scholarly journals Pilot-Scale Removal of Trace Steroid Hormones and Pharmaceuticals and Personal Care Products from Municipal Wastewater Using a Heterogeneous Fenton’s Catalytic Process

2013 ◽  
Vol 2013 ◽  
pp. 1-10 ◽  
Author(s):  
George Tangyie Chi ◽  
John Churchley ◽  
Katherine D. Huddersman
Keyword(s):  
Wastewater Treatment ◽  
Municipal Wastewater ◽  
Personal Care Products ◽  
Endocrine Disrupting Compounds ◽  
Pilot Scale ◽  
Treatment System ◽  
Continuous Stir Tank Reactor ◽  
Stir Tank Reactor ◽  
Municipal Wastewater Treatment ◽  
Personal Care

The pollution of water sources by endocrine disrupting compounds (EDCs) and pharmaceutical and personal care products (PPCPs) is a growing concern, as conventional municipal wastewater treatment systems are not capable of completely removing these contaminants. A continuous stir tank reactor incorporating a modified polyacrylonitrile (PAN) catalyst and dosed with hydrogen peroxide in a heterogeneous Fenton’s process was used at pilot scale to remove these compounds from wastewater that has undergone previous treatment via a conventional wastewater treatment system. The treatment system was effective at ambient temperature and at the natural pH of the wastewater. High levels of both natural and synthetic hormones (EDCs) and PPCPs were found in the effluent after biological treatment of the wastewater. The treatment system incorporating the modified PAN catalyst/H2O2decomposed >90% of the EDCs and >40% of PPCPs using 200 mgL−1H2O2, 3 hr residence time. The estrogenic potency EE2-EQ was removed by 82.77%, 91.36%, and 96.13% from three different wastewater treatment plants. BOD was completely removed (below detection limits); 30%–40% mineralisation was achieved and turbidity reduced by more than 68%. There was a <4% loss in iron content on the catalyst over the study period, suggesting negligible leaching of the catalyst.

scholarly journals Effect of O3 Dose on the O3/UV Treatment Process for the Removal of Pharmaceuticals and Personal Care Products in Secondary Effluent

2019 ◽  
Vol 3 (2) ◽  
pp. 53 ◽  
Author(s):  
N. Evelin Paucar ◽  
IIho Kim ◽  
Hiroaki Tanaka ◽  
Chikashi Sato
Keyword(s):  
Municipal Wastewater ◽  
Treatment Process ◽  
Limit Of Detection ◽  
Personal Care Products ◽  
Treatment Plant ◽  
Pilot Scale ◽  
Secondary Effluent ◽  
Municipal Wastewater Treatment ◽  
Personal Care ◽  
Uv Treatment

A municipal wastewater treatment plant (WWTP) is a melting pot of numerous pharmaceuticals and personal care products (PPCPs) together with many other substances. The removal of PPCPs using advanced oxidation processes within a WWTP is one way to reduce the amount of PPCPs that potentially enter an aquatic environment. The aim of this study was to examine the effectiveness of the ozone (O3)/UV treatment process, especially, the effects of O3 dose and reaction time, on the removal of PPCPs in the secondary effluent of a WWTP. Experiments were conducted using a pilot-scale treatment process that consisted of two flow-through reactors connected in series. Each reactor was equipped with three 65 W lamps (UV65W). The experimental variables were ozone dosage (1, 2, 3, 4, and 6 mg L−1) and hydraulic retention time (HRT; 5 and 10 min). On the basis of the PPCP concentrations after O3/UV65W treatment and their limit of detection (LOD), 38 PPCPs detected in the secondary effluent were classified into 5 groups ranging from the category of “sensitive” to O3/UV65W or “unstable” in the O3/UV65W process to the category of “insensitive” to O3/UV65W or “very stable” in the O3/UV65W process.

Nanofiltration of endocrine disrupting compounds

2003 ◽  
Vol 3 (5-6) ◽  
pp. 321-327 ◽  
Author(s):  
M. Gallenkemper ◽  
T. Wintgens ◽  
T. Melin
Keyword(s):  
Wastewater Treatment ◽  
Municipal Wastewater ◽  
Wastewater Treatment Plants ◽  
Endocrine Disrupting Compounds ◽  
Municipal Wastewater Treatment ◽  
Water And Wastewater Treatment ◽  
Wide Range ◽  
Endocrine Disrupting ◽  
Municipal Wastewater Treatment Plants ◽  
Set Up

Endocrine disrupting compounds can affect the hormone system in organisms. A wide range of endocrine disrupters were found in sewage and effluents of municipal wastewater treatment plants. Toxicological evaluations indicate that conventional wastewater treatment plants are not able to remove these substances sufficiently before disposing effluent into the environment. Membrane technology, which is proving to be an effective barrier to these substances, is the subject of this research. Nanofiltration provides high quality permeates in water and wastewater treatment. Eleven different nanofiltration membranes were tested in the laboratory set-up. The observed retention for nonylphenol (NP) and bisphenol A (BPA) ranged between 70% and 100%. The contact angle is an indicator for the hydrophobicity of a membrane, whose influence on the permeability and retention of NP was evident. The retention of BPA was found to be inversely proportional to the membrane permeability.

Performance of hybrid small wastewater treatment system consisting of jet mixed separator and rotating biological contactor

1997 ◽  
Vol 35 (6) ◽  
pp. 63-70 ◽  
Author(s):  
Yoshimasa Watanabe ◽  
Yoshihiko Iwasaki
Keyword(s):  
Wastewater Treatment ◽  
Electric Power ◽  
Hybrid System ◽  
Municipal Wastewater ◽  
Treatment Plant ◽  
Treatment System ◽  
Municipal Wastewater Treatment ◽  
Wastewater Treatment System ◽  
Pre Treatment ◽  
Organic Particles

This paper describes a pilot plant study on the performance of a hybrid small municipal wastewater treatment system consisting of a jet mixed separator(JMS) and upgraded RBC. The JMS was used as a pre-treatment of the RBC instead of the primary clarifier. The treatment capacity of the system was fixed at 100 m3/d, corresponding to the hydraulic loading to the RBC of 117 L/m2/d. The effluent from the grid chamber at a municipal wastewater treatment plant was fed into the hybrid system. The RBC was operated using the electric power produced by a solar electric generation panel with a surface area of 8 m2 under enough sunlight. In order to reduce the organic loading to the RBC, polyaluminium chloride(PAC) was added to the JMS influent to remove the colloidal and suspended organic particles. At the operational condition where the A1 dosage and hydraulic retention time of the JMS were fixed at 5 g/m3 and 45 min., respectively, the average effluent water quality of hybrid system was as follows: TOC=8 g/m3, Total BOD=8 g/m3, SS=8 g/m3, Turbidity=6 TU, NH4-N=7 g/m3, T-P=0.5 g/m3. In this operating condition, electric power consumption of the RBC for treating unit volume of wastewater is only 0.07 KWH/m3.

Potential use of mangrove plantation as constructed wetland for municipal wastewater treatment

2003 ◽  
Vol 48 (5) ◽  
pp. 257-266 ◽  
Author(s):  
K. Boonsong ◽  
S. Piyatiratitivorakul ◽  
P. Patanaponpaiboon
Keyword(s):  
Wastewater Treatment ◽  
Constructed Wetland ◽  
Municipal Wastewater ◽  
Free Water ◽  
Avicennia Marina ◽  
Pilot Scale ◽  
Natural Forest ◽  
Municipal Wastewater Treatment ◽  
Detention Time ◽  
Bruguiera Cylindrica

The study evaluated the possibility of using mangrove plantation to treat municipal wastewater. Two types of pilot scale (100 × 150 m2) free water surface constructed wetland were set up. One system was a natural Avicennia marina dominated forest system. The other system was a newly planted system in which seedlings of Rhizophora spp., A. marina, Bruguiera cylindrica and Ceriops tagal were planted in 4 strips. Municipal wastewater was retained within the systems for 7 and 3 days, respectively. The results indicated that the average removal percentage of TSS, BOD, NO3-N, NH4-N, TN, PO4-P and TP in the newly planted system were 27.6-77.1, 43.9-53.9, 37.6-47.5, 81.1-85.9, 44.8-54.4, 24.7-76.8 and 22.6-65.3, respectively. Whereas the removal percentage of those parameters in the natural forest system were 17.1-65.9, 49.5-51.1, 44.0-60.9, 51.1-83.5, 43.4-50.4, 28.7-58.9 and 28.3-48.0, respectively. Generally, the removal percentages within the newly planted system and the natural forest system were not significantly different. However, when the removal percentages were compared with detention time, TSS, PO4-P and TP percentages removed were significantly higher in the 7-day detention time treatment. Even though the removal percentages were highly varied and temporally dependent, the overall results showed that mangrove plantation could be used as constructed wetland for municipal wastewater treatment in a similar way to the natural mangrove system.

A proposed sustainable BNR plant with the emphasis on recovery of COD and phosphate

2003 ◽  
Vol 48 (1) ◽  
pp. 77-85 ◽  
Author(s):  
X.-D. Hao ◽  
M.C.M. van Loosdrecht
Keyword(s):  
Wastewater Treatment ◽  
Municipal Wastewater ◽  
Water Environment ◽  
Pilot Scale ◽  
Ammonium Oxidation ◽  
Municipal Wastewater Treatment ◽  
Nitrogen And Phosphorus ◽  
Water Problems ◽  
Sustainable Wastewater Treatment ◽  
The Impact

Water problems have to be solved in an integrated way, and sustainability has become a major issue. For this reason, developing more sustainable wastewater treatment processes is needed. New discoveries and good understanding on microbial conversions of nitrogen and phosphorus make more sustainable processes possible. New options for decentralized sustainable sanitation are generally compared to conventional sewage systems, we think that for a proper comparison also innovative centralized treatment schemes should be evaluated. In this article, a more sustainable WWTP is proposed for municipal wastewater treatment, mainly based on the principles of denitrifying dephosphatation and anaerobic ammonium oxidation (ANAMMOX). The proposed system consists of a first stage of the A/B process in which maximal sludge production is achieved. In this way, COD is regained as sludge for methanation. The following BCFS® and CANON processes can remove N and P with minimal or no COD need. As a potential fertiliser, struvite can easily be removed from the sludge water by adding magnesium compounds. A case study is done on the basis of the mass balance over the proposed plant. The effluent from the system has a good quality to be recycled. This could also make a contribution to meeting the world's water needs and lessening the impact on the world's water environment. Since all the separate units are already applied or tested on pilot-scale, no problems for technical implementation are foreseen.

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