Evaluation of Distribution of Succinic Acid between Binary Phase System with Biodiesel + N,N-Dioctyloctan-1-amine

The present study is aimed at using one of the most promising methods called reactive extraction to extract succinic acid from aqueous solution by using N,N-dioctyloctan-1-amine in biodiesel as diluent made from sunflower oil, rice bran oil, sesame oil, and karanji oil. The results of extraction studies with the diluents (physical) showed their inability to recover any acid by themselves. In reactive extraction, the organic phase extracting power solely depends on tri-n-octylamine. The ranges of the distribution coefficient are found as 7.62–18.12 for sunflower oil biodiesel, 8.33–17.45 for rice bran oil biodiesel, 7.0–17.67 for sesame oil biodiesel, and 9.85–21.36 for karanji oil biodiesel. The ranges of the loading ratio are 0.1–3.0 for sunflower oil biodiesel, 0.1–2.9 for rice bran oil biodiesel, 0.2–2.9 for sesame oil biodiesel, and 0.1–2.9 for karanji oil biodiesel. The karanji and sunflower oil showed higher values of distribution coefficient (KD) over rice bran oil and sesame oil which might be due to presence of both C20 and special fatty acids. The results show that biogenous diluents along with N,N-dioctyloctan-1-amine as extractant form a nontoxic and viable option for the extraction of succinic acid in the binary phase system.

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ENHANCING THE FRYING PERFORMANCE OF HIGH OLEIC SUNFLOWER OIL USING SESAME OIL AND RICE BRAN OIL

Foodservice Research International ◽

10.1111/j.1745-4506.1998.tb00147.x ◽

1998 ◽

Vol 10 (2) ◽

pp. 139-156 ◽

Cited By ~ 1

Author(s):

A. KAMAL-ELDIN ◽

L. A. APPELQVIST ◽

CHR. GERTZ ◽

R.F. STIER

Keyword(s):

Rice Bran ◽

Sunflower Oil ◽

Rice Bran Oil ◽

Sesame Oil ◽

High Oleic Sunflower Oil ◽

High Oleic ◽

Frying Performance

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Assessment of the Efficiency of Aliquat 336+Rice Bran Oil for Separation of Acrylic Acid from Aqueous Solution Using Reactive Extraction

International Journal of Chemical Reactor Engineering ◽

10.1515/ijcre-2017-0214 ◽

2018 ◽

Vol 16 (9) ◽

Cited By ~ 1

Author(s):

Himangshu Mondal ◽

Kanti Kumar Athankar ◽

Kailas L. Wasewar

Keyword(s):

Acrylic Acid ◽

Rice Bran ◽

Renewable Resources ◽

Extraction Efficiency ◽

Process Development ◽

Rice Bran Oil ◽

Reactive Extraction ◽

Aliquat 336 ◽

Proposed Model ◽

Predicted Values

Abstract Biomass is an attractive target in process development for the emerging renewable resources based bio-refinery industry. Due to the ample range of application of acrylic acid, its production through bio-route received more awareness in scientific fraternity. In this view, an attempted was made to study the reactive extraction of acrylic acid with aliquat 336 in rice bran oil. Moreover, Box-Behnken matrix was employed to corroborate the effects of process variables viz. concentration of acrylic acid [CAA]aq, concentration of aliquat 336 [CR4N+Cl], and temperature on the extraction efficiency (η%). In physical extraction, average extraction efficiency was found in the order as: 43.55 > 35.36 > 29.14 at 303 K, 323 K, and 343 K respectively in rice bran oil. The correlation coefficient, R2 = 0.988 % indicates the appropriateness of proposed model to predict the extraction efficiency in terms of independent variables, and the predicted values were found in close agreement with that of experimental results. Further, R2(Pred) = 0.806 is in reasonable agreement with the R2(Adj) = 0.972. The optimum conditions for extraction of acrylic acid using aliquat 336 as an extractant in rice bran oil are [CAA]aq = 0.0.5 (mol/kg); [CR4N+Cl] = 1.98 (mol/kg); temperature = 323 K and the model predicted extraction efficiency 77.5 % was found to be an excellent fit with the experimental value 75 %. Further, number of theoretical stages was found to be 3 and S/F ratio 0.247.

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Determination of sesame oil, rice bran oil and pumpkin seed oil in ternary mixtures using FTIR spectroscopy and multivariate calibrations

Food Research ◽

10.26656/fr.2017.4(1).260 ◽

2019 ◽

Vol 4 (1) ◽

pp. 135-142 ◽

Cited By ~ 3

Author(s):

Irnawati ◽

S. Riyanto ◽

S. Martono ◽

Abdul Rohman

Keyword(s):

Root Mean Square Error ◽

Rice Bran ◽

Seed Oil ◽

Rice Bran Oil ◽

Sesame Oil ◽

Ftir Spectra ◽

Ternary Mixtures ◽

Mean Square ◽

Pumpkin Seed ◽

Pumpkin Seed Oil

Pumpkin seed oil (PSO), rice bran oil (RBO), sesame oil (SEO) are considered as functional oils due to its biological activities which are beneficial to human health, as a consequence, these oils had the higher price. This attracted unethical players to blend these oils with lower price oils, therefore, its authentication by analysis of purity levels of oils is very important. This study highlighted the potential application of FTIR spectroscopy and multivariate calibrations for analysis of PSO, RBO, and SEO in ternary mixtures. Individual FTIR spectra of studied oils as well as in ternary mixtures with certain compositions were scanned and pre-processed. Two multivariate calibrations of principle component regression (PCR) and partial least square regression (PLSR) were compared and used to build the prediction models at optimized FTIR spectra regions. The selection of multivariate calibrations, wavenumbers region, and FTIR spectra modes was based on the statistical parameters of highest R2 and lowest values of root mean square error of calibration (RMSEC) and root mean square error of prediction (RMSEP). The results showed that PLSR using second derivative FTIR spectra at wavenumbers region of 3100-2750 and 1500-663 cm-1 was used to predict the levels of PSO in ternary mixtures with RBO and SEO with R2 > 0.99 in calibration and validation models along with RMSEC value of 0.0054% and RMSEP of 0.0179%. FTIR spectra using the second and first derivatives at wavenumbers of 3100-650 cm-1 were used for prediction of RBO and SEO in ternary mixture with PSO, respectively. It can be concluded that FTIR spectra combined with PLSR at certain wavenumbers region are accurate as indicated by high R2 values and precise as indicated by low values of RMSEC and RMSEP for analysis of PSO, RBO and SEO in ternary mixtures.

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Sesame Oil and Rice Bran Oil Ameliorates Adjuvant-Induced Arthritis in Rats: Distinguishing the Role of Minor Components and Fatty Acids

Lipids ◽

10.1007/s11745-016-4203-4 ◽

2016 ◽

Vol 51 (12) ◽

pp. 1385-1395 ◽

Cited By ~ 15

Author(s):

Nayana Venugopal Yadav ◽

Sadashivaiah ◽

Breetha Ramaiyan ◽

Pooja Acharya ◽

Lokesh Belur ◽

...

Keyword(s):

Fatty Acids ◽

Rice Bran ◽

Rice Bran Oil ◽

Sesame Oil ◽

Minor Components ◽

Adjuvant Induced Arthritis

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Hypolipidemic Effect of Oils with Balanced Amounts of Fatty Acids Obtained by Blending and Interesterification of Coconut Oil with Rice Bran Oil or Sesame Oil

Journal of Agricultural and Food Chemistry ◽

10.1021/jf0718042 ◽

2007 ◽

Vol 55 (25) ◽

pp. 10461-10469 ◽

Cited By ~ 34

Author(s):

Malongil B. Reena ◽

Belur R. Lokesh

Keyword(s):

Fatty Acids ◽

Rice Bran ◽

Rice Bran Oil ◽

Coconut Oil ◽

Sesame Oil ◽

Hypolipidemic Effect

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Investigation on improving the thermal efficiency of a mini boiler fired with straight vegetable oils

Thermal Science ◽

10.2298/tsci180126243p ◽

2020 ◽

Vol 24 (2 Part A) ◽

pp. 713-722

Author(s):

Maran Punnaivanam ◽

Arumugam Krishnan

Keyword(s):

Vegetable Oils ◽

Rice Bran ◽

Thermal Efficiency ◽

Sunflower Oil ◽

Rice Bran Oil ◽

Supply System ◽

Compressed Air ◽

Exhaust Gases ◽

Oil Blends ◽

Air Supply

In the present work, straight sunflower oil and rice bran oil blended with diesel have been used as fuel diesel in a mini boiler. The thermal efficiency of the boiler and emission levels in the exhaust gases have been investigated by burning the oil blends of varying proportions ranging from 0-50%. An additional air supply system and compressed air atomization of fuel with a new burner have been used to improve the thermal efficiency of the mini boiler. Results revealed that the addi?tional air supply improved the thermal efficiency up-to 7% and reduced the CO and HC emission up-to 40%. The use of compressed air atomization further increased the thermal efficiency up-to 4% and reduced the CO and HC emission up-to 70%.

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Reactive Extraction of Levulinic Acid using Tri-n-octylamine in 1-Octanol: Equilibria and Effect of pH

International Journal of Recent Technology and Engineering - 2 ◽

10.35940/ijrte.e3203.018520 ◽

2020 ◽

Vol 8 (5) ◽

pp. 5252-5256

Keyword(s):

Distribution Coefficient ◽

Levulinic Acid ◽

Extraction Efficiency ◽

Fermentation Broth ◽

Reactive Extraction ◽

High Yield ◽

Chemical Extraction ◽

Effect Of Ph ◽

Loading Ratio ◽

Physical And Chemical

Reactive extraction is a sophisticated separation technique used for the recovery of carboxylic acids from fermentation broth. Levulinic acid is a versatile chemical. A right combination of extractant and diluent will provide a high yield. The reactive extraction of levulinic acid from aqueous solution with tri-n-octylamine (TOA) dissolved in 1-octanol was investigated at room temperature. The effect of pH was studied. From the physical and chemical equilibrium experimental results, the distribution coefficient (KD), extraction efficiency (E%), loading ratio (Z), stoichiometric loading factor (ZS) and modified separation factor (Sf ) are calculated. It was found that physical extraction provided less yield compared to chemical extraction. A maximum KD was obtained as 5.248 using 40% TOA (0.9059 mol/L) while 83.99 % of the levulinic acid was extracted. By increasing the initial concentration of levulinic acid increased the concentration of levulinic acid in both the organic phase and aqueous phase. As the concentration of TOA increases from 10 to 40 % (0.2264 mol/L to 0.9059 mol/L), the distribution coefficient and extraction efficiency also increase. By increasing the pH from 3 to 7, the distribution coefficient and extraction efficiency were drastically affected.

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Equilibrium & kinetic studies of reactive extraction of trans-aconitic acid using sunflower oil with tri-n-octylamine

International Journal of Chemical Reactor Engineering ◽

10.1515/ijcre-2021-0107 ◽

2021 ◽

Vol 0 (0) ◽

Author(s):

Rajesh Nimmakayala ◽

Dharm Pal ◽

Dhananjay Singh ◽

Abhinesh Kumar Prajapati

Keyword(s):

Sunflower Oil ◽

Fermentation Broth ◽

Kinetic Studies ◽

Reactive Extraction ◽

Equilibrium Studies ◽

Aconitic Acid ◽

Equilibrium And Kinetics ◽

Loading Ratio ◽

Stirred Cell ◽

Complex Formations

Abstract In order to design an efficient extraction system for the separation of biochemically produced trans-aconitic acid (TAH) from fermentation broth; equilibrium and kinetics of reactive extraction of TAH from aqueous solutions was investigated using tri-n-octylamine (TOA) as an extractant and sunflower oil as a diluent. Through the equilibrium studies stoichiometry (acid, extractant) of complex formations was determined with the help of loading ratio. Formation of (1, 1), (2, 1), & (3, 1) stoichiometry complexes were observed having complexation constants values 179.73 kmol−1 m3, 9512.58 kmol−2 m6, and 614,407.02 kmol−3 m9, respectively. Kinetics experiments were performed in Lewis type stirred cell and results confirmed that reaction between TAH and TOA in sunflower oil fall in regime 1, i.e. slow reaction occurring in bulk organic phase. The overall order of reaction is pseudo first order with rate constant (K mn ) 1.78 × 10−5 (kmol m−3)−0.71 s−1 and physical mass transfer coefficient (K l ) 4.22 × 10−5 m s−1.

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