Comparison of processing and mechanical properties of polypropylene/recycled acrylonitrile butadiene rubber/rice husk powder composites modified with silane and acetic anhydride compound

2013 ◽  
Vol 27 (12) ◽  
pp. 1651-1666 ◽  
Author(s):  
S Ragunathan ◽  
H Ismail ◽  
K Hussin
2013 ◽  
Vol 795 ◽  
pp. 441-445
Author(s):  
Santiagoo Ragunathan ◽  
S.T. Sam ◽  
N.Z. Noriman ◽  
W.A. Amneera ◽  
A.M. Andrew ◽  
...  

Polypropylene (PP)/Acrylonitrile butadiene rubber (NBRr)/rice husk powder (RHP) composites was fabricated with silane and acetic anhydride treatment agent. The in-situ formed RHP filled PP/NBRr composites were prepared by melt mixing technique using Haake internal mixer at 180 °C. The tensile properties of the both treatment methods were invesigated with Instron mechanical analysis. The results indicated that acetic anhydride treatment was found to exhibit better mechanical properties for RHP filled PP/NBRr composites. Good compatibility and stronger interaction between anhydride moieties with PP/NBRr was resulted.


2011 ◽  
Vol 471-472 ◽  
pp. 478-483 ◽  
Author(s):  
Santiagoo Ragunathan ◽  
Hanafi Ismail ◽  
Hussin Kamarudin

The effect of silane treatment on processing characteristic and swelling behavior of recycled acrylonitrile butadiene rubber (NBRr)/polypropylene (PP)/rice husk powder (RHP) composites has been studied. Polypropylene/recycled acrylonitrile butadiene rubber/rice husk powder (PP/NBRr/RHP) composite were prepared by melt mixing technique at 180º C for 9 minutes and 50rpm rotor speed using an internal mixer. Five different composites compositions (70/30/0, 7030/5, 70/30/10, 70/30/15 and 70/30/30), with silane treated RHP (treated) and without silane treatment RHP (untreated) was studied. The specimens were analyzed for swelling behavior with ASTM oil No.3 and processing torque of composites was obtained during composite preparation. The results showed that swelling percentage for both composites increased with NBRr content. However the treated composites exhibited lower swelling characteristics. Processing torque of both composites also showed higher torque reading with increasing NBRr content. However the treated composite with silane exhibited much higher torque value for similar composition composites. Better interaction between RHP filler and PP/NBRr matrixs was obtained with treated composites.


2013 ◽  
Vol 594-595 ◽  
pp. 613-617
Author(s):  
Santiagoo Ragunathan ◽  
Sung Ting Sam ◽  
Abdul Ghani Azlinda ◽  
Hussin Kamaruddin ◽  
Ismail Hanafi ◽  
...  

Composites of polypropylene/Acylonitrile butadiene rubber/Rice husk powder/ (PP/NBRr/RHP) with and without trans-polyoctylene rubber (TOR) were prepared, and the effects of trans-polyoctylene rubber were investigated. By using rice husk powder of 150300μm, five different compositions of PP/NBRr/RHP composites (i.e.100/0, 80/20, 70/30, 60/40 and 40/60 phr) were prepared in an internal mixer at 180 °C and 50 rpm rotor speed. The results indicate that the incorporation of TOR improved the tensile properties of PP/NBRr/RHPcomposites. Scanning electron microscopy of the fractured surfaces proved that TOR promoted good adhesion between the PP-NBRr matrices and RHP.Keywords: Polypropylene; Trans-polyoctylene rubber; Rice husk powder; Acrylonitrile Butadiene rubber; composite


2015 ◽  
Vol 754-755 ◽  
pp. 201-204
Author(s):  
Ragunathan Santiagoo ◽  
Sam Sung Ting ◽  
Azlinda Abdul Ghani ◽  
Hanafi Ismail ◽  
Awiezan Mislan

The compatibilizer effect of ENR-50 on the tensile properties of high density polyethylene (HDPE)/recycled acrylonitrile butadiene rubber (NBRr)/banana skin powder (BSP)/ composites has been studies. HDPE/NBRr/BSP composites were prepared by melt mixing technique using twin-screw at 180 °C for 9 minutes at rotor speed 50 rpm. The six different composites studied were 100/0/5, 80/20/5, 70/30/5, 60/40/5, 50/50/5, and 40/60/5. As for compatibilized composite a fix 5 wt% of ENR-50 was evaluated. The specimens were analysed for tensile strength and elongation at break (Eb). The results showed that tensile strength and the elongation at break were decreases with the increasing of NBRr loading. However for ENR-50 compatibilized composites, higher tensile strength and elongation at break was recorded. The ENR-50 was found to be an excellent compatibilizer for HDPE/NBRr/BSP composites.


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