scholarly journals Development of an Efficient Analytical Method for the Extraction and Analysis of Biocide Contents from the Textile Test Specimens on LC-DAD

2020 ◽  
Vol 2020 ◽  
pp. 1-6
Author(s):  
Muhammad Jahangir ◽  
Uzman Khan
Keyword(s):  
Extraction Method ◽  
Direct Contact ◽  
Consumer Products ◽  
Quantitative Detection ◽  
Dilution Ratio ◽  
Extraction Solvent ◽  
Solvent Extraction Method ◽  
Relative Standard ◽  
Isocratic Mode ◽  
Real Test

Biocides are frequently used in the manufacturing of textiles that are in direct contact with human skin. Recently regulated biocides do not have validated methods for testing; so, their presence cannot be estimated in the consumer products. Hence a rapid method was developed for the separation and quantitative analysis of biocide contents (2-methyl-4-isothaizolin (MIT), 5-chloro-2-methyl-4-isothaizolin-3-one (CIT), 2-octo-4-isothaizolin-3-one (OIT), and 5-chloro-2-(2,4-dichlorophenxy) phenol (triclosan)) from the textile test specimens. Test specimens were extracted with methanolic sonication and purified by centrifugation and filtration. Biocide contents were separated at C18 column with 0.4% acetic acid: methanol (1 : 1 v/v) under isocratic mode and detected at 280 nm wavelength. Pretreatment factors such as extraction solvent, extraction method, dilution ratio, and extraction time were optimized initially and plotted calibration curve showed regression (r2 ≥ 0.9995) in the range of 1.0–5.0 mg L−1. Recoveries were between 95% and 108% with the relative standard deviation ≤ 4%. Limits of detection (LODs) were between 0.06 mg L−1 and 0.12 mg L−1 and limits of quantification (LOQs) were between 0.21 mg L−1 and 0.38 mg L−1. From the results, conclusion was made that the method can achieve the purpose of quantitative detection and the analysis of real test specimens verified the reliability of this method.

A New Green In Situ Effervescent CO2-Table-Induced Switchable Hydrophilicity Solvent Extraction Method of Rhodamine B in Food and Soft Drink Samples

2020 ◽  
Author(s):  
Naeemullah Khan ◽  
Mustafa Tuzen
Keyword(s):  
Solvent Extraction ◽  
Rhodamine B ◽  
Extraction Method ◽  
Limit Of Detection ◽  
Soft Drink ◽  
Main Theme ◽  
Solvent Extraction Method ◽  
Relative Standard ◽  
Switchable Hydrophilicity Solvent

Abstract Background A new and simple effervescent CO2-table-induced switchable hydrophilicity solvent extraction method (CI-SHS) was used for the preconcentration of rhodamine B (RB). Objective The main theme of the proposed method to disperse green solvent by in situ CO2-table system overcome on the contamination and to avoid the dispersion by using different chemicals. Methods Switchable hydrophilicity solvent (N, N-Dimethyl cyclohexylamine) was dispersed in an aqueous solution by reaction of CO2-table of sodium carbonate and citric acid to enhance the contact area between two medium, which radically improved the extraction capacity of the RB from aqueous medium to switchable solvent. The phase separation was achieved by simple heating not by centrifugation that makes a change on hydrophilicity to hydrophobicity. The supernatant-enriched RB- N, N-Dimethyl cyclohexylamine phase was withdrawn and injected into the UV glass cells. The absorbance was measured at 542. Results Limit of detection and enhancement factor were achieved to be 0.042 and 50 µg/L. Validity and accuracy of the method verified by analysis of real samples by the spiking addition method. The relative standard deviation was obtained at 3.2%. The method was applied to food and soft drink samples. Conclusions This method offers high sensitivity, selectivity, accuracy, and precision for the separation, preconcentration, and spectrophotometric determination of RB. Simple, fast, low-cost, and green extraction method was developed. Highlights High enrichment factor and lower detection limits were observed in this microextraction method. Present method is sensitive, selective, very accurate, and precise.

scholarly journals Quantitative Detection of Chromium Pollution in Biochar Based on Matrix Effect Classification Regression Model

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 2069
Author(s):  
Mei Guo ◽  
Rongguang Zhu ◽  
Lixin Zhang ◽  
Ruoyu Zhang ◽  
Guangqun Huang ◽  
...  
Keyword(s):  
Regression Model ◽  
Matrix Effect ◽  
Nearest Neighbor ◽  
Quantitative Detection ◽  
Least Squares Regression ◽  
K Nearest Neighbor ◽  
Breakdown Spectroscopy ◽  
Relative Standard ◽  
Calibration Samples ◽  
Standard Deviations

Returning biochar to farmland has become one of the nationally promoted technologies for soil remediation and improvement in China. Rapid detection of heavy metals in biochar derived from varied materials can provide a guarantee for contaminated soil, avoiding secondary pollution. This work aims first to apply laser-induced breakdown spectroscopy (LIBS) for the quantitative detection of Cr in biochar. Learning from the principles of traditional matrix effect correction methods, calibration samples were divided into 1–3 classifications by an unsupervised hierarchical clustering method based on the main elemental LIBS data in biochar. The prediction samples were then divided into diverse classifications of calibration samples by a supervised K-nearest neighbor (KNN) algorithm. By comparing the effects of multiple partial least squares regression (PLSR) models, the results show that larger numbered classifications have a lower averaged relative standard deviations of cross-validation (ARSDCV) value, signifying a better calibration performance. Therefore, the 3 classification regression model was employed in this study, which had a better prediction performance with a lower averaged relative standard deviations of prediction (ARSDP) value of 8.13%, in comparison with our previous research and related literature results. The LIBS technology combined with matrix effect classification regression model can weaken the influence of the complex matrix effect of biochar and achieve accurate quantification of contaminated metal Cr in biochar.

scholarly journals A highly sensitive octopus-like azobenzene fluorescent probe for determination of abamectin B1 in apples

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Zhenlong Guo ◽  
YiFei Su ◽  
Kexin Li ◽  
MengYi Tang ◽  
Qiang Li ◽  
...  
Keyword(s):  
Fluorescent Probe ◽  
Limit Of Detection ◽  
Quantitative Detection ◽  
Fluorescence Signal ◽  
Ionization Mass ◽  
Limit Of Quantification ◽  
Visible Absorption ◽  
Esi Ms ◽  
Relative Standard ◽  
Ft Ir

AbstractThe development of detecting residual level of abamectin B1 in apples is of great importance to public health. Herein, we synthesized a octopus-like azobenzene fluorescent probe 1,3,5-tris (5′-[(E)-(p-phenoxyazo) diazenyl)] benzene-1,3-dicarboxylic acid) benzene (TPB) for preliminary detection of abamectin B1 in apples. The TPB molecule has been characterized by ultraviolet–visible absorption spectrometry, 1H-nuclear magnetic resonance, fourier-transform infrared (FT-IR), electrospray ionization mass spectroscopy (ESI-MS) and fluorescent spectra. A proper determination condition was optimized, with limit of detection and limit of quantification of 1.3 µg L−1 and 4.4 μg L−1, respectively. The mechanism of this probe to identify abamectin B1 was illustrated in terms of undergoing aromatic nucleophilic substitution, by comparing fluorescence changes, FT-IR and ESI-MS. Furthermore, a facile quantitative detection of the residual abamectin B1 in apples was achieved. Good reproducibility was present based on relative standard deviation of 2.2%. Six carboxyl recognition sites, three azo groups and unique fluorescence signal towards abamectin B1 of this fluorescent probe demonstrated reasonable sensitivity, specificity and selectivity. The results indicate that the octopus-like azobenzene fluorescent probe can be expected to be reliable for evaluating abamectin B1 in agricultural foods.

Detection of 20 Phthalate Esters in Different Kinds of Food Packaging Materials by GC-MS/MS with Five Internal Standards

2019 ◽  
Vol 102 (1) ◽  
pp. 255-261 ◽  
Author(s):  
Ji-cai Fan ◽  
Quan Jin ◽  
Hua-li He ◽  
Ren Ren ◽  
Shu-ting Wang
Keyword(s):  
Food Packaging ◽  
Large Scale ◽  
Phthalate Esters ◽  
Correlation Coefficients ◽  
Packaging Materials ◽  
Purification Step ◽  
Internal Standards ◽  
Extraction Solvent ◽  
Food Packaging Materials ◽  
Relative Standard

Abstract Background: Phthalate esters (PAEs) are a group of chemical compounds widely used as plasticizers to increase the flexibility of plastics that are used in the manufacturing of kitchen utensils and food containers. Objective: In this study, a simple, rapid, and sensitive method for the determination of 20 PAEs in different kinds of food packaging materials has been developed. Methods: Samples injected with five internal standards were extracted with acetonitrile saturated with n-hexane and then detected by GC-MS/MS without a purification step. Results: The standard calibration curves were linear for all analytes over the concentration range of 5–500 μg/L, and the correlation coefficients ranged from 0.9913 to 0.9999. The LODs and LOQs were in the ranges of 1.7–62.5 and 5.5–208.3 μg/kg, respectively. The accuracy of this method was evaluated by measuring the recovery from spiked samples. The recoveries of all 20 phthalates from samples spiked at three different concentrations were measured, and the recovery was in the range of 82.1–110.8% and the relative standard deviation range of recovery result (n = 6) was 0.3–9.7%. Conclusions: The method presented here is simple, rapid, and sensitive and can be applied to large-scale detection of PAEs in plastic materials. Highlights: Instead of only one solvent, acetonitrile saturated with n-hexane was used as the extraction solvent. Samples were pretreated without a purification step. Five internal standards were used for quantitative determination.

scholarly journals Gas Chromatography of Urinary Anthranilic Acid and 3-Hydroxyanthranilic Acid by Solvent Extraction Method

1972 ◽  
Vol 20 (7) ◽  
pp. 1412-1416 ◽  
Author(s):  
KAZUYUKI HIRANO ◽  
KAZUMI MORI ◽  
NOBUKO TSUBOI ◽  
SATOSHI KAWAI ◽  
TAKEO OHNO
Keyword(s):  
Gas Chromatography ◽  
Solvent Extraction ◽  
Anthranilic Acid ◽  
Extraction Method ◽  
Solvent Extraction Method ◽  
Hydroxyanthranilic Acid

scholarly journals Homogeneous Liquid-Liquid Extraction Method for Selective Separation and Preconcentration of Trace Amounts of Palladium

2009 ◽  
Vol 6 (4) ◽  
pp. 1077-1084 ◽  
Author(s):  
Mohammad Reza Jamali ◽  
Yaghoub Assadi ◽  
Reyhaneh Rahnama Kozani ◽  
Farzaneh Shemirani
Keyword(s):  
Extraction Method ◽  
Limit Of Detection ◽  
Liquid Extraction ◽  
Selective Separation ◽  
Complexing Agent ◽  
Homogeneous Liquid ◽  
Liquid Liquid Extraction ◽  
Relative Standard ◽  
Separation And Preconcentration ◽  
Ternary Component System

A simple and effective homogeneous liquid-liquid extraction method for selective separation, preconcentration and spectrophotometric determination of palladium(II) ion was developed by using a ternary component system (water / tetrabutylammonium ion (TBA+) / chloroform). The phase separation phenomenon occurred by an ion–pair formation of TBA+and perchlorate ion. Thio-Michler’s ketone (TMK), 4, 4ˊ-bis (dimethylamino) thiobenzophenone, was used as a complexing agent. After optimization of complexation and extraction conditions ([TMK]=5.0x10-2mol L-1, [TBA+] = 2.0×10-2mol L-1, [CHCl3] = 60.0 µL, [ClO4-] = 2.5×10-2mol L-1and pH= 3.0), a preconcentration factor 10 was obtained for 10 mL of sample. The analytical curve was linear in the range of 2-100 ng mL-1and the limit of detection was 0.4 ng mL-1. The relative standard deviation was 3.2% (n=10). Accuracy and application of the method was estimated by using test samples of natural and synthetic water spiked with different amounts of palladium(II) ion. The method is very simple and inexpensive.

Extraction of 2-Acetyl-1-Pyrroline (2AP) in Pandan Leaves (Pandanus Amaryllifolius Roxb.) Via Solvent Extraction Method: Effect of Solvent

2014 ◽  
Vol 67 (2) ◽  
Author(s):  
Norzita Ngadi ◽  
Noor Yahida Yahya
Keyword(s):  
Solvent Extraction ◽  
Extraction Method ◽  
Extraction Process ◽  
Natural Sources ◽  
Effect Of Solvent ◽  
Method Effect ◽  
Solvent Extraction Method ◽  
Pandanus Amaryllifolius

Pandan (Pandanus amaryllifolius Roxb.) leaves are widely used in Malaysia as a source of natural flavoring.  The major compound contributing to the characteristic flavour of Pandan is 2-acetyl-1-pyrroline (2AP). As the consumer requirement for use of natural flavours, extraction of components from natural sources has been sought. In this study, solvent extraction of 2AP from Pandan leaves was performed. The effect of solvent used during extraction process (i.e. methanol, ethanol, propanol) towards the yield of 2AP was investigated. The presence of 2AP was determined using GCMS. The results obtained showed that ethanol was the best solvent to extract 2AP from Pandan leaves compared to methanol as higher 2AP peak arises from ethanol chromatogram.  However there is no 2AP detected when propanol was used as solvent.  It is believed that polarity of the solvent plays an important role in the extraction of 2AP.

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