Experimental study in the Na2O–CaO–MgO–Al2O3–SiO2–CO2 system at 3 GPa: the effect of sodium on mantle melting to carbonate-rich liquids and implications for the petrogenesis of silicocarbonatites

2012 ◽  
Vol 76 (2) ◽  
pp. 285-309 ◽  
Author(s):  
K. R. Moore
Keyword(s):  
Sodium Content ◽  
Silicate Melts ◽  
Monovalent Cations ◽  
Silicate System ◽  
Free System ◽  
Enriched Mantle ◽  
Mantle Sources ◽  
Analogue System ◽  
Carbonated Liquids ◽  
Metasomatized Mantle

AbstractMelt compositions in equilibrium with peridotite assemblages were determined in the analogue system Na2O–CaO–MgO–Al2O3–SiO2–CO2 at 3 GPa with Ca/Ca + Mg = 0.56–0.43 and up to 6 wt.% Na2O. There is a greater compositional range generated isobarically over a larger temperature interval than in a sodium-absent system: increasing sodium content drives liquids to compositions with lower CaO and higher SiO2 concentrations. A positive correlation between silica and Na2O content of liquids produced at constant temperature is due to the depolymerization of silicate tetrahedra in the presence of monovalent cations, as in the volatile-free system. Liquids with Na2O >6 wt.% occur in association with wehrlites as the composition of diopsidic pyroxene expands towards enstatite with addition of Na2O, decreasing the orthopyroxene content of peridotite. The orthopyroxene-out curve intersects an enriched mantle solidus at 3 GPa where near-solidus liquids have Na2O = 7 1.5 wt.%. Sodium partitioning between a metaluminous liquid and clinopyroxene follows the jadeite partitioning models calculated for the dry silicate system but sodium partitions into peralkaline carbonated liquids as both the pyroxene and the carbonate molecules. The peralkaline liquids generated are essentially carbonated silicate melts that are analogous to silica-bearing carbonatites and silicocarbonatites from a range of possible metasomatized mantle sources.

Archean granitoids: classification, petrology, geochemistry and origin

2019 ◽  
Vol 489 (1) ◽  
pp. 15-49 ◽  
Author(s):  
Jean-François Moyen
Keyword(s):  
Partial Melting ◽  
Mantle Source ◽  
Enriched Mantle ◽  
Mantle Sources ◽  
Tectonic System ◽  
End Members ◽  
Continuous Range ◽  
Metasomatized Mantle

AbstractThis paper describes the petrology, geochemistry and petrogenesis of Archean granitoids. Archean granites define a continuum of compositions between several end members: (i) magmas that originated by partial melting of a range of crustal sources, from amphibolites to metasediments (‘C-type’ granitoids); and (ii) magmas that formed by partial melting of an enriched mantle source, the most common agent of enrichment being felsic (TTG) melts. Differences in the degree of metasomatism results in different primitive liquids for these ‘M-type’ granitoids.Mixed sources, differentiation and interactions between different melts resulted in a continuous range of compositions, defined by variable proportions of each end member.During the Archean, evolved crustal sources (sediments or felsic crust) and metasomatized mantle sources become increasingly more important, mirroring the progressive maturation of crustal segments and the stabilization of the global tectonic system.

scholarly journals Ore and Geochemical Specialization and Substance Sources of the Ural and Timan Carbonatite Complexes (Russia): Insights from Trace Element, Rb–Sr, and Sm–Nd Isotope Data

Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 711
Author(s):  
Irina Nedosekova ◽  
Nikolay Vladykin ◽  
Oksana Udoratina ◽  
Boris Belyatsky
Keyword(s):  
Trace Element ◽  
Mantle Source ◽  
Crustal Evolution ◽  
Trace Element Data ◽  
The Urals ◽  
Nd Isotope ◽  
Enriched Mantle ◽  
Depleted Mantle ◽  
Mantle Sources ◽  
Geochemical Specialization

The Ilmeno–Vishnevogorsk (IVC), Buldym, and Chetlassky carbonatite complexes are localized in the folded regions of the Urals and Timan. These complexes differ in geochemical signatures and ore specialization: Nb-deposits of pyrochlore carbonatites are associated with the IVC, while Nb–REE-deposits with the Buldym complex and REE-deposits of bastnäsite carbonatites with the Chetlassky complex. A comparative study of these carbonatite complexes has been conducted in order to establish the reasons for their ore specialization and their sources. The IVC is characterized by low 87Sr/86Sri (0.70336–0.70399) and εNd (+2 to +6), suggesting a single moderately depleted mantle source for rocks and pyrochlore mineralization. The Buldym complex has a higher 87Sr/86Sri (0.70440–0.70513) with negative εNd (−0.2 to −3), which corresponds to enriched mantle source EMI-type. The REE carbonatites of the Chetlassky сomplex show low 87Sr/86Sri (0.70336–0.70369) and a high εNd (+5–+6), which is close to the DM mantle source with ~5% marine sedimentary component. Based on Sr–Nd isotope signatures, major, and trace element data, we assume that the different ore specialization of Urals and Timan carbonatites may be caused not only by crustal evolution of alkaline-carbonatite magmas, but also by the heterogeneity of their mantle sources associated with different degrees of enrichment in recycled components.

Magma oxygen fugacity of mafic-ultramafic intrusions in convergent margin settings: Insights for the role of magma oxidation states on magmatic Ni-Cu sulfide mineralization

2020 ◽  
Vol 105 (12) ◽  
pp. 1841-1856 ◽  
Author(s):  
Yonghua Cao ◽  
Christina Yan Wang ◽  
Bo Wei
Keyword(s):  
Key Factors ◽  
Convergent Margin ◽  
Sulfide Deposits ◽  
Central Asian ◽  
Mantle Sources ◽  
Oxygen Buffer ◽  
Mafic Magmas ◽  
Orogenic Belts ◽  
Ocean Ridge ◽  
Metasomatized Mantle

Abstract Oxygen fugacities (fO2) of mantle-derived mafic magmas have important controls on the sulfur status and solubility of the magmas, which are key factors to the formation of magmatic Ni-Cu sulfide deposits, particularly those in convergent margin settings. To investigate the fO2 of mafic magmas related to Ni-Cu sulfide deposits in convergent margin settings, we obtained the magma fO2 of several Ni-Cu sulfide-bearing mafic-ultramafic intrusions in the Central Asian Orogenic Belt (CAOB), North China, based on the olivine-spinel oxygen barometer and the modeling of V partitioning between olivine and melt. We also calculated the mantle fO2 on the basis of V/Sc ratios of primary magmas of these intrusions. Ni-Cu sulfide-bearing mafic-ultramafic intrusions in the CAOB include arc-related Silurian-Carboniferous ones and post-collisional Permian-Triassic ones. Arc-related intrusions formed before the closure of the paleo-Asian ocean and include the Jinbulake, Heishan, Kuwei, and Erbutu intrusions. Post-collisional intrusions were emplaced in extensional settings after the closure of the paleo-Asian ocean and include the Kalatongke, Baixintan, Huangshandong, Huangshan, Poyi, Poshi, Tulaergen, and Hongqiling No. 7 intrusions. It is clear that the magma fO2 values of all these intrusions in both settings range mostly from FMQ+0.5 (FMQ means fayalite-magnetite-quartz oxygen buffer) to FMQ+3 and are generally elevated with the fractionation of magmas, much higher than that of MORBs (FMQ-1 to FMQ+0.5). However, the mantle fO2 values of these intrusions vary from ~FMQ to ~FMQ+1.0, just slightly higher than that of mid-ocean ridge basalts (MORBs) (≤FMQ). This slight difference is interpreted as the intrusions in the CAOB may have been derived from the metasomatized mantle wedges where only minor slab-derived, oxidized components were involved. Therefore, the high-magma fO2 values of most Ni-Cu sulfide-bearing mafic-ultramafic intrusions in the CAOB were attributed to the fractionation of magmas derived from the slightly oxidized metasomatized mantle. In addition, the intrusions that host economic Ni-Cu sulfide deposits in the CAOB usually have magma fO2 of >FMQ+1.0 and sulfides with mantle-like δ34S values (–1.0 to +1.1‰), indicating that the oxidized mafic magmas may be able to dissolve enough mantle-derived sulfur to form economic Ni-Cu sulfide deposits. Oxidized mafic magmas derived from metasomatized mantle sources may be an important feature of major orogenic belts.

scholarly journals Shona and Discovery Aseismic Ridge Systems, South Atlantic: Trace Element Evidence for Enriched Mantle Sources

2010 ◽  
Vol 51 (10) ◽  
pp. 2089-2120 ◽  
Author(s):  
A. le Roex ◽  
C. Class ◽  
J. O'Connor ◽  
W. Jokat
Keyword(s):  
Trace Element ◽  
South Atlantic ◽  
Enriched Mantle ◽  
Mantle Sources

Possible crustal contamination of Midcontinent Rift igneous rocks: examples from the Mineral Lake intrusions, Wisconsin

1992 ◽  
Vol 29 (6) ◽  
pp. 1140-1153 ◽  
Author(s):  
Karl E. Seifert ◽  
Zell E. Peterman ◽  
Scott E. Thieben
Keyword(s):  
Fractional Crystallization ◽  
Crustal Contamination ◽  
Flood Basalt ◽  
Igneous Rocks ◽  
Midcontinent Rift ◽  
Mafic Intrusions ◽  
Enriched Mantle ◽  
Mantle Sources ◽  
Geochemical Variations ◽  
Compositional Pattern

Interlayered mafic–telsic intrusions from the Mineral Lake intrusive complex in northwest Wisconsin reflect the typical bimodal basalt–rhyolite compositional pattern of the Midcontinent Rift flood basalt province in the Lake Superior region. The later felsic intrusions were emplaced between the mafic intrusions and overlying basalt flows, and postemplacement fractional crystallization produced gradational mineralogical and geochemical variations. Isotopic and trace-element data for the Mineral Lake intrusions are consistent with mantle sources for both mafic and felsic intrusions, with compositional differences explained by the extent of fractional crystallization and crustal contamination or mantle source characteristics.εNd–εSr plots of analyzed Midcontinent Rift igneous rocks define three largely separate isotopic fields that suggest separate sources. However, the spread in isotopic data and a spider diagram plot of mafic samples from the εNd = εSr = 0 field suggest a crustal component and derivation from depleted rather than chondritic mantle. Evolved felsic rocks plotting in two negative εNd – positive εSr fields can be explained by derivation from separate enriched mantle sources or crustal contamination or both.

scholarly journals Sub-arc mantle enrichment in the Sunda rear-arc inferred from HFSE systematics in high-K lavas from Java

2021 ◽  
Vol 177 (1) ◽  
Author(s):  
M. Kirchenbaur ◽  
S. Schuth ◽  
A. R. Barth ◽  
A. Luguet ◽  
S. König ◽  
...  
Keyword(s):  
Trace Element ◽  
Geochemical Data ◽  
Arc Volcanism ◽  
Enriched Mantle ◽  
Arc Melting ◽  
Sunda Arc ◽  
High K ◽  
Mantle Sources ◽  
Slab Tear ◽  
Arc Volcano

AbstractMany terrestrial silicate reservoirs display a characteristic depletion in Nb, which has been explained in some studies by the presence of reservoirs on Earth with superchondritic Nb/Ta. As one classical example, K-rich lavas from the Sunda rear-arc, Indonesia, have been invoked to tap such a high-Nb/Ta reservoir. To elucidate the petrogenetic processes active beneath the Java rear-arc and the causes for the superchondritic Nb/Ta in some of these lavas, we studied samples from the somewhat enigmatic Javanese rear-arc volcano Muria, which allow conclusions regarding the across-arc variations in volcanic output, source mineralogy and subduction components. We additionally report some data for an along-arc sequence of lavas from the Indonesian part of the Sunda arc, extending from Krakatoa in the west to the islands of Bali and Lombok in the east. We present major and trace element concentrations, Sr–Nd–Hf–Pb isotope compositions, and high-field-strength element (HFSE: Nb, Ta, Zr, Hf, W) concentrations obtained via isotope dilution and MC-ICP-MS analyses. The geochemical data are complemented by melting models covering different source compositions with slab melts formed at variable P–T conditions. The radiogenic isotope compositions of the frontal arc lavas in combination with their trace element systematics confirm previously established regional variations of subduction components along the arc. Melting models show a clear contribution of a sediment-derived component to the HFSE budget of the frontal arc lavas, particularly affecting Zr–Hf and W. In contrast, the K-rich rear-arc lavas tap more hybrid and enriched mantle sources. The HFSE budget of the rear-arc lavas is in particular characterized by superchondritic Nb/Ta (up to 25) that are attributed to deep melting involving overprint by slab melts formed from an enriched garnet–rutile-bearing eclogitic residue. Sub-arc slab melting was potentially triggered along a slab tear beneath the Sunda arc, which is the result of the forced subduction of an oceanic basement relief ~ 8 Myr ago as confirmed by geophysical studies. The purported age of the slab tear coincides with a paucity in arc volcanism, widespread thrusting of the Javanese basement crust as well as the short-lived nature of the K-rich rear-arc volcanism at that time.

The Early Proterozoic carbonatite complex of Angico dos Dias, Bahia State, Brazil: geochemical and Sr-Nd isotopic evidence for an enriched mantle origin

2003 ◽  
Vol 67 (5) ◽  
pp. 1039-1057 ◽  
Author(s):  
P. Antonini ◽  
P. Comin-chiaramonti ◽  
C. B. Gomes ◽  
P. Censi ◽  
B. F. Riffel ◽  
...  
Keyword(s):  
Large Scale ◽  
Alkaline Complex ◽  
Carbonatite Complex ◽  
Early Proterozoic ◽  
Isotopic Signatures ◽  
Enriched Mantle ◽  
Mantle Sources ◽  
Northern Side ◽  
Very High ◽  
Potassic Magmatism

AbstractBorehole samples of carbonatites and phlogopite-pyroxenites from the Angico dos Dias (AdD) intrusive alkaline complex, State of Bahia, Brazil, have been investigated in terms of mineralogy, geochemistry and C-O-Sr-Nd isotopes. The AdD complex, of Early Proterozoic age (2 Ga), intrudes the northern side of the São Francisco Craton. Mineralogy and petrography indicate that the studied rocks only partially preserved their magmatic textural features owing to their metamorphic re-equilibration (greenschist facies). The REE contents and LREE/HREE ratios of the AdD carbonatites are very high (mean 3979±718 ppm and La/Yb = 215±23, respectively), as for most Precambrian magmatic carbonatites. The AdD carbonatites are also enriched in 18O (δ18O = 11.9 to 15.8‰), possibly due to secondary processes (e.g. metamorphism, alteration) whereas carbon isotopes are in the range of ‘primary carbonatites’ (δ13C = –5.7 to –7.1‰). Most of the initial 87Sr/86Sr and 143Nd/144Nd values of the studied carbonatites were not appreciably modified by secondary processes. Their εtSr and εtNd values (20.0 to 25 and 0.7 to –4.5, respectively) indicate enriched mantle sources very different from the ‘depleted’ ones related to many Precambrian carbonatites from North America (0.6 –2.6 Ga) and Africa (0.5 –2.0 Ga). The Early Proterozoic Sr-Nd isotopic signatures of the AdD carbonatites are similar to those of the Early Cretaceous carbonatites from the Paraná basin. The latter carbonatites show a great isotopic variability ranging from Bulk Earth to the related potassic magmatism from Asunción-Sapucai graben in the Eastern Paraguay (K-ASU magmatism: εtSr = 35 to 50 and εtNd = –12 to –20). The very similar isotopic compositions of Precambrian and post-Palaeozoic carbonatites worldwide indicate that the subcontinental mantle variability lasted for long periods of time and indicate a large-scale mantle heterogeneity.

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