scholarly journals The Effects of Using Waste Engine Oil Bottom on Physical, Rheological Properties and Composite Modification Mechanism of SBS-Modified Asphalt

2022 ◽  
Vol 2022 ◽  
pp. 1-12
Author(s):  
Yanbo Wang ◽  
Ailian Liu ◽  
Weixiang Ding ◽  
Fangping Rao ◽  
Jun Yuan ◽  
...  
Keyword(s):  
Low Temperature ◽  
Rheological Properties ◽  
Asphalt Binder ◽  
Polymer Network ◽  
Engine Oil ◽  
Chemical Compositions ◽  
Modified Asphalt ◽  
Waste Engine Oil ◽  
Sbs Modified Asphalt ◽  
Composite Modification

This research explores the effects of using waste engine oil bottom on physical, rheological properties and composite modification mechanism of SBS-modified asphalt. The SBS asphalt binder was modified by WEOB with different concentrations (2, 4, and 6 wt%). The GC-MS and FTIR spectrometry were conducted to evaluate the chemical compositions of WEOB- and WEOB-modified asphalt. RV, DSR, and BBR were tested to evaluate high- and low-temperature pavement performance. Fluorescence microscope (FM) test, bar thin layer chromatograph (BTLC) test, and AFM test were performed to evaluate the micromorphologies and modification mechanism. The test results showed that a new characteristic peak appeared in the infrared spectrum of the WEOB-modified SBS asphalt, indicating a chemical reaction in the modification process. Incorporation of WEOB improves both the high-temperature and low-temperature properties of the SBS asphalt binder. It was confirmed that with the increase of WEOB concentration, the content of colloid gradually increases, which promotes the swelling and compaction of SBS polymer network structure. Furthermore, WEOB promotes the polarity of SBS and forms graft product MAH-g-SBS with asphalt, thus inhibiting the thermal movement of asphalt molecules. On the contrary, light components have a good correlation with the surface roughness of modified asphalt; the results show that the modified asphalt has good rutting resistance.

scholarly journals Enhancing Effect of Waste Engine Oil Bottom Incorporation on the Performance of CR+SBS Modified Bitumen: A Sustainable and Environmentally-Friendly Solution for Wastes

2021 ◽  
Vol 13 (22) ◽  
pp. 12772
Author(s):  
Changjiang Liu ◽  
Qiuping Wang
Keyword(s):  
Asphalt Binder ◽  
Engine Oil ◽  
Chemical Compositions ◽  
Self Healing ◽  
Temperature Property ◽  
Modified Bitumen ◽  
Modified Asphalt ◽  
Waste Engine Oil ◽  
Sbs Modified Asphalt ◽  
Low Temperature Property

Waste engine oil bottom (WEOB) is a hazardous waste whose effect as an additive to CR+SBS modified asphalt is rarely studied. In this study, the CR+SBS asphalt binder was modified with WEOB in different concentrations (3, 6, and 9 wt%). The GC–MS and FTIR were performed to evaluate the chemical compositions of WEOB and WEOBCR+SBS asphalt. The results showed that the main constituents of WEOB were similar to the functional groups of asphalt, along with maleic anhydride (MAH). Pavement performance-related rheological tests such as RV, temperature sweep (TS), FS, MSCR, and BBR were carried out. Results show that WEOBCR+SBS-6 exhibited the best high- and low-temperature property, followed by CR+SBS-3 and CR+SBS-9. Fluorescence microscope (FM) test, bar thin layer chromatograph (BTLC) test, FTIR, and AFM tests were carried out to evaluate the micro-morphologies and modification mechanism. The analysis revealed increased trends in resin fraction as opposed to asphaltene fraction with the increase of WEOB content. FTIR analysis revealed that the amide groups in WEOBCR+SBS asphalt bonded to the free radicals of CR. Moreover, a modification mechanism was elaborated. WEOB strengthens the cross-linked structure of CR+SBS polymers, reacting with SBS to graft onto MAH-g-SBS, and the free radical of CR interacts with the amide group in WEOB to form a bond. In addition, the content of lightweight components and surface roughness of SBS specimens were in good correlation, which contributed to the rutting resistance and adhesion and self-healing performance.

scholarly journals Evaluation of High-Temperature and Low-Temperature Performances of Lignin–Waste Engine Oil Modified Asphalt Binder and Its Mixture

Materials ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 52
Author(s):  
Xue Xue ◽  
Junfeng Gao ◽  
Jiaqing Wang ◽  
Yujing Chen
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Asphalt Binder ◽  
Asphalt Mixture ◽  
Engine Oil ◽  
Bending Beam Rheometer ◽  
Modified Asphalt ◽  
Waste Engine Oil ◽  
Modified Asphalt Binder ◽  
Maximum Tensile Strain

This research aims to explore the high-temperature and low-temperature performances of lignin–waste engine oil-modified asphalt binder and its mixture. For this research, the lignin with two contents (4%, 6%) and waste engine oil with two contents (3%, 5%) were adopted to modify the control asphalt binder (PG 58-28). The high-temperature rheological properties of the lignin–waste engine oil-modified asphalt binder were investigated by the viscosity obtained by the Brookfield viscometer and the temperature sweep test by the dynamic shear rheometer. The low-temperature rheological property of the lignin–waste engine oil-modified asphalt binder was evaluated by the stiffness and m-value at two different temperatures (−18 °C, −12 °C) obtained by the bending beam rheometer. The high-temperature and the low-temperature performances of the lignin–waste engine oil-modified asphalt mixture were explored by the rutting test and low-temperature bending beam test. The results displayed that the rotational viscosity and rutting factor improved with the addition of lignin and decreased with the incorporation of waste engine oil. Adding the lignin into the control asphalt binder enhanced the elastic component while adding the waste engine oil lowered the elastic component of the asphalt binder. The stiffness of asphalt binder LO60 could not meet the requirement in the specification, but the waste engine oil made it reach the requirement based on the bending beam rheometer test. The waste engine oil could enhance the low-temperature performance. The dynamic stabilities of LO40- and LO60-modified asphalt mixture increased by about 9.05% and 17.41%, compared to the control mixture, respectively. The maximum tensile strain of LO45 and LO65 increased by 16.39% and 25.28% compared to that of LO40 and LO60, respectively. The high- and low-temperature performances of the lignin–waste engine oil-modified asphalt LO65 was higher than that of the control asphalt. The dynamic stability had a good linear relationship with viscosity, the rutting factor of the unaged at 58 °C, and the rutting factor of the aged at 58 °C, while the maximum tensile strain had a good linear relationship with m-value at −18 °C. This research provides a theoretical basis for the further applications of lignin–waste engine oil-modified asphalt.

scholarly journals Effect of Recycled Shell Waste as a Modifier on the High- and Low-Temperature Rheological Properties of Asphalt

2021 ◽  
Vol 13 (18) ◽  
pp. 10271
Author(s):  
Yuchen Guo ◽  
Xuancang Wang ◽  
Guanyu Ji ◽  
Yi Zhang ◽  
Hao Su ◽  
...  
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Low Temperatures ◽  
High Speed ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Modified Asphalt ◽  
Temperature Performance

The deteriorating ecological environment and the concept of sustainable development have highlighted the importance of waste reuse. This article investigates the performance changes resulting from the incorporation of shellac into asphalt binders. Seashell powder-modified asphalt was prepared with 5%, 10%, and 15% admixture using the high-speed shear method. The microstructure of the seashell powder was observed by scanning electron microscope test (SEM); the physical-phase analysis of the seashell powder was carried out using an X-ray diffraction (XRD) test; the surface characteristics and pore structure of shellac were analyzed by the specific surface area Brunauer-Emmett-Teller (BET) test; and Fourier infrared spectroscopy (FTIR) qualitatively analyzed the composition and changes of functional groups of seashell powder-modified asphalt. The conventional performance index of seashell powder asphalt was analyzed by penetration, softening point, and ductility (5 °C) tests; the effect of seashell powder on asphalt binder was studied using a dynamic shear rheometer (DSR) and bending beam rheometer (BBR) at high and low temperatures, respectively. The results indicate the following: seashell powder is a coarse, porous, and angular CaCO3 bio-material; seashell powder and the asphalt binder represent a stable physical mixture of modified properties; seashell powder improves the consistency, hardness, and high-temperature performance of the asphalt binder but weakens the low-temperature performance of it; seashell powder enhances the elasticity, recovery performance, and permanent deformation resistance of asphalt binders and improves high-temperature rheological properties; finally, seashell powder has a minimal effect on the crack resistance of asphalt binders at very low temperatures. In summary, the use of waste seashells for recycling as bio-modifiers for asphalt binders is a practical approach.

scholarly journals Effect of Warm-Mix Agent EC-120 on Performance of Asphalt Binder and Its Microscopic Mechanism

2019 ◽  
Vol 2019 ◽  
pp. 1-7 ◽  
Author(s):  
Tian Xiaoge ◽  
Ren Zhang ◽  
Yichao Xv ◽  
Yantian Chu ◽  
Zhen Yang ◽  
...  
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Asphalt Binder ◽  
Warm Mix Asphalt ◽  
Performance Tests ◽  
Mixing Process ◽  
Microscopic Mechanism ◽  
Modified Asphalt ◽  
Infrared Spectrometer ◽  
Sbs Modified Asphalt

In order to figure out the influence of the warm-mix agent EC-120 on the performance of the asphalt binder and its micro mechanism in warm-mixing process, a matrix asphalt, A-70, and SBS-modified asphalt, SBS I-D, were modified with different contents of EC-120, respectively. Then, conventional macromechanic performance tests, dynamic shear rheological (DSR) test at high-temperature, and bending beam rheological (BBR) test at low-temperature were carried out on asphalt binder samples. Meanwhile, they were microscopically analyzed through Fourier transform infrared spectrometer (FTIR) and differential scanning calorimeter (DSC). The results indicated that EC-120 can reduce the viscosity of asphalt binder at high temperature. With the increase of EC-120 content, the high-temperature rutting resistance of two kinds of warm-mix asphalt (WMA) increased, but their crack resistance at low-temperature was reduced. FTIR indicated that this is due to the generation of oxides containing carbonyl functional groups after EC-120 was blended with asphalt binder. The DSC endothermic curves of WMA binders are obviously different from those of base binders, and a strong endothermic peak appears in the interval of 102°C–113°C, indicating that EC-120 will endothermically melt at the temperature of 102°C∼113°C, so it can play the role in reducing the viscosity of asphalt binder at the range of construction temperatures.

scholarly journals Multiple Stress Creep Recovery (MSCR) Test for Determination of Waste Engine Oil Modified Asphalt Binder as Pavement Material

2022 ◽  
pp. 8-14
Author(s):  
Biruk Tadele ◽  
Emer T Quezon
Keyword(s):  
Asphalt Binder ◽  
Engine Oil ◽  
Creep Recovery ◽  
Multiple Stress ◽  
Modified Asphalt ◽  
Waste Engine Oil ◽  
Modified Asphalt Binder ◽  
Multiple Stress Creep Recovery ◽  
Modified Binder ◽  
Pavement Material

Engineers have been using modified binders to improve the quality of flexible pavements. The use of waste material is one of the solutions taken in this direction. It is for this ground that the studies emphasis on the evaluation of waste engine oil as a modifier for asphalt binder as a pavement material. In the study uses four samples extracted from 80/100 penetration grade bitumen. From four sample first sample was checked for weather requirements of asphalt binder meet or not and the three were modified with different content of engine oil (3,6 and 9%). The behaviors of both unmodified and modified binder were checked for rheological properties. Dynamic shear rheometer (DSR) was used to determine high temperature performance grade (PG) and multiple stress creep recovery tests to determine rutting resistance properties of the binder. PG analysis indicates that both aged and un-aged 3% and 6% modified binder have similar higher PG grade with the unmodified one and 9% modified to have lower PG vale. Jnr3.2 value of modified asphalt binder is lower than unmodified binder indicating that modification had improved the rutting resistance and design traffic load (ESALS). The study shows that it is possible to use waste engine oil-modified binder as a pavement material.

scholarly journals Impact of Ultraviolet Radiation on the Aging Properties of SBS-Modified Asphalt Binders

Polymers ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1111 ◽  
Author(s):  
Huanan Yu ◽  
Xianping Bai ◽  
Guoping Qian ◽  
Hui Wei ◽  
Xiangbing Gong ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Uv Radiation ◽  
Asphalt Pavement ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Shrinkage Stress ◽  
Uv Aging ◽  
Modified Asphalt ◽  
Aging Properties ◽  
Sbs Modified Asphalt

Styrene Butadiene Styrene (SBS) polymer-modified asphalt binders have become widely used in asphalt pavement because of their advantages in high- and low-temperature performance and fatigue resistance. Asphalt pavement is inevitably exposed to sunlight and ultraviolet (UV) radiation during its construction and service life. However, consideration of the aging effect of UV radiation is still limited in current pavement design and evaluation systems. In order to evaluate the impact of UV radiation on the aging properties of SBS-modified asphalt binders, UV aging tests were performed on Rolling Thin Film Oven Test (RTFOT)-aged samples with different UV radiation intensities and aging times. Sixteen different groups of tests were conducted to compare the rheological properties and functional group characteristics of SBS-modified asphalt binders. Dynamic Shear Rheometer (DSR), Bending Beam Rheometer (BBR), FTIR, and SEM tests were conducted to evaluate the aging mechanisms in various UV aging conditions. The results found that UV radiation seriously destroys the network structure formed by the cross-linking effect in SBS-modified asphalt binders, which aggravates the degradation of SBS and results in a great change of rheological properties after UV aging. The nature of SBS-modified asphalt binder aging resulted from the degradation of SBS and the changes of asphalt binder base composition, which lead to the transformation of colloidal structure and the deterioration of asphalt binder performance. The tests also found that continuous UV radiation can increase shrinkage stress in the asphalt binder surface and leads to surface cracking of the asphalt binder.

scholarly journals Study on Properties of Bone Glue/Polyurethane Composite Modified Asphalt and Its Mixture

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3769
Author(s):  
Wei Yan ◽  
Yangjia Ou ◽  
Jing Xie ◽  
Tuo Huang ◽  
Xinghai Peng
Keyword(s):  
Rheological Properties ◽  
Performance Test ◽  
Asphalt Mixture ◽  
High Temperature Stability ◽  
Road Engineering ◽  
Modified Asphalt ◽  
Polyurethane Composite ◽  
Sbs Modified Asphalt ◽  
Composite Modification ◽  
Bone Glue

Composite modification technology is widely used in the materials field. To enhance the property of polyurethane modified asphalt and realize its application in road engineering, the bone glue/polyurethane composite modified asphalt (CMA) was prepared using bone glue, polyurethane, and neat asphalt in this research. The bone glue content ranges 5–10%, that of the polyurethane is 1–5%. The relationship between the modifier’s content and the conventional properties and rheological properties of CMA was revealed by response surface methodology (RSM). The CMA performance was further verified under the optimal content of the bone glue and polyurethane. The differences of properties of styrene–butadienestyrene (SBS) modified asphalt mixture, neat asphalt mixture, and bone glue/polyurethane CMA mixture were compared and analyzed by using the pavement performance test. The results showed that the CMA’s conventional properties and rheological properties are improved. The optimal bone glue content and polyurethane content determined by RSM are 6.848% and 2.759%, respectively. The low-temperature crack resistance and water stability of the CMA mixture are enhanced, better than neat asphalt mixture and SBS modified asphalt mixture. The CMA mixture’s dynamic stability is 85% of SBS modified asphalt mixture, but it is 2.4 times of neat asphalt mixture. The result indicated that the bone glue/polyurethane CMA mixture still has certain advantages of high-temperature stability. In this research, the composite modification of bone glue and polyurethane can significantly enhance the characteristic of asphalt and asphalt mixture and provide a new method for applying and promoting polyurethane modified asphalt in road engineering.

scholarly journals Study on Properties of Drainage SBS Modified Asphalt Mixture with Fiber

2021 ◽  
Vol 2021 ◽  
pp. 1-17
Author(s):  
Zhenxia Li ◽  
Tengteng Guo ◽  
Yuanzhao Chen ◽  
Menghan Zhang ◽  
Qingyu Xu ◽  
...  
Keyword(s):  
Low Temperature ◽  
Asphalt Binder ◽  
Asphalt Mixture ◽  
Three Dimensional ◽  
Basalt Fiber ◽  
Temperature Stability ◽  
High Temperature Stability ◽  
Modified Asphalt ◽  
The Road ◽  
Sbs Modified Asphalt

In order to improve the road performance of drainage SBS modified asphalt mixture, basalt fiber was added to prepare drainage styrene-butadiene-styrene (SBS) modified asphalt mixture. The viscosity-toughness, toughness, and 60°C dynamic viscosity of SBS modified asphalt were tested. The modification effect was evaluated from the perspective of high and low temperature rheological properties by dynamic shear rheometer (DSR) and bending beam rheometer (BBR) tests. The high temperature stability, water stability, low temperature crack resistance, and drainage of basalt fiber SBS drainage asphalt mixture were evaluated and compared with nonfiber SBS drainage asphalt mixture and TPS drainage asphalt mixture. The morphology characteristics of asphalt mixture and the distribution of basalt fiber in the mixture were analyzed from a micro perspective. The results showed the following: the overall performance of basalt fiber is better than that of lignin fiber. SBS modifier content in 7% can meet the requirements of drainage asphalt pavement on asphalt binder. The optimum asphalt content of SBS modified asphalt mixture with basalt fiber content of 0, 0.15, 0.25, and 0.35% is 4.9, 5.05, 5.15, and 5.2%. The fiber is irregularly distributed in the mixture to form a three-dimensional network structure, which has a series skeleton function. It plays a tensile role in the initial cracking of asphalt mixture and prevents further expansion of cracks.

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