Factors Affecting Formation of Metastable Ni3C Phase in a Solution-Based Method

2008 ◽  
Vol 8 (9) ◽  
pp. 4477-4481 ◽  
Author(s):  
Yonghua Leng ◽  
Yang Liu ◽  
Xubo Song ◽  
Xingguo Li
Keyword(s):  
Organic Molecule ◽  
Nickel Nanoparticles ◽  
Ni Nanoparticles ◽  
Organic Solution ◽  
Reaction Conditions ◽  
Factors Affecting ◽  
Diffusion Controlled ◽  
Wide Range ◽  
Organometallic Precursors ◽  
Carbon Component

Ni3C nanoparticles are synthesized over a wide range of reaction conditions by thermal decomposition of organometallic precursors in the organic solution medium. It is found that Ni3C nanoparticles are formed using Ni nanoparticles as an intermediate. The carbon component originating from the organic solution medium to enter into Ni metal lattice is identified as a diffusion-controlled reaction, which is speeded up by increasing the reaction temperature and completed by prolonging the reaction time. Any organic molecule which contains active carbon atoms is found to be a good candidate as carbon source and combine with nickel nanoparticles to form Ni3C phase. Although this paper emphasizes on the preparation of metastable Ni3C phase, at the same time, this work could effectively direct the synthesis of Ni nanoparticles in organic solution, by avoiding the formation of Ni3C phase.

Factors Affecting Molecular Self-Assembly and Its Mechanism

2012 ◽  
Vol 9 (1) ◽  
pp. 43 ◽  
Author(s):  
Hueyling Tan
Keyword(s):  
Self Assembly ◽  
Building Blocks ◽  
Molecular Engineering ◽  
Molecular Structures ◽  
Polymer Science ◽  
New Approach ◽  
Factors Affecting ◽  
Dna Structures ◽  
Self Assembling ◽  
Wide Range

Molecular self-assembly is ubiquitous in nature and has emerged as a new approach to produce new materials in chemistry, engineering, nanotechnology, polymer science and materials. Molecular self-assembly has been attracting increasing interest from the scientific community in recent years due to its importance in understanding biology and a variety of diseases at the molecular level. In the last few years, considerable advances have been made in the use ofpeptides as building blocks to produce biological materials for wide range of applications, including fabricating novel supra-molecular structures and scaffolding for tissue repair. The study ofbiological self-assembly systems represents a significant advancement in molecular engineering and is a rapidly growing scientific and engineering field that crosses the boundaries ofexisting disciplines. Many self-assembling systems are rangefrom bi- andtri-block copolymers to DNA structures as well as simple and complex proteins andpeptides. The ultimate goal is to harness molecular self-assembly such that design andcontrol ofbottom-up processes is achieved thereby enabling exploitation of structures developed at the meso- and macro-scopic scale for the purposes oflife and non-life science applications. Such aspirations can be achievedthrough understanding thefundamental principles behind the selforganisation and self-synthesis processes exhibited by biological systems.

Uphoff Norman, Priti Ramamurthy, and Roy Steiner. Managing Irrigation: Analysing and Improving the Performance of Bureaucracies. New Delhi/Newbury Park/London: Sage Publications. 1991. Hardbound. Price not given.

1993 ◽  
Vol 32 (2) ◽  
pp. 226-228
Author(s):  
Zakir Hussain
Keyword(s):  
Water Distribution ◽  
Irrigation System ◽  
Irrigation Management ◽  
Performance Criterion ◽  
New Delhi ◽  
Irrigation Performance ◽  
Factors Affecting ◽  
Wide Range ◽  
Resource Mobilisation ◽  
Management Issues

The book; under review provides a valuable account of the issues and factors in managing the irrigation system, and presents a lucid and thorough discussion on the performance of the irrigation bureaucracies. It comprises two parts: the first outlines the factors affecting irrigation performance under a wide range of topics in the first five chapters. In Chapter One, the authors have attempted to assess the performance of the irrigation bureaucracies, conceptualise irrigation management issues, and build an empirical base for analysis while drawing upon the experience of ten country cases in Asia, Africa, and Latin America. The Second Chapter focuses on the variations in the management structures identified and the types of irrigation systems; and it defines the variables of the management structures. The activities and objectives of irrigation management are discussed in Chapter Three. The objectives include: greater production and productivity of irrigation projects; improved water distribution; reduction in conflicts; greater resource mobilisation and a sustained system performance. The authors also highlight the performance criterion in this chapter. They identify about six contextual factors which affect the objectives and the performance of irrigation, which are discussed in detail in Chapter Four. In Chapter Five, some organisational variables, which would lead to improvements in irrigation, are examined.

Business Aviation in Russia: Specific Features and Prospects of Development

2020 ◽  
Vol 26 (1) ◽  
pp. 86-93
Author(s):  
D. V. Slivinsky ◽  
I. A. Fomina ◽  
D. G. Menshikh
Keyword(s):  
Systems Approach ◽  
National Policy ◽  
Civil Aviation ◽  
Economic Growth Rate ◽  
Factors Affecting ◽  
Organization And Management ◽  
Transport Services ◽  
Business Aviation ◽  
Wide Range

The presented study determines the role of business aviation in the modern economy and examines the specific features of its development in Russia.Aim. The study aims to analyze the development of business aviation in Russia and its correlation with economic development in general.Tasks. The authors determine the benefits of business aviation as a business tool, examine the specific features of the Russian business aviation market and problems of its development, and identify factors that affect the development of business aviation in Russia.Methods. This study uses the methods of comparative and retrospective analysis, cross-country comparison, systems approach, and expert analytics.Results. Business aviation is a new segment of civil aviation for Russia. Therefore, it is advisable to rely on foreign practices in the management of its development. In many countries, business aviation is a separate industry that specializes in providing transport services to a wide range of corporate clients and/or individuals. The development of this industry is associated with the economic growth rate and the development level of the national economy, and also depends on the national institutional specifics. This study describes the specific features of development of business aviation in Russia and problems arising in the organization and management of this type of business.Conclusions. The authors develop a system of factors affecting the development of business aviation in Russia, describe the major problems of this industry, and propose solutions. The results of this study can be used in the development (adjustment) of business aviation development strategies in Russia both at the industrial and corporate level, and in the implementation of the national policy in this field.

p-Sulfonic acid calix[n]arene catalyzed synthesis of bioactive heterocycles: A review

2020 ◽  
Vol 24 ◽  
Author(s):  
Bubun Banerjee ◽  
Gurpreet Kaur ◽  
Navdeep Kaur
Keyword(s):  
Supramolecular Chemistry ◽  
Sulfonic Acid ◽  
Catalytic Efficiency ◽  
The Other ◽  
Reaction Conditions ◽  
Metal Free ◽  
Bioactive Scaffolds ◽  
Wide Range ◽  
Efficient Alternative ◽  
Bioactive Heterocycles

: Metal-free organocatalysts are becoming an important tool for the sustainable developments of various bioactive heterocycles. On the other hand, during last two decades, calix[n]arenes have been gaining considerable attention due to their wide range of applicability in the field of supramolecular chemistry. Recently, sulfonic acid functionalized calix[n] arenes are being employed as an efficient alternative catalyst for the synthesis of various bioactive scaffolds. In this review we have summarized the catalytic efficiency of p-sulfonic acid calix[n]arenes for the synthesis of diverse biologically promising scaffolds under various reaction conditions. There is no such review available in the literature showing the catalytic applicability of p-sulfonic acid calix[n]arenes. Therefore, we strongly believe that this review will surely attract those researchers who are interested about this fascinating organocatalyst.

A Comprehensive Review on C-3 Functionalization of β-Lactams

2019 ◽  
Vol 16 (1) ◽  
pp. 3-16 ◽  
Author(s):  
Reshma Nagpal ◽  
Jitender Bhalla ◽  
Shamsher S. Bari
Keyword(s):  
Scientific Community ◽  
Organometallic Reagent ◽  
Reaction Conditions ◽  
Biological Potential ◽  
Wide Range ◽  
Economic Strategies ◽  
Synthetic Utility ◽  
Recent Advancement ◽  
Equivalent Method ◽  
Made In

Background:A lot of advancement has been made in the area of β-lactams in recent times. Most of the research is targeted towards the synthesis of novel β-lactams, their functionalization and exploring their biological potential. The C-3 functionalization of β-lactams has continued to attract considerable interest of the scientific community due to their utility as versatile intermediates in organic synthesis and their therapeutic applications. This has led to the significant increase in efforts towards developing efficient and economic strategies for C-3 functionalized β-lactams.Objective:The present review aims to highlight recent advancement made in C-3 functionalization of β-lactams.Conclusion:To summarize, functionalization of β-lactams at C-3 is an essential aspect of β-lactam chemistry in order to improve/modify its synthetic utility as well as biological potential. The C-3 carbocation equivalent method has emerged as an important and convenient strategy for C-3 functionalization of β-lactam heterocycles which provides a wide range of β-lactams viz. 3-alkylated β-lactams, 3-aryl/heteroarylated β-lactams, 3- alkoxylated β-lactams. On the other hand, base mediated functionalization of β-lactams via carbanion intermediate is another useful approach but their scope is limited by the requirement of stringent reaction conditions. In addition to this, organometallic reagent mediated α-alkylation of 3-halo/3-keto-β-lactams also emerged as interesting methods for the synthesis of functionalized β-lactams having good yields and diastereoselectivities.

The chemistry of 4-(dicyanomethylene)-3-methyl-l-phenyl-2-pyrazoline-5- ones as a privileged scaffold in synthesis of heterocycles

2020 ◽  
Vol 17 ◽  
Author(s):  
Mohsen A.-M. Gomaa ◽  
Huda A. Ali
Keyword(s):  
Building Block ◽  
Heterocyclic Compounds ◽  
Recent Progress ◽  
Reaction Conditions ◽  
Azacrown Ethers ◽  
Wide Range ◽  
Privileged Scaffold ◽  
Number Of Publications ◽  
Near Future

Background : The reactivity of 4-(dicyanomethylene)-3-methyl-l-phenyl-2-pyrazoline-5-one DCNP 1 and its derivatives makes it valuable as a building block for the synthesis of heterocyclic compounds like pyrazolo-imidazoles, - thiazoles, spiropyridines, spiropyrroles, spiropyrans and others. As a number of publications have reported on the reactivity of DCNP and its derivatives, we compiled some features of this interesting molecule. Objective: This article aims to review the preparation of DCNP, its reactivity and application in heterocyclic and dyes synthesis. Conclusion: In this review we have provided an overview of recent progress in the chemistry of DCNP and its significance in synthesis of various classes of heterocyclic compounds and dyes. The unique reactivity of DCNP offers unprecedentedly mild reaction conditions for the generation of versatile cynomethylene dyes from a wide range of precursors including amines, α-aminocarboxylic acids, their esters, phenols, malononitriles and azacrown ethers. We anticipate that more innovative transformations involving DCNP will continue to emerge in the near future.

Qualitative Analysis of Underlying Factors Affecting Vaccine Hesitancy in Iran- A Study Protocol (Preprint)

2020 ◽  
Author(s):  
Salime Goharinezhad
Keyword(s):  
Vaccine Coverage ◽  
Deep Understanding ◽  
World Health ◽  
Vaccine Hesitancy ◽  
Slight Reduction ◽  
Cultural Variation ◽  
Global Public Health ◽  
Factors Affecting ◽  
Wide Range ◽  
Context Specific

BACKGROUND World Health Organization declared the vaccine hesitancy as a global public health threat in 2019. Since even a slight reduction in vaccine coverage rates can lead to a decrease in herd immunity, it is imperative to explore the underlying factors affecting vaccine hesitancy. in specific contexts, considering socioeconomic and cultural variation, to ensure interventions targeting hesitancy are well formulated and intervened. OBJECTIVE The main objective of this study is to identify underlying factors affecting vaccine hesitancy in Iran. METHODS A framework qualitative study will be conducted in the west of Tehran province in 2020. Participants in the study will be recruited hesitance-parents who extracted from the SIB system (an electronic health record in Iran) to maximize diversity. Interviews will be analyzed based on ''Determinants of Vaccine Hesitancy Matrix'' which developed by the WHO-SAGE Working Group. RESULTS deep understanding from the context-specific reasons for vaccine hesitancy cause to formulate better strategies to address them. The ultimate goal of this study is to inform future policies to increase the uptake of the vaccine in Iran. CONCLUSIONS This result of study will show variety opinions about vaccination among different types of socioeconomic and demographic households. The wide range of reasons related to vaccine hesitancy imply to more comprehensive, context-specific interventions. Today, the most important intervention issues focus on improving information about effectiveness and safety of vaccines, while other interventions for promoting vaccination is need to addressed.

scholarly journals Factors Affecting Acoustic Properties of Natural-Fiber-Based Materials and Composites: A Review

Textiles ◽  
2021 ◽  
Vol 1 (1) ◽  
pp. 55-85
Author(s):  
Tufail Hassan ◽  
Hafsa Jamshaid ◽  
Rajesh Mishra ◽  
Muhammad Qamar Khan ◽  
Michal Petru ◽  
...  
Keyword(s):  
Sound Absorption ◽  
Natural Fiber ◽  
Volume Fraction ◽  
Fiber Type ◽  
Alkali Treatment ◽  
Acoustic Properties ◽  
Synthetic Fiber ◽  
Sound Insulation ◽  
Factors Affecting ◽  
Wide Range

Recently, very rapid growth has been observed in the innovations and use of natural-fiber-based materials and composites for acoustic applications due to their environmentally friendly nature, low cost, and good acoustic absorption capability. However, there are still challenges for researchers to improve the mechanical and acoustic properties of natural fiber composites. In contrast, synthetic fiber-based composites have good mechanical properties and can be used in a wide range of structural and automotive applications. This review aims to provide a short overview of the different factors that affect the acoustic properties of natural-fiber-based materials and composites. The various factors that influence acoustic performance are fiber type, fineness, length, orientation, density, volume fraction in the composite, thickness, level of compression, and design. The details of various factors affecting the acoustic behavior of the fiber-based composites are described. Natural-fiber-based composites exhibit relatively good sound absorption capability due to their porous structure. Surface modification by alkali treatment can enhance the sound absorption performance. These materials can be used in buildings and interiors for efficient sound insulation.

Factors affecting red-osier dogwood seed germination

1992 ◽  
Vol 70 (5) ◽  
pp. 1012-1016 ◽  
Author(s):  
S. N. Acharya ◽  
C. B. Chu ◽  
R. Hermesh ◽  
G. B. Schaalje
Keyword(s):  
Seed Germination ◽  
Germination Percentage ◽  
Collection Site ◽  
Moisture Condition ◽  
Seed Formation ◽  
Factors Affecting ◽  
Year Effect ◽  
Wide Range ◽  
Cornus Stolonifera ◽  
Moisture Conditions

Seeds from 55 populations of native Alberta red-osier dogwood (Cornus stolonifera Michx.) were collected over 2 years (1984 and 1985) to determine the range of variability for seed germination and the effect of ecoregion and moisture conditions in the collection sites on this trait. Each year the unscarified seeds were stored at 3 °C for 30 days, stratified at 3 °C for an additional 30 days and then incubated on an 8 h light: 16 h dark cycle at a temperature of 25:10 °C (light:dark) for germination. A wide range of germination percentages was observed among populations collected in any 1 year. However, the variability was not due to the ecoregion or moisture condition of the collection site. Germination percentage of populations collected in 1984 and 1985 formed five and seven groups, respectively. A study involving eight sites that were common to 1984, 1985, and 1986 revealed a significant effect of population on seed germination. This population effect was not obscured by the combined effects of year, precipitation, temperature, and seed size. The year effect was significant only when population was used as a covariate. Precipitation during seed formation significantly influenced germination performance even after adjustments were made for population and year. Seed germination in red-osier dogwood appears to be influenced by the population from which the seeds are collected and by yearly environmental fluctuations. Therefore, germination studies in this species must include seeds from diverse populations collected over several years. Key words: red-osier dogwood, Cornus stolonifera Michx., germination, population, environment.

Historical Dynamics

2018 ◽  
Author(s):  
Peter Turchin
Keyword(s):  
Religious Conversion ◽  
Synthetic Approach ◽  
Dynamical Processes ◽  
Factors Affecting ◽  
Historical Processes ◽  
Wide Range ◽  
Historical Dynamics ◽  
State Breakdown ◽  
Political Economic ◽  
High Degree

Many historical processes are dynamic. Populations grow and decline. Empires expand and collapse. Religions spread and wither. Natural scientists have made great strides in understanding dynamical processes in the physical and biological worlds using a synthetic approach that combines mathematical modeling with statistical analyses. Taking up the problem of territorial dynamics—why some polities at certain times expand and at other times contract—this book shows that a similar research program can advance our understanding of dynamical processes in history. The book develops hypotheses from a wide range of social, political, economic, and demographic factors: geopolitics, factors affecting collective solidarity, dynamics of ethnic assimilation/religious conversion, and the interaction between population dynamics and sociopolitical stability. It then translates these into a spectrum of mathematical models, investigates the dynamics predicted by the models, and contrasts model predictions with empirical patterns. The book's highly instructive empirical tests demonstrate that certain models predict empirical patterns with a very high degree of accuracy. For instance, one model accounts for the recurrent waves of state breakdown in medieval and early modern Europe. And historical data confirm that ethno-nationalist solidarity produces an aggressively expansive state under certain conditions (such as in locations where imperial frontiers coincide with religious divides). The strength of the book's results suggests that the synthetic approach advocated can significantly improve our understanding of historical dynamics.

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