scholarly journals Electrochemical Investigation of Catechol at Poly(niacinamide) Modified Carbon Paste Electrode: A Voltammetric Study

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
A. B. Teradale ◽  
S. D. Lamani ◽  
B. E. Kumara Swamy ◽  
P. S. Ganesh ◽  
S. N. Das
Keyword(s):  
Carbon Paste Electrode ◽  
Limit Of Detection ◽  
Phosphate Buffer Solution ◽  
Modified Carbon Paste Electrode ◽  
Rate Variation ◽  
Carbon Paste ◽  
Buffer Solution ◽  
Limit Of Quantification ◽  
Paste Electrode

A polymeric thin film modified electrode, that is, poly(niacinamide) modified carbon paste electrode (MCPE), was developed for the electrochemical determination of catechol (CC) by using cyclic voltammetric technique. Compared to bare carbon paste electrode (BCPE), the poly(niacinamide) MCPE shows good electrocatalytic activity towards the oxidation of catechol in phosphate buffer solution (PBS) of physiological pH 7.4. All experimental parameters were optimized. Poly(niacinamide) modified carbon paste electrode gave a linear response between concentration of CC and its anodic peak current in the range within 20.6–229.0 μM. The limit of detection (3S/M) and limit of quantification (10S/M) were 1.497 μM and 4.99 μM, respectively. From the study of scan rate variation, the electrode process was found to be adsorption-controlled. The involvement of protons and electrons in the oxidation of CC was found to be equal. The probable electropolymerisation mechanism of niacinamide was proposed. Finally, this method can be used in development of a sensor for sensitive determination of CC.

Voltammetric study of secnidazole and its determination in pharmaceutical tablet using 1, 4-benzoquinone modified carbon paste electrode

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Carbon Paste Electrode ◽  
Limit Of Detection ◽  
Modified Carbon Paste Electrode ◽  
Carbon Paste ◽  
Buffer Solution ◽  
Limit Of Quantification ◽  
Pharmaceutical Tablet ◽  
Relative Standard ◽  
Paste Electrode

In this study voltammetric behaviour of secnidazole (SCZ) at 1, 4-Benzoquinone Modified Carbon Paste Electrode (1,4-BQMCPE) was investigated in Britton Robinson buffer solution using cyclic voltammetric technique. A well-defined cathodic peak was observed for the SCZ in the entire pH range. The current increases steadily with scan rate and the results indicated that the process is irreversible reduction and adsorption controlled. The number of electrons transferred and different kinetic parameters like transfer coefficient and rate constant were calculated by using cyclic voltammetry technique. Differential pulse voltammetric method has been used for the determination of SCZ content in pharmaceutical tablet. This method enabled to determine SCZ in the concentration range 1.0 × 10-8 to 4.0 × 10-4 M. The limit of detection (LOD) and limit of quantification (LOQ) were found to be 2.13 × 10-9 and 2.85 × 10-9 respectively. The method was applied to determine the content of SCZ in different sample solutions of SCZ tablet with excellent recovery and relative standard deviation results (99.892±1.53 respectively) for spiked standard SCZ in tablet sample solutions. The selectivity of the method for SCZ was further studied in the presence of selected potential interferents such as fluconazole, azithromycin etc and confirmed the potential applicability of the developed method for the determination of SCZ in real pharmaceutical tablets.

scholarly journals Electro-Polymerized Titan Yellow Modified Carbon Paste Electrode for the Analysis of Curcumin

Surfaces ◽  
2021 ◽  
Vol 4 (3) ◽  
pp. 191-204
Author(s):  
Edwin S. D’Souza ◽  
Jamballi G. Manjunatha ◽  
Chenthattil Raril ◽  
Girish Tigari ◽  
Huligerepura J. Arpitha ◽  
...  
Keyword(s):  
Carbon Paste Electrode ◽  
Limit Of Detection ◽  
Phosphate Buffer Solution ◽  
Modified Carbon Paste Electrode ◽  
Carbon Paste ◽  
Buffer Solution ◽  
Solution Ph ◽  
Real Sample Analysis ◽  
Titan Yellow ◽  
Paste Electrode

A modest, efficient, and sensitive chemically modified electrode was fabricated for sensing curcumin (CRC) through an electrochemically polymerized titan yellow (TY) modified carbon paste electrode (PTYMCPE) in phosphate buffer solution (pH 7.0). Cyclic voltammetry (CV) linear sweep voltammetry (LSV) and differential pulse voltammetry (DPV) approaches were used for CRC detection. PTYMCPE interaction with CRC suggests that the electrode exhibits admirable electrochemical response as compared to bare carbon paste electrode (BCPE). Under the optimized circumstances, a linear response of the electrode was observed for CRC in the concentration range 2 × 10−6 M to 10 × 10−6 M with a limit of detection (LOD) of 10.94 × 10−7 M. Moreover, the effort explains that the PTYMCPE electrode has a hopeful approach for the electrochemical resolution of biologically significant compounds. Additionally, the proposed electrode has demonstrated many advantages such as easy preparation, elevated sensitivity, stability, and enhanced catalytic activity, and can be successfully applied in real sample analysis.

Electrocatalytic performance of a zinc sulphide nanoparticles-modified carbon paste electrode for the simultaneous determination of acetaminophen, guanine and adenine

2018 ◽  
Vol 10 (11) ◽  
pp. 1362-1371 ◽  
Author(s):  
Mallappa Mahanthappa ◽  
Nagaraju Kottam ◽  
Shivaraj Yellappa
Keyword(s):  
Carbon Paste Electrode ◽  
Phosphate Buffer ◽  
Phosphate Buffer Solution ◽  
Zinc Sulphide ◽  
Modified Carbon Paste Electrode ◽  
Carbon Paste ◽  
Buffer Solution ◽  
Guanine And Adenine ◽  
Paste Electrode

The simultaneous electroanalysis of acetaminophen (AC), guanine (G) and adenine (A) was successfully achieved on the zinc sulphide nanoparticles-modified carbon paste electrode (ZnS NPs/CPE) in phosphate buffer solution (PBS).

Enhanced Electrochemical Determination Of Riboflavin In Biological And Pharmaceutical Samples At Poly (Arginine) Modified Carbon Paste Electrode

2019 ◽  
Vol 14 (4) ◽  
pp. 216-223 ◽  
Author(s):  
Girish Tigari ◽  
J.G. Manjunatha ◽  
D.K. Ravishankar ◽  
G. Siddaraju
Keyword(s):  
Carbon Paste Electrode ◽  
Limit Of Detection ◽  
Phosphate Buffer Solution ◽  
Differential Pulse ◽  
Modified Carbon Paste Electrode ◽  
Current Response ◽  
Carbon Paste ◽  
Serum Samples ◽  
Buffer Solution ◽  
Paste Electrode

An electrogenerated Polyarginine modified carbon paste electrode (PAMCPE) was fabricated through a simple electropolymerization procedure. The devised electrode was characterized by cyclic voltammetry (CV) and Field Emission Scanning Electron Microscopy (FESEM). This electrode was utilized for electrocatalytic estimation of Riboflavin (RF) and its instantaneous resolution with ascorbic acid (AA) and folic acid (FA) in phosphate buffer solution (PBS) of pH 6.0 by differential pulse voltammetry (DPV). It was observed to be a very responsive electrode for the electrochemical detection and quantification of RF. It was revealed that PAMCPE generates higher current response towards RF contrast to the bare carbon paste electrode (BCPE). Under optimized condition, the RF oxidation current values were linearly reliant on the RF concentration increment with a limit of detection (LOD) of 9.3·10-8 M using DPV. The stable PAMCPE was effectively applied for estimation of RF in B-complex pill and complex human blood serum samples.

scholarly journals Voltammetric determination of phenylephrine hydrochloride using a multi-walled carbon nanotube-modified carbon paste electrode

2018 ◽  
Vol 5 (12) ◽  
pp. 181264 ◽  
Author(s):  
Q. Zhou ◽  
H. Y. Zhai ◽  
Y. F. Pan
Keyword(s):  
Carbon Paste Electrode ◽  
Electrochemical Behaviour ◽  
Saturated Calomel Electrode ◽  
Phosphate Buffer Solution ◽  
Modified Carbon Paste Electrode ◽  
Carbon Paste ◽  
Buffer Solution ◽  
Phenylephrine Hydrochloride ◽  
Paste Electrode

A chemically modified carbon paste electrode (CPE) was designed by mixing graphite and multi-walled carbon nanotubes (MWCNT). The electrochemical behaviour was studied, and the determination method of phenylephrine hydrochloride (PHE) on this sensor was established. According to the results, the optimal ratio of MWCNTs was approximately 12.5% (w/w). MWCNT-modified carbon paste electrodes (MWCNT-CPEs) showed high electrochemical activity for PHE, producing a sharp oxidation peak current ( I p ) at approximately +0.816 V versus a saturated calomel electrode (SCE) reference electrode in phosphate buffer solution (PBS, pH 6.45), and the I p increased by approximately two times compared to that of the bare CPE. The anodic I p was linearly related with 5.0 × 10 −6 –7.5 × 10 −4 mol l −1 PHE, with a detection limit of 3.7 × 10 −7 mol l −1 . Furthermore, MWCNT-CPEs were successfully applied to the determination of PHE in injection, eye drop and nasal spray liquid samples as a simple, rapid and low-cost method.

scholarly journals Electrochemical analysis of indigo carmine using polyarginine modified carbon paste electrode

2021 ◽  
Author(s):  
D'Souza S. Edwin ◽  
Jamballi G. Manjunatha ◽  
Chenthattil Raril ◽  
Tigari Girish ◽  
Doddarasinakere K. Ravishankar ◽  
...  
Keyword(s):  
Carbon Paste Electrode ◽  
Limit Of Detection ◽  
Indigo Carmine ◽  
Electrochemical Analysis ◽  
Modified Carbon Paste Electrode ◽  
Carbon Paste ◽  
Limit Of Quantification ◽  
Selective Determination ◽  
Paste Electrode

Suitable electro-catalytic technique is established for the selective determination of Indigo Carmine (IC) at poly(arginine) modified carbon paste electrode (PAMCPE). The surface morphological study of the electrode is done through Field Emission Scanning Electron Microscopy (FESEM). The different parameters such as concentration, pH and scan rate on the electrode response are studied. The individual and simultaneous performance of IC and Riboflavin (RF) is carried out through differential pulse voltammetry. The electrocatalytic response of the sensor varied with the concentration of IC in the range from 2×10-7 M to 1×10-6 M and 1.5×10-6 M to 3.5×10-6 M is observed. Limit of detection (LOD) and the limit of quantification (LOQ) is found 2.53×10-8 M and 8.43×10-8 M respectively. The developed PAMCPE successfully shows better electrochemical response towards IC when compared with BCPE. Preparation and characterization of both the electrodes is simple and easier. This has derived a standard method for the determination of IC in real samples.      

Microwave-assisted synthesis of NaA nanozeolite from slag and performance of Ag-doped nanozeolite as an efficient material for determination of hydrogen peroxide

RSC Advances ◽  
2016 ◽  
Vol 6 (57) ◽  
pp. 52058-52066 ◽  
Author(s):  
Seyed Naser Azizi ◽  
Shahram Ghasemi ◽  
Mehrnaz Mikhchian
Keyword(s):  
Hydrogen Peroxide ◽  
Phosphate Buffer Solution ◽  
Modified Carbon Paste Electrode ◽  
Microwave Assisted Synthesis ◽  
Carbon Paste ◽  
Buffer Solution ◽  
Microwave Assisted ◽  
And Performance ◽  
Paste Electrode

A new amperometric sensor is prepared based on a Ag doped NaA nanozeolite modified carbon paste electrode (Ag/ACPE) in order to detect hydrogen peroxide (H2O2) in phosphate buffer solution (PBS, pH 7.0).

scholarly journals Online Coupling of Lab-on-Valve Format to Amperometry Based on Polyvinylpyrrolidone-Doped Carbon Paste Electrode and Its Application to the Analysis of Morin

2012 ◽  
Vol 2012 ◽  
pp. 1-8 ◽  
Author(s):  
Yang Wang ◽  
Guojun Yao ◽  
Jie Tang ◽  
Chun Yang ◽  
Qin Xu ◽  
...  
Keyword(s):  
Carbon Paste Electrode ◽  
Supporting Electrolyte ◽  
Phosphate Buffer Solution ◽  
Current Response ◽  
Oxidation Peak ◽  
Carbon Paste ◽  
Buffer Solution ◽  
Electrochemical Behaviors ◽  
Paste Electrode

The potential capabilities and analytical performance of lab-on-valve (LOV) manifold as a front end to amperometry have been explored for the on-line determination of morin. Meanwhile, the electrochemical behaviors of morin were investigated based on polyvinylpyrrolidone- (PVP-) doped carbon paste electrode (CPE), which found that PVP can significantly improve its oxidation peak current. The excellent amperometric current response was achieved when the potential difference (ΔE) of 0.6 V was implemented in pH 6.5 phosphate buffer solution (PBS) that served as the supporting electrolyte. A well-defined oxidation peak has been obtained in studies using PVP as a modifier of CPE based on the oxidation of morin. The present work introduces the LOV technique as a useful tool for amperometric measurement, documents advantages of using programmable flow, and outlines means for miniaturization of assays on the basis of PVP modified CPE. The proposed method was applied successfully to the determination of morin in real samples, and the spiked recoveries were satisfactory.

scholarly journals Electrocatalytic determination of levodopa in presence of cabergoline using carbon paste electrode modified with graphene quantum dots/2-chlorobenzoyl ferrocene/ionic liquid

2021 ◽  
Author(s):  
Peyman Mohammadzadeh Jahani
Keyword(s):  
Quantum Dots ◽  
Ionic Liquid ◽  
Carbon Paste Electrode ◽  
Limit Of Detection ◽  
Graphene Quantum Dots ◽  
Simultaneous Detection ◽  
Phosphate Buffer Solution ◽  
Carbon Paste ◽  
Paste Electrode

The electrochemical sensor was fabricated for the simultaneous determination of levodopa and cabergoline using carbon paste electrode (CPE) modified with graphene quantum dots (GQD), 2-chlorobenzoyl ferrocene (2CBF) and ionic liquid (IL). Then, the electrochemical behavior of levodopa alone and simultaneously with cabergoline at the surface of GQDs/2CBF/IL/CPE was investigated in phosphate buffer solution (PBS). Under optimal PBS, pH=7 condition, oxidation peak current has been found proportional to levodopa concentration in the range between 0.07 μM and 500.0 μM, with the limit of detection (LOD) of 0.02 μM (S/N=3). Outputs showed that at GQDs/2CBF/IL/CPE surface, the levodopa and cabergoline oxidation peaks are separated by the potential difference of 200 mV. In addition, it was found that this modified electrode possesses acceptable sensitivity, selectivity, stability and repeatability. All these properties were sufficient to allow simultaneous detection of levodopa and cabergoline in real samples at the surface of GQDs/2CBF/IL/CPE. This was supported by the successful application of this electro­chemical sensor electrode for the determination of levodopa and cabergoline in urine, serum, and cabergoline tablets.

scholarly journals Direct Electron Transfer of Cytochrome c on ZnO Nanoparticles Modified Carbon Paste Electrode

2012 ◽  
Vol 2012 ◽  
pp. 1-6 ◽  
Author(s):  
Masoud Negahdary ◽  
Saeed Rezaei-Zarchi ◽  
Neda Rousta ◽  
Soheila Samei Pour
Keyword(s):  
Cytochrome C ◽  
Carbon Paste Electrode ◽  
Zno Nanoparticles ◽  
Direct Electron Transfer ◽  
Direct Electrochemistry ◽  
Phosphate Buffer Solution ◽  
Modified Carbon Paste Electrode ◽  
Carbon Paste ◽  
Buffer Solution ◽  
Paste Electrode

The direct electrochemistry of cytochrome c (cyt c) immobilized on a modified carbon paste electrode (CPE) was described. The electrode was modified with ZnO nanoparticles. Direct electrochemistry of cytochrome c in this paste electrode was easily achieved, and a pair of well-defined quasireversible redox peaks of a heme Fe (III)/Fe(II) couple appeared with a formal potential (E0) of −0.303 V (versus SCE) in pH 7.0 phosphate buffer solution (PBS). The fabricated modified bioelectrode showed good electrocatalytic ability for reduction of H2O2. The preparation process of the proposed biosensor was convenient, and the resulting biosensor showed high sensitivity, low detection limit, and good stability.

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