scholarly journals GC-FID/MS Profiling of Supercritical CO2 Extracts of Peels from Citrus aurantium, C. sinensis cv. Washington navel, C. sinensis cv. Tarocco and C. sinensis cv. Doppio Sanguigno from Dubrovnik Area (Croatia)

2015 ◽  
Vol 10 (7) ◽  
pp. 1934578X1501000
Author(s):  
Igor Jerković ◽  
Jasmina Družić ◽  
Zvonimir Marijanović ◽  
Mirko Gugić ◽  
Stela Jokić ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Citrus Sinensis ◽  
Supercritical Co2 ◽  
Geranyl Acetate ◽  
Citrus Aurantium ◽  
Coumarin Derivatives ◽  
Linalyl Acetate ◽  
Washington Navel ◽  
Peel Oil

The peels of Citrus aurantium L. and Citrus sinensis Osbeck cultivars from the Dubrovnik region (south Croatia) were extracted by supercritical CO2 at 40°C and 10 MPa at 1.76 kg/h to obtain enriched extracts in comparison with simple pressing of the peels. The extracts were analyzed in detail by gas chromatography and mass spectrometry (GC-FID/MS). Relevant similarities among the peel oil compositions of C. aurantium and C. sinensis cultivars were found with limonene predominance (up to 54.3%). The principal oxygenated monoterpenes were linalool (3.0%–5.9%), α-terpineol (0.7%–2.4%), linalyl acetate (0.0%–5.0%), geranyl acetate (0.0%-0.4%), ( Z)-citral (0.0%–1.8%) and ( E)-citral (0.0%–1.9%). Several sesquiterpenes were found with minor percentages. Coumarin derivatives were identified in all the samples among the relevant compounds. Isogeijerin dominated in the peels of C. sinensis cv. Tarocco (15.3%) and C. aurantium (11.2%). Scoparone ranged from 0.1% to 0.5% in all the samples. Bergapten (up to 1.4%), osthole (up to 1.1%) and 7-methoxy-8-(2-formylpropyl)coumarin (up to 1.1%) were found mostly in C. sinensis cv. Doppio Sanguigno. It was possible to indicate a few other differences among the extracts such as higher percentage of linalool, linalyl and geranyl acetates, as well as the abundance of sabinene and isogeijerin in C. aurantium or the occurrence of β-sinensal in C. sinensis cultivars.

scholarly journals The Aroma Composition of Baby Ginger Paocai

2017 ◽  
Vol 2017 ◽  
pp. 1-9 ◽  
Author(s):  
Songming Luo ◽  
Qiang Li ◽  
Anjun Chen ◽  
Xingyan Liu ◽  
Biao Pu
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Volatile Compounds ◽  
Solid Phase Microextraction ◽  
Fermentation Process ◽  
Solid Phase ◽  
Relative Content ◽  
Gas Chromatography Mass Spectrometry ◽  
Geranyl Acetate ◽  
Aroma Components

The purpose of this study was to analyze the volatile compounds in baby ginger paocai and the fresh baby ginger and identify the key aroma components that contribute to the flavor of baby ginger paocai. A total of 86 volatile compounds from the two baby ginger samples were quantified; these compounds were extracted by headspace solid-phase microextraction (HS-SPME) and analyzed by gas chromatography–mass spectrometry (GC-MS). The aroma composition of baby ginger paocai was different from that of fresh baby ginger. Baby ginger paocai was characterized by the presence of aroma-active compounds which varied in concentration from 0.03 to 28.14%. Geranyl acetate was the aroma component with the highest relative content in baby ginger paocai. β-myrcene, eucalyptol, trans-β-ocimene, Z-ocimene, linalool, decanal, cis-citral, geraniol, geranyl acetate, curcumene, and β-bisabolene contributed to the overall aroma of the product of baby ginger paocai which had gone through a moderate fermentation process.

scholarly journals Essential Oil Composition of Lavandin (Lavandula x intermedia) cultivated in Bismil-Turkey

2018 ◽  
Vol 1 (1) ◽  
pp. 1120-1125
Author(s):  
Mustafa Abdullah Yilmaz
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Essential Oil ◽  
Essential Oils ◽  
Essential Oil Composition ◽  
Gas Chromatography Mass Spectrometry ◽  
Oil Composition ◽  
Linalyl Acetate ◽  
Stem Leaf ◽  
Different Parts

The goal of this study was to investigate the essential oil compositions of different parts (stem, leaf, flower and mixture) of Lavandula x intermedia in Bismil-Diyarbakır,Turkey. The chemical composition of essential oils obtained by hydrodistillation from fresh Lavandin samples were analyzed using gas chromatography-mass spectrometry (GC/MS). The results indicate the major components of the studied parts of lavandin was; linalool (24.97-2.52-43.86-39.43 %), linalyl acetate (3.,4-0.29-9.37-15.76 %), eucalyptol (33.81-43.81-18.47-12.08 %), camphor (13.12-15.91-8.72-9.21 %), endo-borneol (2.03-5.18-0.68-1.24 %) and alpha-terpineol (2.84-2.47-1.28-3.86 %) in essential oils of stem, leaf, flower and mixture parts of fresh lavandin respectively. It was understood that linalool and linalyl acetate level were the highest in flower and mix parts while eucalyptol, camphor and endo-borneol levels were the highest in stem and leaf parts of the plant.

scholarly journals Extraction of phytosterols from melon (Cucumis melo) seeds by supercritical CO2 as a clean technology

2019 ◽  
Vol 8 (1) ◽  
pp. 677-682 ◽  
Author(s):  
Mustafa Serhat Ekinci ◽  
Metin Gürü
Keyword(s):  
Mass Spectrometry ◽  
Carbon Dioxide ◽  
Gas Chromatography ◽  
Particle Size ◽  
Cucumis Melo ◽  
Supercritical Co2 ◽  
Seed Oil ◽  
Clean Technology ◽  
Gas Chromatography Mass Spectrometry ◽  
Melon Seed Oil

Abstract Extraction with supercritical carbon dioxide (SC-CO2) which is known as a clean technology was carried out to extract oil from melon (Cucumis melo) seeds. SC-CO2 extraction technique does not contaminate extracts. SC-CO2 is not a toxic and a flammable solvent. Phytosterols, natural and bioactive compounds, which is known to provide protection against various chronic diseases were examined in the seed oil by using gas chromatography – mass spectrometry (GC-MS). Stigmasterol and β-sitosterol were detected in the melon seed oil. SC-CO2 extractions were performed in a range of 30-55°C, 150-240 bar, 7-15 g CO2/min, 0.4-1.7 mm (mean particle size of the seeds) and 1-4 h. The optimal quantities of extracted oil, β-sitosterol and stigmasterol were 36.8 g/100 g seed, 304 mg/ kg seed and 121 mg/ kg seed, respectively, at 33°C, 200 bar, 11 g CO2/min, 0.4 mm and 3 h.

scholarly journals Determination of the Volatile Profile of Lemon Peel Oils as Affected by Rootstock

Foods ◽  
2020 ◽  
Vol 9 (2) ◽  
pp. 241 ◽  
Author(s):  
Marlene G. Aguilar-Hernández ◽  
Paola Sánchez-Bravo ◽  
Francisca Hernández ◽  
Ángel A. Carbonell-Barrachina ◽  
Joaquín J. Pastor-Pérez ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
The Other ◽  
Gas Chromatography Mass Spectrometry ◽  
Citrus Limon ◽  
Citrus Aurantium ◽  
Volatile Profile ◽  
The Usa ◽  
Citrus Macrophylla

Citrus limon (L.) Burm is an important crop that grows between latitudes 30° North and 30° South, the main producers being China, the USA, Mexico, India, Brazil, and Spain. In Spain, lemon grows mainly in Mediterranean areas such as Murcia, Valencia, and Andalucía. The most cultivated varieties are “Fino” and “Verna”. In this study, five varieties of lemon, “Verna”, “Bétera”, “Eureka”, “Fino 49”, and “Fino 95” were evaluated on different rootstocks: three new Forner-Alcaide (“FA13”, “FA5”, “FA517”), Citrus macrophylla, Wester, and Citrus aurantium L. Hydrodistillation was used to obtain essential oil from fresh peels and then the volatile profile was studied by gas chromatography-mass spectrometry (GC-MS). A total of 26 volatile compounds were identified, limonene being the main one followed by β-pinene, γ-terpinene, sabinene, and α-pinene. The results revealed that Forner-Alcaide rootstocks (“FA5” > “FA517” > “FA13”) proved to be the best rootstocks for the aroma quality as they led to high volatile contents, followed by C. aurantium and C. macrophylla. Among the other varieties, the most aromatic one was “Eureka”. The whole trend was as follows (in decreasing order): “Eureka” > “Bétera” > “Fino 95” > “Verna” > “Fino 49”.

Gas Chromatographic-Mass Spectrometric Analysis, Identification, and Detection of Adulteration of Natural and Concentrated Lemon Oils

1982 ◽  
Vol 65 (1) ◽  
pp. 166-171
Author(s):  
Manfred J Prager ◽  
Michael A Miskiewicz
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Capillary Gas Chromatography ◽  
Mass Spectrometric ◽  
Mass Spectrometric Analysis ◽  
Geranyl Acetate ◽  
Spectrometric Analysis ◽  
Glass Capillary ◽  
Chromatographic Mass

Abstract Lemon oils were characterized by quantitative glass capillary gas chromatography. Components present to the extent of more than 0.05% were measured and identified by mass spectrometry. In expressed lemon oils, monoterpenes and geranial were the only components present at concentrations of 1.0% or more. In concentrated lemon oils, β-caryophyllene, linalool, neral, β-terpineol, neryl acetate, and geranyl acetate were present in some samples in amounts of 1% or more. Adulteration was detected by component concentrations outside characteristic ranges for oils judged to be authentic.

Sign in / Sign up

Export Citation Format

Share Document