Enrichment Mechanism of the Upper Carboniferous-Lower Permian Transitional Shale in the East Margin of the Ordos Basin, China: Evidence from Geochemical Proxies

The organic-rich shale of the Upper Carboniferous-Lower Permian transition period in the eastern margin of the Ordos Basin, China, was formed in a marine-continental facies sedimentary environment. With a high content of total organic carbon (TOC) and a large cumulative thickness, it is considered a good source rock for shale gas development. The sedimentary environment of marine-continental transitional shale is obviously different from that of marine shale, which leads to different enrichment characteristics of organic matter. In this paper, shale samples were collected from XX# well of the Taiyuan and Shanxi Formations across the Upper Carboniferous-Lower Permian, which is typical marine-continental transitional shale. The TOC, major elements, and trace elements were measured, and the formation and preservation conditions were investigated using multiple geochemical proxies, including paleoclimate, redox parameters, paleoproductivity, and controls on the accumulation of organic matter. The TOC of Shanxi Formation is higher than that of Taiyuan Formation. In the Taiyuan Formation, TOC is positively related to the redox index (V, U, and V/Cr), indicating that the dysoxic bottom water environment is the key factor controlling organic matter accumulation. For Shanxi Formation, there is a positive correlation between TOC and paleoclimate, which indicates that the enrichment of organic matter is affected by warm and humid paleoclimate and oxic environment. In addition, the paleoproductivity is lower with a positive correlation with TOC for the marine-continental transitional organic-rich shale, suggesting that it was inferior to the gathering of organic matter.

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Pore Structures of the Lower Permian Taiyuan Shale and Limestone in the Ordos Basin and the Significance to Unconventional Natural Gas Generation and Storage

Geofluids ◽

10.1155/2022/3156547 ◽

2022 ◽

Vol 2022 ◽

pp. 1-16

Author(s):

L. Zhang ◽

Q. Zhao ◽

C. Wu ◽

Z. Qiu ◽

Q. Zhang ◽

...

Keyword(s):

Organic Matter ◽

Natural Gas ◽

Shale Gas ◽

Pore Volume ◽

Ordos Basin ◽

Source Rocks ◽

Taiyuan Formation ◽

Oil Generation ◽

Unconventional Natural Gas ◽

The Ordos Basin

In the Ordos Basin, multiple sets of coal seams, organic-rich shale, and limestone are well developed in the Permian Taiyuan Formation, which are favorable targets for collaborative exploration of various types of unconventional natural gas resources, including coalbed methane, shale gas, and tight gas. In this study, core samples from the Permian Taiyuan Formation in the eastern margin of the Ordos Basin were used to carry out a series of testing and analysis, such as the organic matter characteristics, the mineral composition, and the pore development characteristics. In the shale of the Taiyuan Formation, the total organic carbon (TOC) content is relatively high, with an average of 5.38%. A thin layer of black shale is developed on the top of the Taiyuan Formation, which is relatively high in TOC content, with an average of 9.72%. The limestone in the Taiyuan Formation is also relatively high in organic matter abundance, with an average of 1.36%, reaching the lower limit of effective source rocks (>1%), being good source rocks. In the shale of the Taiyuan Formation, various types of pores are well developed, with relatively high overall pore volume and pore-specific surface area, averaging 0.028 ml/g and 13.28 m2/g, respectively. The pore types are mainly mineral intergranular pores and clay mineral interlayer fractures, while organic matter-hosted pores are poorly developed. The limestone of the Taiyuan Formation is relatively tight, with lower pore volume and pore-specific surface area than those of shale, averaging 0.0106 ml/g and 2.72 m2/g, respectively. There are mainly two types of pores, namely, organic matter-hosted pores and carbonate mineral dissolution pores, with a high surface pore rate. The organic matter in the limestone belongs to the oil-generation kerogen. During thermal evolution, the organic matter has gone through the oil-generation window, generating a large number of liquid hydrocarbons, which were cracked into a large number of gaseous hydrocarbons at the higher mature stage. As a result, a large number of organic matter-hosted pores were generated. The study results show that in the Ordos Basin, the shale and limestone of the Permian Taiyuan Formation have great potential in terms of unconventional natural gas resources, providing a good geological basis for the collaborative development of coal-bearing shale gas and tight limestone gas in the Taiyuan Formation.

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Reservoir Characteristics of the Lower Permian Marine-Continental Transitional Shales: Example from the Shanxi Formation and Taiyuan Formation in the Ordos Basin

Geofluids ◽

10.1155/2021/9373948 ◽

2021 ◽

Vol 2021 ◽

pp. 1-17

Author(s):

H. Wang ◽

L. Zhang ◽

Q. Zhao ◽

Z. Qiu ◽

D. Liu ◽

...

Keyword(s):

Pore Size ◽

Clay Minerals ◽

Co2 Adsorption ◽

Ordos Basin ◽

Lower Permian ◽

Reservoir Properties ◽

Taiyuan Formation ◽

Adsorption Analysis ◽

The Ordos Basin ◽

Pore Types

The pore types and pore structure parameters of the heterogenetic shale will affect the percolation and reservoir properties of shale; therefore, the research on these parameters is very important for shale reservoir evaluation. We used X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), low-pressure CO2 adsorption analysis, mercury injection capillary pressure (MICP), and high-pressure methane adsorption analysis to analyze the characteristics of different pore types and their parameters of the Lower Permian Shanxi Formation and Taiyuan Formation in the Ordos Basin. The influence of different mineral contents on the porosity and pore size is also investigated. The Shanxi Formation (SF) is composed of quartz (average of 38.4%), plagioclase, siderite, Fe-dolomite, calcite, pyrite, and clay minerals (average of 50.1%), while the Taiyuan Formation (TF) is composed of calcite (average of 37%), siderite, Fe-dolomite, quartz, pyrite, and clay minerals (average of 32.3%). The most common types of pores observed in this formation are interparticle pores (InterP pores), intraparticle pores (IntraP pores), interclay pores, intercrystalline pores (InterC pores), organic matter pores (OM pores), and microfractures. CO2 adsorption analysis demonstrates the type I physisorption isotherms, showing microporous solids having comparatively small external surfaces. The similar types of isothermal shapes of the Shanxi Formation (SF) and Taiyuan Formation (TF) suggest that both types have similar pore size distribution (PSD) within the measured pore range by the low-pressure CO2 adsorption experiment. The micropore pore size of the TF is larger than that of the SF. MICP shows the larger pores (>50 nm), and most of the volume was adsorbed by macropores. Methane gas sorption capacity increases with increasing pressure. Clay minerals and quartz played an important role in providing adsorption sites for methane gas. The overall analysis of both formations shows that TF has good reservoir properties than SF.

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The petrological characteristics and significance of organic-rich shale in the Chang 7 member of the Yanchang Formation, south margin of the Ordos basin, central China

Petroleum Science ◽

10.1007/s12182-019-00386-0 ◽

2019 ◽

Vol 16 (6) ◽

pp. 1255-1269 ◽

Cited By ~ 2

Author(s):

Sen Li ◽

Ru-Kai Zhu ◽

Jing-Wei Cui ◽

Zhong Luo ◽

Jing-Gang Cui ◽

...

Keyword(s):

Organic Matter ◽

Positive Impact ◽

Sedimentary Environment ◽

Ordos Basin ◽

Redox Status ◽

Ash Content ◽

Central China ◽

X Ray Diffraction ◽

The Ordos Basin ◽

The Relationship

Abstract The organic-rich shale of the Chang 7 member is the most important source rock in the Ordos basin. The sedimentary environment and the controlling factors of organic matter enrichment, however, are still in contention. In this investigation, the Yishicun outcrop, located on the south margin of the Ordos basin, has been considered for the study. X-ray diffraction, polarizing microscopy, field emission scanning electron microscopy and cathodoluminescence (CL) were used to investigate the petrological features of the organic-rich shale. The content of volcanic ash and the diameter of pyrite framboid pseudocrystals were measured to illustrate the relationship between oxygen level, ash content and the enrichment of organic matter. It has been found that the diameter of pyrite framboid pseudocrystals has a strong correlation with the total organic carbon, demonstrating that the redox status degree of the water column has a positive impact on the enrichment of organic matter. Additionally, with an increase in the ash content, the content of organic matter increased at first and then decreased, and reached a maximum when the ash content was about 6%, illustrating that the ash input has a double effect on the enrichment of organic matter.

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