuric Acid

2013 ◽  
Vol 2013 ◽  
pp. 1-9 ◽  
Author(s):  
I. Y. Suleiman ◽  
O. B. Oloche ◽  
S. A. Yaro
Keyword(s):  
Corrosion Rate ◽  
Mild Steel ◽  
Plant Extract ◽  
Acidic Medium ◽  
Sample Surface ◽  
Linear Regression Equation ◽  
Inhibitor Concentration ◽  
Influence Of Process Parameters ◽  
Rate Behaviour ◽  
Scanning Electron

The effect of varying temperature, concentration, and time on the corrosion rate of mild steel in 0.5 M H2SO4 acid with and without (wild jute tree) grewia venusta plant extract has been investigated by weight loss. The temperature, concentration of inhibitor and time were varied in the range of 0–10% v/v at 2% v/v interval, 30–70∘C at 20∘C interval, and 45–270 minutes at 45 minutes interval respectively. Scanning electron microscope was used to analyze the morphology of the sample surface. Linear regression equation and analysis of variance (ANOVA) were employed to investigate the influence of process parameters on the corrosion rate of the samples. The predicted corrosion rate of the samples was found to lie close to those experimentally observed ones. The confirmation of the experiment conducted using ANOVA to verify the optimal testing parameters shows that the increase in inhibitor concentration above 2% v/v and time would reduce the corrosion rate. The results also showed that the increase in temperature would also increase the corrosion rate greatly and that the plant extract was very effective for the corrosion inhibition of mild steel in acidic medium.

scholarly journals Anti-Corrosive Behavior of the Seed Extract of Amomum sabulatum

2021 ◽  
Vol 309 ◽  
pp. 01026
Author(s):  
Neha Daksh ◽  
Akhil Saxena ◽  
Jayahari Lade ◽  
Nakul Gupta
Keyword(s):  
Weight Loss ◽  
Electron Microscope ◽  
Corrosion Rate ◽  
Scanning Electron Microscope ◽  
Mild Steel ◽  
Plant Extract ◽  
Inhibition Efficiency ◽  
Protective Layer ◽  
Seed Extract ◽  
Scanning Electron

An aqueous extract of Amomum sabulatum seeds was evaluated for anticorrosive effects on mild steel in the presence of HCl. Weight loss measurements were taken to determine the corrosion rate and inhibition efficiency at various concentrations. With the increasing concentrations of plant extract, the results showed an improvement in inhibition efficiency and a decrease in corrosion rate. In the presence of 1500 ppm concentration of plant extract, it has an inhibition efficiency of 82.08 % at 303 K. The scanning electron microscope was used to examine the surface, which proves that while the extract was there, a protective layer formed on the metal surface.

ELECTROCHEMICAL INVESTIGATION OF 2-THIOHYDANTOIN DERIVATIVES AS CORROSION INHIBITORS FOR MILD STEEL IN ACIDIC MEDIUM

2021 ◽  
Author(s):  
Petar Stanić ◽  
◽  
Nataša Vukićević ◽  
Vesna Cvetković ◽  
Miroslav Pavlović ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Mild Steel ◽  
Acidic Medium ◽  
Corrosion Inhibitors ◽  
Electrochemical Impedance ◽  
Electrochemical Investigation ◽  
Force Microscopy ◽  
Atomic Force ◽  
Hcl Solution ◽  
Scanning Electron

Four 2-thiohydantoin derivatives were synthesized and their corrosion inhibition properties on mild steel (MS) in 0.5M HCl solution was evaluated using usual gravimetric and electrochemical methods (weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS). Morphology of the metal surface was characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The study has shown that these compounds provide good protection for mild steel against corrosion in the acidic medium.

scholarly journals A Comparative Study on the Corrosion Inhibition of Mild Steel and Aluminium by Synthesized Inhibitors in Organic Acidic Medium

2020 ◽  
pp. 41-51
Author(s):  
Lalita Saini ◽  
R. K. Upadhyay
Keyword(s):  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Acidic Medium ◽  
Trichloroacetic Acid ◽  
Inhibition Efficiency ◽  
Corrosion Inhibition Efficiency ◽  
Scanning Electron Microscope Method ◽  
Scanning Electron

Mass loss and Scanning Electron Microscope method (SEM) have been used to study the corrosion inhibition efficiency on mild steel and aluminium using synthesized inhibitors i.e. N-Benzylidene aniline (CI1) and N-Benzylidene 4-methylaniline (CI2) in Trichloroacetic acid (TCAA). Study reveals that both mild steel and aluminium are prone to corrosion in organic acid like TCAA. Out of these two metals, aluminium is more vigorously corroded by the TCAA in comparison to mild steel in same conditions and synthesized inhibitors CI1 and CI2 are almost same effective for mild steel and aluminium.

scholarly journals Study of Corrosion Behavior of N’-(2-(2-oxomethylpyrrol-1-yl)ethyl)piperidine for Mild Steel in the Acid Environment

2021 ◽  
Vol 12 (3) ◽  
pp. 3638-3646
Keyword(s):  
Electron Microscopy ◽  
Mild Steel ◽  
Steel Surface ◽  
Inhibition Efficiency ◽  
Protective Layer ◽  
Solution Temperature ◽  
Inhibitor Concentration ◽  
Acid Environment ◽  
Experimental Findings ◽  
Scanning Electron

The corrosion inhibition of mild steel in 1 M hydrochloric acid solution by N'-(2-(2-oxomethylpyrrol-1-yl)ethyl)piperidine (N-OPEP) was studied employing weight loss techniques. The experimental findings revealed that N-OPEP is the most excellent corrosion inhibitor, and the inhibitory performance increases with an increase in the inhibitor concentration. Furthermore, the inhibition efficiency decreases with an increase in the solution Temperature. The adsorption of inhibitor molecules on a mild steel surface followed Langmuir’s isotherm model and was found to be spontaneous. Scanning electron microscopy (SEM) photographs approved the formation of a protective layer of the inhibitor molecules on the surface of mild steel.

POLYVINYLPYROLLIDONE AND POLYACRYLAMIDE AS CORROSION INHIBITORS FOR MILD STEEL IN ACIDIC MEDIUM

2008 ◽  
Vol 15 (03) ◽  
pp. 277-286 ◽  
Author(s):  
S. A. UMOREN ◽  
I. B. OBOT
Keyword(s):  
Adsorption Isotherm ◽  
Corrosion Rate ◽  
Mild Steel ◽  
Acidic Medium ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Adsorption Process ◽  
Physical Adsorption ◽  
Activation Parameters ◽  
Temkin Adsorption Isotherm

The corrosion inhibition of mild steel in 1 M H 2 SO 4 in the presence of polyvinylpyrollidone (PVP) and polyacrylamide (PA) as inhibitors at 30–60°C was studied using gravimetric and gasometric techniques. The inhibition efficiency (1%) increased with increase in concentration of the inhibitors. Increase in temperature increased the corrosion rate in the absence and presence of inhibitors but decreased the inhibition efficiency. Both PVP and PA were found to obey Temkin adsorption isotherm and Kinetic-Thermodynamic Model of El-Awady at all the concentrations and temperatures studied. Phenomenon of physical adsorption is proposed from the activation parameters obtained. Thermodynamic parameters reveal that the adsorption process is spontaneous. PVP was found to be a better inhibitor than PA.

scholarly journals Green corrosion inhibition of mild steel using Prunus Dulcis seeds extract in an acidic medium

2020 ◽  
Vol 26 (2) ◽  
pp. 171-178
Author(s):  
Frederick Okhakumhe Oshomogho ◽  
Thelma Ejiro Akhihiero ◽  
Osariemen Edokpayi ◽  
Joy Ehimwenma Ossai
Keyword(s):  
Activation Energy ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Plant Extract ◽  
Steel Corrosion ◽  
Prunus Dulcis ◽  
Inhibitor Concentration ◽  
Mild Steel Corrosion ◽  
Soxhlet Apparatus ◽  
Inhibition Experiment

Synthetic inhibitors use by industries often have adverse effect on the environment. This work therefore investigates the use of plant extract as an  inhibition to mild steel corrosion in an acidic environment. Weight loss method was adopted to evaluate inhibition efficiency by plant extract as corrosion inhibitors. Almond seeds (Prunusdulcis) was extracted with the aid of Soxhlet apparatus. The corrosion inhibition experiment was  performed by setting up reactors containing mild steel coupon with variable concentrations of plant extract and 200ml of 1.5M HCl solution. The  study revealed that the extract was an efficient inhibitor and was most effective as the concentration increased from 0.81% at 0.01g/ml to 69.95% at 0.15g/ml respectively. Adsorption study on mild steel surface showed that the experimental data fitted better into the Temkin isotherm with regression R2 closer to unity. Arrhenius constant and activation energy estimated at temperatures 308K to 328K revealed that activation energy aE increased with increasing inhibitor concentration from 5348.23J/mol at 0.01g/ml to 6151.44J/mol at 0.05g/ml. The outcome of the study revealed  that mild steel is susceptible to corrosionwhich is capable of destroying the material and increasing inhibitor concentration and temperature has significant influence on the corrosion. Keywords: Mild steel, Corrosion, Inhibitor, Plant Extract, Adsorption

scholarly journals Variasi Konsentrasi Inhibitor Ekstrak Buah Harendong (Melastoma Affine D. Don) Pada Baja Per Daun Dengan Perlakuan Panas 300 Dan 700 °C Terhadap Laju Korosi Dalam Larutan NaCl 3%

2019 ◽  
Vol 7 (2) ◽  
pp. 187-196
Author(s):  
Dwi Kurniawan ◽  
◽  
Ediman Ginting Suka ◽  
Suprihatin Suprihatin ◽  
◽  
...  
Keyword(s):  
Crystal Structure ◽  
Heat Treatment ◽  
Weight Loss ◽  
Corrosion Rate ◽  
Surface Area ◽  
Sample Surface ◽  
Sem Analysis ◽  
Inhibitor Concentration ◽  
Fruit Extract ◽  
Eds Analysis

Research on variations in the concentration of inhibitors of harendong extract (Melastoma Affine D. Don) on steel per leaf with heat treatments 300 and 700 °C has been carried out on the corrosion rate in 3% nacl solution.The purpose of this study was to determine the efficiency of harendong fruit extract on the rate of koros in steel per leaf with heat treatment 300 and 700 °C. To determine the corrosion rate, the method of weight loss is used. The results showed that the efficiency of harendong fruit extract on the 5% inhibitor concentration at 300 °C was 90.345%. Based on the results of XRD in the sample Fe obtained with the Orthorombic crystal structure. Based on the results of SEM analysis and EDS the corroded sample surface area was reduced and fewer FeO levels in the sample were reduced. From the results of the corrosion rate and SEM and EDS analysis, it was found that the harendong fruit extract inhibitors were effective in inhibiting the corrosion rate in steel per leaf

Corrosion Inhibition of Mild Steel in Acidic Medium Using High Altitude Plant Extract

2018 ◽  
Vol 38 ◽  
pp. 48-57
Author(s):  
Roshan Lama ◽  
Anju Kumari Das ◽  
Brahamdeo Yadav ◽  
Yogesh Chaudhary ◽  
Prakash Chandra Lama ◽  
...  
Keyword(s):  
Mild Steel ◽  
High Altitude ◽  
Corrosion Inhibition ◽  
Plant Extract ◽  
Acidic Medium

Available with fulltext.

scholarly journals The mixture of dicyclohexilamine and oleylamine as corrosion inhibitor for mild steel in NaCl solution saturated with CO2 under both continual immersion and top of the line corrosion

2012 ◽  
Vol 77 (8) ◽  
pp. 1047-1061 ◽  
Author(s):  
Ivana Jevremovic ◽  
Aleksandra Debeljkovic ◽  
Marc Singer ◽  
Mohsen Achour ◽  
Srdjan Nesic ◽  
...  
Keyword(s):  
Weight Loss ◽  
Corrosion Rate ◽  
Mild Steel ◽  
Corrosion Inhibitor ◽  
Vapor Phase ◽  
Electrical Resistance ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Electrical Resistance Measurements ◽  
Scanning Electron

This paper presents a comprehensive method to evaluate the mixture of dicyclohexilamine and oleylamine (DCHA+OA) as corrosion inhibitor for mild steel in CO2 environment in liquid and vapor phase. Corrosion inhibitor volatile properties were investigated in order to determine if DCHA+OA can be used to control the severity of the top of the line (TLC) corrosion attack. Corrosion measurements were performed using electrochemical impedance spectroscopy, linear polarization resistance, potentiodynamic sweep measurements, as well as the electrical resistance measurements and weight loss measurements, in order to determine the inhibitive performances of dicyclohexilamine and oleylamine. In order to define surface morphological characteristics scanning electron microscopy technique was applied. The electrochemical study and weight loss measurements indicated that DCHA+OA significantly decreased the corrosion rate in liquid phase when 50 ppm of DCHA+OA was added. Scanning electron microphotographs indicated protective inhibitor film has formed on the steel surface and revealed that good protection was achieved, along with the decrease in the corrosion rate determined by weight loss and electrochemical techniques. Using electrical resistance measurements in vapor phase it was shown that concentration of 1000 ppm DCHA+OA significantly decreased the corrosion rate at the top of the line, only when it was carried there within its own foam and not due its volatility.

scholarly journals Synthesis New Pyridinium Salts as Corrosion Inhibitors for Mild Steel in 1 M H2SO4

2021 ◽  
Vol 24 (2) ◽  
pp. 14-20
Author(s):  
Rania Kareem Hameed ◽  
◽  
Mehdi Salih Shihab ◽  
Keyword(s):  
Weight Loss ◽  
Free Energy ◽  
Corrosion Rate ◽  
Mild Steel ◽  
Corrosion Inhibitors ◽  
Organic Molecules ◽  
Inhibition Efficiency ◽  
Pyridinium Salts ◽  
Inhibitor Concentration ◽  
Pyridinium Bromide

Some new pyridinium salts, namely 4-(4-Chloro-benzylidene-hydrazinocarbonyl)-1-phenyl-pyridinium bromide, C1; 4-(4-Chloro-benzylidene-hydrazinocarbonyl)-1-butyl-pyridinium bromide, C2; 4-(4-Chloro-benzylidene-hydrazinocarbonyl)-1-phencyl-pyridinium bromide, C3; were synthesized and Corrosion inhibitors for mild steel were tested in a 1M H2SO4aqueous solution at 20ºC for 24 hours using weight loss measurements. The findings revealed that the inhibition efficiency of all pyridinium bromide derivatives converges at the maximum concentration. An increase in inhibitor concentration is associated with a decrease in corrosion rate, an increase in inhibition efficiencies, and an increase in surface degree of coverage. The physisorption effects for (C1, C2, and C3) were revealed by the free energy values of adsorption, which provided useful information for predicting the interaction between the metal surface and organic molecules as corrosion inhibitors.

Sign in / Sign up

Export Citation Format

Share Document