Synthesis and Electroluminescence Property of Anthracene Green Fluorescent Derivatives Based on Optimized Side Groups

2021 ◽  
Vol 21 (7) ◽  
pp. 4037-4041
Author(s):  
Sangshin Park ◽  
Hyukmin Kwon ◽  
Seokwoo Kang ◽  
Sunwoo Park ◽  
Hyocheol Jung ◽  
...  
Keyword(s):  
Electric Field ◽  
Energy Conversion ◽  
Current Efficiency ◽  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
High Efficiency ◽  
Molecular Size ◽  
Green Fluorescent ◽  
Fluorescent Derivatives ◽  
Electroluminescence Property

Molecular size of OLED emitting materials is nano-metric size and when it is applied to the electric field it emits the light based on the energy conversion result. As new green fluorescent emitters, N,N,N',N'-Tetra-m-tolyl-anthracene-9,10-diamine (m-Me-TAD) and N,N,N',N'-Tetra-p-tolyl-anthracene-9,10-diamine (p-Me-TAD) were synthesized and the properties were evaluated. In solution state, photoluminescence (PL) maximum wavelength is 517 nm for m-Me-TAD and 529 nm for p-Me-TAD. In electroluminescence (EL) spectra, EL maximum wavelength of m-Me-TAD is 518 nm and p-Me-TAD is 533 nm. The doped device using m-Me-TAD as green fluorescent dopant exhibited current efficiency (CE) of 17.41 cd/A and external quantum efficiency (EQE) of 7.41%. The doped device with p-Me-TAD was optimized in order to achieve a green OLED with high efficiency.

High Efficiency Green Fluorescent Dopant Through the Optimized Side Group for Organic Light Emitting Diodes

2021 ◽  
Vol 21 (7) ◽  
pp. 4000-4004
Author(s):  
Hyukmin Kwon ◽  
Seokwoo Kang ◽  
Sangshin Park ◽  
Sunwoo Park ◽  
Seungeun Lee ◽  
...  
Keyword(s):  
Current Efficiency ◽  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
High Efficiency ◽  
Green Light ◽  
Molecular Size ◽  
Electrical Energy ◽  
Light Emitting ◽  
Tert Butyl ◽  
Green Fluorescent

OLED light emitting materials have a molecular size corresponding to the nano scale and are converted into light energy when given electrical energy. The new green fluorescent dopant material was successfully synthesized by using anthracene as a central core and introducing a methyl group and tert-butyl group at various positions as diphenylamine group. Two compounds are N9,N9,N10,N10-tetraphenylanthracene-9,10-diamine (TAD) and N9,N10-bis(4-(tert-butyl) phenyl)-N9,N10-di-o-tolylanthracene-9,10-diamine (p-Tb-o-Me-TAD). The synthesized material emits green light with the maximum wavelengths of 508 and 523 nm. p-Tb-o-Me-TAD shows excellent PLQY of 86.2% in solution state. When the synthesized material was used as a dopant in a device, TAD showed current efficiency (CE) of 17.71 cd/A and external quantum efficiency (EQE) of 6.11%. The device using p-Tb-o-Me-TAD dopant exhibited current efficiency (CE) of 24.24 cd/A and external quantum efficiency (EQE) of 7.27%.

High-efficiency organic light-emitting diodes of phosphorescent PtAg2heterotrinuclear acetylide complexes supported by triphosphine

2017 ◽  
Vol 5 (12) ◽  
pp. 3072-3078 ◽  
Author(s):  
Yi-Peng Li ◽  
Xin-Xia Fan ◽  
Yue Wu ◽  
Xian-Chong Zeng ◽  
Jin-Yun Wang ◽  
...  
Keyword(s):  
Current Efficiency ◽  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
High Efficiency ◽  
Organic Light Emitting Diodes ◽  
Light Emitting ◽  
Heterometallic Cluster ◽  
Organic Light ◽  
New Type ◽  
Heterometallic Cluster Complexes

Platinum(ii)–silver(i) heterometallic cluster complexes are used as a new type of phosphorescent dopant to achieve high-efficiency OLEDs with 67.4 cd A−1peak current efficiency (CE) and 17.4% external quantum efficiency (EQE).

High-efficiency solution-processed OLEDs based on cationic Ag6Cu heteroheptanuclear cluster complexes with aromatic acetylides

2016 ◽  
Vol 4 (9) ◽  
pp. 1787-1794 ◽  
Author(s):  
Liang-Jin Xu ◽  
Xu Zhang ◽  
Jin-Yun Wang ◽  
Zhong-Ning Chen
Keyword(s):  
Current Efficiency ◽  
Quantum Efficiency ◽  
Bias Voltage ◽  
External Quantum Efficiency ◽  
High Efficiency ◽  
Solution Processed ◽  
Cluster Complexes ◽  
Highly Efficient ◽  
A Current

Strongly phosphorescent cationic Ag6Cu cluster complexes show highly efficient electroluminescence from solution-processed OLEDs with a current efficiency of 42.5 cd A−1 and an external quantum efficiency of 13.9% at a low bias voltage (4.5 V).

scholarly journals Pyridinyl-Carbazole Fragments Containing Host Materials for Efficient Green and Blue Phosphorescent OLEDs

Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4615
Author(s):  
Dovydas Blazevicius ◽  
Daiva Tavgeniene ◽  
Simona Sutkuviene ◽  
Ernestas Zaleckas ◽  
Ming-Ruei Jiang ◽  
...  
Keyword(s):  
Current Efficiency ◽  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
Power Efficiency ◽  
Triplet Energy ◽  
New Host ◽  
High Brightness ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Host Materials

Pyridinyl-carbazole fragments containing low molar mass compounds as host derivatives H1 and H2 were synthesized, investigated, and used for the preparation of electro-phosphorescent organic light-emitting devices (PhOLEDs). The materials demonstrated high stability against thermal decomposition with the decomposition temperatures of 361–386 °C and were suitable for the preparation of thin amorphous and homogeneous layers with very high values of glass transition temperatures of 127–139 °C. It was determined that triplet energy values of the derivatives are, correspondingly, 2.82 eV for the derivative H1 and 2.81 eV for the host H2. The new derivatives were tested as hosts of emitting layers in blue, as well as in green phosphorescent OLEDs. The blue device with 15 wt.% of the iridium(III)[bis(4,6-difluorophenyl)-pyridinato-N,C2′]picolinate (FIrpic) emitter doping ratio in host material H2 exhibited the best overall characteristics with a power efficiency of 24.9 lm/W, a current efficiency of 23.9 cd/A, and high value of 10.3% of external quantum efficiency at 100 cd/m2. The most efficient green PhOLED with 10 wt% of Ir(ppy)3 {tris(2-phenylpyridine)iridium(III)} in the H2 host showed a power efficiency of 34.1 lm/W, current efficiency of 33.9 cd/A, and a high value of 9.4% for external quantum efficiency at a high brightness of 1000 cd/m2, which is required for lighting applications. These characteristics were obtained in non-optimized PhOLEDs under an ordinary laboratory atmosphere and could be improved in the optimization process. The results demonstrate that some of the new host materials are very promising components for the development of efficient phosphorescent devices.

Ultra high-efficiency multi-photon emission blue phosphorescent OLEDs with external quantum efficiency exceeding 40%

2012 ◽  
Vol 13 (11) ◽  
pp. 2615-2619 ◽  
Author(s):  
Hisahiro Sasabe ◽  
Kazuhiro Minamoto ◽  
Yong-Jin Pu ◽  
Masakatsu Hirasawa ◽  
Junji Kido
Keyword(s):  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
High Efficiency ◽  
Photon Emission ◽  
Blue Phosphorescent

scholarly journals Record High External Quantum Efficiency of 19.2% Achieved in Light-Emitting Diodes of Colloidal Quantum Wells Enabled by Hot-Injection Shell Growth

2019 ◽  
Author(s):  
Baiquan Liu ◽  
Yemliha Altintas ◽  
Lin Wang ◽  
Sushant Shendre ◽  
Manoj Sharma ◽  
...  
Keyword(s):  
Quantum Wells ◽  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
High Performance ◽  
High Efficiency ◽  
Light Emitting Diodes ◽  
Shell Growth ◽  
Light Emitting ◽  
Hot Injection ◽  
Key Factor

<p> Colloidal quantum wells (CQWs) are regarded as a new, highly promising class of optoelectronic materials thanks to their unique excitonic characteristics of high extinction coefficient and ultranarrow emission bandwidth. Although the exploration of CQWs in light-emitting diodes (LEDs) is impressive, the performance of CQW-LEDs lags far behind compared with other types of LEDs (e.g., organic LEDs, colloidal quantum-dot LEDs, and perovskite LEDs). Herein, for the first time, the authors show high-efficiency CQW-LEDs reaching close to the theoretical limit. A key factor for this high performance is the exploitation of hot-injection shell (HIS) growth of CQWs, which enables a near-unity photoluminescence quantum yield (PLQY), reduces nonradiative channels, ensures smooth films and enhances the stability. Remarkably, the PLQY remains 95% in solution and 87% in film despite rigorous cleaning. Through systematically understanding their shape-, composition- and device- engineering, the CQW-LEDs using CdSe/Cd<sub>0.25</sub>Zn<sub>0.75</sub>S core/HIS CQWs exhibit a maximum external quantum efficiency of 19.2%. Additionally, a high luminance of 23,490 cd m<sup>-2</sup>, extremely saturated red color with the Commission Internationale de L’Eclairage coordinates of (0.715, 0.283) and stable emission are obtained. The findings indicate that HIS grown CQWs enable high-performance solution-processed LEDs, which may pave the path for CQW-based display and lighting technologies.</p>

Photoluminescence and electroluminescence of cationic PtAu2 heterotrinuclear complexes with aromatic acetylides

2017 ◽  
Vol 46 (3) ◽  
pp. 865-874 ◽  
Author(s):  
Li-Yi Zhang ◽  
Liang-Jin Xu ◽  
Jin-Yun Wang ◽  
Xian-Chong Zeng ◽  
Zhong-Ning Chen
Keyword(s):  
Current Efficiency ◽  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
Solution Process ◽  
Heterometallic Complexes ◽  
Highly Efficient

Cationic PtAu2 heterometallic complexes are used as phosphorescent emitters for highly efficient electroluminescent OLEDs through a solution process with the highest current efficiency of 51.7 cd A−1 and external quantum efficiency of 14.5%.

High-efficiency, deep blue ZnCdS/CdxZn1−xS/ZnS quantum-dot-light-emitting devices with an EQE exceeding 18%

Nanoscale ◽  
2018 ◽  
Vol 10 (12) ◽  
pp. 5650-5657 ◽  
Author(s):  
Ouyang Wang ◽  
Lei Wang ◽  
Zhaohan Li ◽  
Qiulei Xu ◽  
Qingli Lin ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Quantum Dot ◽  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
High Efficiency ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Deep Blue

18% peak external quantum efficiency (EQE) for deep blue QLEDs by using ZnCdS/CdxZn1−xS/ZnS quantum dots.

Dopant preferential site occupation and high efficiency white emission in K2BaCa(PO4)2:Eu2+,Mn2+ phosphors for high quality white LED applications

2019 ◽  
Vol 6 (5) ◽  
pp. 1289-1298 ◽  
Author(s):  
Xinguo Zhang ◽  
Zhenpeng Zhu ◽  
Ziying Guo ◽  
Zishan Sun ◽  
Zichao Yang ◽  
...  
Keyword(s):  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
High Efficiency ◽  
White Led ◽  
High Quality ◽  
White Emission ◽  
Site Occupation ◽  
Preferential Site ◽  
Color Tunable

Novel color-tunable and white-emitting K2BaCa(PO4)2:Eu2+,Mn2+ phosphors with external quantum efficiency of 70% were developed for NUV LED.

Efficient electroluminescence of bluish green iridium complexes with 2-(3,5-bis(trifluoromethyl)phenyl)pyrimidine and 2-(3,5-bis(trifluoromethyl)phenyl)-5-fluoropyrimidine as the main ligands

2018 ◽  
Vol 5 (7) ◽  
pp. 1545-1552 ◽  
Author(s):  
Hua-Bo Han ◽  
Zheng-Guang Wu ◽  
You-Xuan Zheng
Keyword(s):  
Current Efficiency ◽  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
Iridium Complexes ◽  
Bluish Green ◽  
Maximum Current

Four bluish green iridium complexes with high photoluminescence quantum efficiencies were applied in OLEDs, and they showed a maximum current efficiency of 74.70 cd A−1 and a maximum external quantum efficiency of 35.0% with mild efficiency roll-off.

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