The Early Proterozoic carbonatite complex of Angico dos Dias, Bahia State, Brazil: geochemical and Sr-Nd isotopic evidence for an enriched mantle origin

2003 ◽  
Vol 67 (5) ◽  
pp. 1039-1057 ◽  
Author(s):  
P. Antonini ◽  
P. Comin-chiaramonti ◽  
C. B. Gomes ◽  
P. Censi ◽  
B. F. Riffel ◽  
...  
Keyword(s):  
Large Scale ◽  
Alkaline Complex ◽  
Carbonatite Complex ◽  
Early Proterozoic ◽  
Isotopic Signatures ◽  
Enriched Mantle ◽  
Mantle Sources ◽  
Northern Side ◽  
Very High ◽  
Potassic Magmatism

AbstractBorehole samples of carbonatites and phlogopite-pyroxenites from the Angico dos Dias (AdD) intrusive alkaline complex, State of Bahia, Brazil, have been investigated in terms of mineralogy, geochemistry and C-O-Sr-Nd isotopes. The AdD complex, of Early Proterozoic age (2 Ga), intrudes the northern side of the São Francisco Craton. Mineralogy and petrography indicate that the studied rocks only partially preserved their magmatic textural features owing to their metamorphic re-equilibration (greenschist facies). The REE contents and LREE/HREE ratios of the AdD carbonatites are very high (mean 3979±718 ppm and La/Yb = 215±23, respectively), as for most Precambrian magmatic carbonatites. The AdD carbonatites are also enriched in 18O (δ18O = 11.9 to 15.8‰), possibly due to secondary processes (e.g. metamorphism, alteration) whereas carbon isotopes are in the range of ‘primary carbonatites’ (δ13C = –5.7 to –7.1‰). Most of the initial 87Sr/86Sr and 143Nd/144Nd values of the studied carbonatites were not appreciably modified by secondary processes. Their εtSr and εtNd values (20.0 to 25 and 0.7 to –4.5, respectively) indicate enriched mantle sources very different from the ‘depleted’ ones related to many Precambrian carbonatites from North America (0.6 –2.6 Ga) and Africa (0.5 –2.0 Ga). The Early Proterozoic Sr-Nd isotopic signatures of the AdD carbonatites are similar to those of the Early Cretaceous carbonatites from the Paraná basin. The latter carbonatites show a great isotopic variability ranging from Bulk Earth to the related potassic magmatism from Asunción-Sapucai graben in the Eastern Paraguay (K-ASU magmatism: εtSr = 35 to 50 and εtNd = –12 to –20). The very similar isotopic compositions of Precambrian and post-Palaeozoic carbonatites worldwide indicate that the subcontinental mantle variability lasted for long periods of time and indicate a large-scale mantle heterogeneity.

scholarly journals Sr-Nd-Pb-Ca Isotopes of Holocene Basalts from Jingpohu, NE China: Implications for the Origin of Their Enriched Mantle Signatures

Minerals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 790
Author(s):  
Feixiang Wei ◽  
Bo Pan ◽  
Jiandong Xu
Keyword(s):  
Volcanic Field ◽  
Magma Chambers ◽  
Ne China ◽  
Isotopic Signatures ◽  
Enriched Mantle ◽  
Depleted Mantle ◽  
Mantle Sources ◽  
Heavy Rare Earth Elements ◽  
Oceanic Island Basalts ◽  
Back Arc

The geochemistry on Holocene lavas from the Jingpohu volcanic field in NE China are compared with other Cenozoic lavas from across the back-arc rift of NE China, in order to constrain their enriched mantle sources. Holocene lavas within Jingpohu volcanic field comprise two separate “Crater Forest” (CF) and “Frog Pool” (FP) volcanic areas. FP lavas have lower MgO, CaO, and heavy rare earth elements and higher Al2O3, Na2O, K2O, and large-ion lithophile elements than CF lavas. Yet, both CF and FP lavas share similar isotopic signatures, with depleted Sr and Nd isotopes (87Sr/86Sr = 0.703915–0.704556, 143Nd/144Nd = 0.512656–0.512849) and unradiogenic Pb isotopes (208Pb/204Pb = 37.79–38.06, 207Pb/204Pb = 15.45–15.54, 206Pb/204Pb = 17.49–18.15), similar to oceanic island basalts. An important new constraint for the Jingpohu lavas lies in their Ca isotopes of δ44/40Ca from 0.63 to 0.77‰, which are lower than that of the bulk silicate earth (0.94 ± 0.05‰). By comparing the isotopic signatures of sodic lavas with that of the potassic lavas across NE China, we propose a three-component mixing model as the source for the sodic lavas. In consistence with geophysical results, we propose that subducting Pacific plate induces asthenospheric mantle upwelling of an upper depleted mantle (DM), including subducted ancient sediments (EM I), which partially melted upon ascent. These primary melts further interacted with the lithospheric mantle (EM II), before differentiating within crustal magma chambers and erupting.

scholarly journals Shell-crossing in a ΛCDM Universe

2020 ◽  
Vol 501 (1) ◽  
pp. L71-L75
Author(s):  
Cornelius Rampf ◽  
Oliver Hahn
Keyword(s):  
Dark Matter ◽  
Perturbation Theory ◽  
Large Scale ◽  
Cold Dark Matter ◽  
Three Dimensional ◽  
Random Initial Data ◽  
Recursion Relations ◽  
Indispensable Tool ◽  
First Time ◽  
Very High

ABSTRACT Perturbation theory is an indispensable tool for studying the cosmic large-scale structure, and establishing its limits is therefore of utmost importance. One crucial limitation of perturbation theory is shell-crossing, which is the instance when cold-dark-matter trajectories intersect for the first time. We investigate Lagrangian perturbation theory (LPT) at very high orders in the vicinity of the first shell-crossing for random initial data in a realistic three-dimensional Universe. For this, we have numerically implemented the all-order recursion relations for the matter trajectories, from which the convergence of the LPT series at shell-crossing is established. Convergence studies performed at large orders reveal the nature of the convergence-limiting singularities. These singularities are not the well-known density singularities at shell-crossing but occur at later times when LPT already ceased to provide physically meaningful results.

scholarly journals Assessing Annual Actual Evapotranspiration Based on Climate, Topography and Soil in Natural and Agricultural Ecosystems

Climate ◽  
2021 ◽  
Vol 9 (2) ◽  
pp. 20
Author(s):  
Kleoniki Demertzi ◽  
Vassilios Pisinaras ◽  
Emanuel Lekakis ◽  
Evangelos Tziritis ◽  
Konstantinos Babakos ◽  
...  
Keyword(s):  
Water Balance ◽  
Large Scale ◽  
Hydrological Model ◽  
Actual Evapotranspiration ◽  
Irrigated Agriculture ◽  
Climate Data ◽  
Natural Ecosystems ◽  
Loading Effects ◽  
Very High ◽  
Of Greece

Simple formulas for estimating annual actual evapotranspiration (AET) based on annual climate data are widely used in large scale applications. Such formulas do not have distinct compartments related to topography, soil and irrigation, and for this reason may be limited in basins with high slopes, where runoff is the dominant water balance component, and in basins where irrigated agriculture is dominant. Thus, a simplistic method for assessing AET in both natural ecosystems and agricultural systems considering the aforementioned elements is proposed in this study. The method solves AET through water balance based on a set of formulas that estimate runoff and percolation. These formulas are calibrated by the results of the deterministic hydrological model GLEAMS (Groundwater Loading Effects of Agricultural Management Systems) for a reference surface. The proposed methodology is applied to the country of Greece and compared with the widely used climate-based methods of Oldekop, Coutagne and Turk. The results show that the proposed methodology agrees very well with the method of Turk for the lowland regions but presents significant differences in places where runoff is expected to be very high (sloppy areas and areas of high rainfall, especially during December–February), suggesting that the proposed method performs better due to its runoff compartment. The method can also be applied in a single application considering irrigation only for the irrigated lands to more accurately estimate AET in basins with a high percentage of irrigated agriculture.

scholarly journals Development of Efficient and Selective Processes for the Synthesis of Commercially Important Chlorinated Phenols

Organics ◽  
2021 ◽  
Vol 2 (3) ◽  
pp. 142-160
Author(s):  
Keith Smith ◽  
Gamal A. El-Hiti
Keyword(s):  
Lewis Acid ◽  
Large Scale ◽  
Commercial Application ◽  
Chlorinated Phenols ◽  
Sulphur Compounds ◽  
Inorganic Solids ◽  
Solvent Free Conditions ◽  
Commercially Important ◽  
Ortho Cresol ◽  
Very High

para-Selective processes for the chlorination of phenols using sulphuryl chloride in the presence of various sulphur-containing catalysts have been successfully developed. Several chlorinated phenols, especially those derived by para-chlorination of phenol, ortho-cresol, meta-cresol, and meta-xylenol, are of significant commercial importance, but chlorination reactions of such phenols are not always as regioselective as would be desirable. We, therefore, undertook the challenge of developing suitable catalysts that might promote greater regioselectivity under conditions that might still be applicable for the commercial manufacture of products on a large scale. In this review, we chart our progress in this endeavour from early studies involving inorganic solids as potential catalysts, through the use of simple dialkyl sulphides, which were effective but unsuitable for commercial application, and through a variety of other types of sulphur compounds, to the eventual identification of particular poly(alkylene sulphide)s as very useful catalysts. When used in conjunction with a Lewis acid such as aluminium or ferric chloride as an activator, and with sulphuryl chloride as the reagent, quantitative yields of chlorophenols can be obtained with very high regioselectivity in the presence of tiny amounts of the polymeric sulphides, usually in solvent-free conditions (unless the phenol starting material is solid at temperatures even above about 50 °C). Notably, poly(alkylene sulphide)s containing longer spacer groups are particularly para-selective in the chlorination of m-cresol and m-xylenol, while, ones with shorter spacers are particularly para-selective in the chlorination of phenol, 2-chlorophenol, and o-cresol. Such chlorination processes result in some of the highest para/ortho ratios reported for the chlorination of phenols.

scholarly journals Truck Appointment System for Cooperation between the Transport Companies and the Terminal Operator at Container Terminals

2020 ◽  
Vol 11 (1) ◽  
pp. 168
Author(s):  
Hyeonu Im ◽  
Jiwon Yu ◽  
Chulung Lee
Keyword(s):  
Large Scale ◽  
Container Terminal ◽  
Container Terminals ◽  
The Past ◽  
Cooperation Model ◽  
Appointment System ◽  
New Form ◽  
Truck Appointment System ◽  
Import Container ◽  
Very High

Despite the number of sailings canceled in the past few months, as demand has increased, the utilization of ships has become very high, resulting in sudden peaks of activity at the import container terminals. Ship-to-ship operations and yard activity at the container terminals are at their peak and starting to affect land operations on truck arrivals and departures. In response, a Truck Appointment System (TAS) has been developed to mitigate truck congestion that occurs between the gate and the yard of the container terminal. The vehicle booking system is developed and operated in-house at large-scale container terminals, but efficiency is low due to frequent truck schedule changes by the transport companies (forwarders). In this paper, we propose a new form of TAS in which the transport companies and the terminal operator cooperate. Numerical experiments show that the efficiency of the cooperation model is better by comparing the case where the transport company (forwarder) and the terminal operator make their own decision and the case where they cooperate. The cooperation model shows higher efficiency as there are more competing transport companies (forwarders) and more segmented tasks a truck can reserve.

scholarly journals Ore and Geochemical Specialization and Substance Sources of the Ural and Timan Carbonatite Complexes (Russia): Insights from Trace Element, Rb–Sr, and Sm–Nd Isotope Data

Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 711
Author(s):  
Irina Nedosekova ◽  
Nikolay Vladykin ◽  
Oksana Udoratina ◽  
Boris Belyatsky
Keyword(s):  
Trace Element ◽  
Mantle Source ◽  
Crustal Evolution ◽  
Trace Element Data ◽  
The Urals ◽  
Nd Isotope ◽  
Enriched Mantle ◽  
Depleted Mantle ◽  
Mantle Sources ◽  
Geochemical Specialization

The Ilmeno–Vishnevogorsk (IVC), Buldym, and Chetlassky carbonatite complexes are localized in the folded regions of the Urals and Timan. These complexes differ in geochemical signatures and ore specialization: Nb-deposits of pyrochlore carbonatites are associated with the IVC, while Nb–REE-deposits with the Buldym complex and REE-deposits of bastnäsite carbonatites with the Chetlassky complex. A comparative study of these carbonatite complexes has been conducted in order to establish the reasons for their ore specialization and their sources. The IVC is characterized by low 87Sr/86Sri (0.70336–0.70399) and εNd (+2 to +6), suggesting a single moderately depleted mantle source for rocks and pyrochlore mineralization. The Buldym complex has a higher 87Sr/86Sri (0.70440–0.70513) with negative εNd (−0.2 to −3), which corresponds to enriched mantle source EMI-type. The REE carbonatites of the Chetlassky сomplex show low 87Sr/86Sri (0.70336–0.70369) and a high εNd (+5–+6), which is close to the DM mantle source with ~5% marine sedimentary component. Based on Sr–Nd isotope signatures, major, and trace element data, we assume that the different ore specialization of Urals and Timan carbonatites may be caused not only by crustal evolution of alkaline-carbonatite magmas, but also by the heterogeneity of their mantle sources associated with different degrees of enrichment in recycled components.

Experimental study on the progressive collapse mechanism in the braced and tied-back retaining systems of deep excavations

2020 ◽  
Author(s):  
Gang Zheng ◽  
Yawei Lei ◽  
Xuesong Cheng ◽  
Xiyuan Li ◽  
Ruozhan Wang
Keyword(s):  
Large Scale ◽  
Large Deformations ◽  
Load Transfer ◽  
Progressive Failure ◽  
Progressive Collapse ◽  
Collapse Mechanism ◽  
Bending Moments ◽  
Failure Path ◽  
Transfer Mechanisms ◽  
Very High

Collapses of braced or tied-back excavations have frequently occurred. However, the influence of the failure of some retaining structure members on the overall safety performance of a retaining system has not been studied. Model tests of failures of retaining piles, struts or anchors were conducted in this study, and the load transfer mechanisms underlying these conditions were analysed. When failures or large deformations occurred in certain piles, the increasing ratios of the bending moments in adjacent piles were much larger in the braced retaining system than in the cantilever system and more easily triggered progressive failure. When the strut elevation was lower or the excavation depth was greater, the degree of influence and range of pile failures became larger. When certain struts/anchors failed, their loads transferred to a few adjacent struts/anchors, possibly leading to further strut/anchor failure. The influence mechanisms of strut or anchor failure on piles were different from those of pile failure. As the number of failed struts or anchors increases, the bending moments of the piles in the failure zone first decrease and then increase to very high values. Therefore, the progressive failure path extends from struts/anchors to piles and will lead to large-scale collapse.

scholarly journals Adakites, High-Nb Basalts and Copper–Gold Deposits in Magmatic Arcs and Collisional Orogens: An Overview

Geosciences ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 29
Author(s):  
Pavel Kepezhinskas ◽  
Nikolai Berdnikov ◽  
Nikita Kepezhinskas ◽  
Natalia Konovalova
Keyword(s):  
Subduction Zones ◽  
Far East ◽  
Gold Deposits ◽  
Type I ◽  
Isotopic Signatures ◽  
Epithermal Mineralization ◽  
Depleted Mantle ◽  
Mantle Sources ◽  
East Russia ◽  
Collisional Orogens

Adakites are Y- and Yb-depleted, SiO2- and Sr-enriched rocks with elevated Sr/Y and La/Yb ratios originally thought to represent partial melts of subducted metabasalt, based on their association with the subduction of young (<25 Ma) and hot oceanic crust. Later, adakites were found in arc segments associated with oblique, slow and flat subduction, arc–transform intersections, collision zones and post-collisional extensional environments. New models of adakite petrogenesis include the melting of thickened and delaminated mafic lower crust, basalt underplating of the continental crust and high-pressure fractionation (amphibole ± garnet) of mantle-derived, hydrous mafic melts. In some cases, adakites are associated with Nb-enriched (10 ppm < Nb < 20 ppm) and high-Nb (Nb > 20 ppm) arc basalts in ancient and modern subduction zones (HNBs). Two types of HNBs are recognized on the basis of their geochemistry. Type I HNBs (Kamchatka, Honduras) share N-MORB-like isotopic and OIB-like trace element characteristics and most probably originate from adakite-contaminated mantle sources. Type II HNBs (Sulu arc, Jamaica) display high-field strength element enrichments in respect to island-arc basalts coupled with enriched, OIB-like isotopic signatures, suggesting derivation from asthenospheric mantle sources in arcs. Adakites and, to a lesser extent, HNBs are associated with Cu–Au porphyry and epithermal deposits in Cenozoic magmatic arcs (Kamchatka, Phlippines, Indonesia, Andean margin) and Paleozoic-Mesozoic (Central Asian and Tethyan) collisional orogens. This association is believed to be not just temporal and structural but also genetic due to the hydrous (common presence of amphibole and biotite), highly oxidized (>ΔFMQ > +2) and S-rich (anhydrite in modern Pinatubo and El Chichon adakite eruptions) nature of adakite magmas. Cretaceous adakites from the Stanovoy Suture Zone in Far East Russia contain Cu–Ag–Au and Cu–Zn–Mo–Ag alloys, native Au and Pt, cupriferous Ag in association witn barite and Ag-chloride. Stanovoy adakites also have systematically higher Au contents in comparison with volcanic arc magmas, suggesting that ore-forming hydrothermal fluids responsible for Cu–Au(Mo–Ag) porphyry and epithermal mineralization in upper crustal environments could have been exsolved from metal-saturated, H2O–S–Cl-rich adakite magmas. The interaction between depleted mantle peridotites and metal-rich adakites appears to be capable of producing (under a certain set of conditions) fertile sources for HNB melts connected with some epithermal Au (Porgera) and porphyry Cu–Au–Mo (Tibet, Iran) mineralized systems in modern and ancient subduction zones.

scholarly journals Analisis Perkembangan Kasus COVID-19 Berkaitan dengan Kebijakan Pemerintah di Pulau Jawa

2021 ◽  
Vol 9 (1) ◽  
pp. 01-12
Author(s):  
Charvia Ismi Zahrani ◽  
Setia Pramana
Keyword(s):  
Local Government ◽  
Large Scale ◽  
Government Policies ◽  
High Increase ◽  
Public Places ◽  
The Public ◽  
Social Restriction ◽  
Almost All ◽  
Death Cases ◽  
Very High

AbstractCOVID-19 is a serious problem that faced by almost all countries in the world. Since announced as a pandemic by WHO on March, the number of positive COVID-19 cases in Indonesia has reached 287,008 patients until the end of September 2020. COVID-19 cases dispersion depends on the local government policies and the awareness of the public to obey. About 60 percent of positive cases and 65 percent of death cases were in Java. Therefore, the aim of this study is to analyze the growth of the COVID-19 case in Java from March to September 2020 in relation to the local government policies. The results showed that six provinces in Java had the same pattern. The large-scale social restriction (PSBB), which was implemented since April 10 2020, seen to be able to contain the dispersion of cases because from April to June the positive cases did not increase significantly. A very high increase occurred in August and September, this was probably due to the easing of the PSBB become new-normal where various public places and facilities have been reopened. Meanwhile, death cases, the number is very high in mid-April and June and late July to September 2020. For cured cases, there was a significant increase in late August to September 2020. The importance of information about the growth of the COVID-19 cases can help government to formulate strategies and policies to prevent the dispersion of COVID-19.Keyword: COVID-19, Pandemic, Java, cases growth AbstrakCOVID-19 merupakan suatu masalah serius yang sedang dihadapi oleh hampir seluruh negara. Sejak diumumkan sebagai pandemi oleh WHO pada Maret lalu, jumlah kasus positif COVID-19 di Indonesia mencapai 287.008 pasien hingga akhir September. Penyebaran kasus COVID-19 sangat bergantung pada kebijakan yang ditetapkan oleh pemerintah serta kesadaran masyarakat untuk mematuhinya. Sebesar 60 persen kasus positif dan 65 persen kasus meninggal berada di Pulau Jawa. Oleh karena itu, tujuan penelitian ini adalah menganalisis perkembangan kasus COVID-19 di Pulau Jawa sejak Bulan Maret-September 2020 dikaitkan dengan kebijakan pemerintah setempat. Hasil penelitian menunjukkan bahwa keenam provinsi memiliki pola yang sama. Pembatasan Sosial Berskala Besar (PSBB) yang dilakukan sejak 10 April 2020 terlihat dapat menahan penyebaran kasus karena pada bulan April-Juni 2020 kasus positif tidak mengalami kenaikan yang signifikan. Kenaikan yang sangat tinggi terjadi pada bulan Agustus dan September 2020, hal ini mungkin disebabkan oleh dilonggarkannya kebijakan PSBB menjadi PSBB Transisi dimana berbagai tempat dan fasilitas umum telah dibuka kembali. Sementara untuk kasus meninggal, angka tertinggi terjadi pada pertengahan April dan Juni serta akhir Juli hingga September 2020. Untuk kasus sembuh, terjadi peningkatan yang signifikan pada akhir Agustus hingga September 2020. Pentingnya informasi tentang perkembangan kasus COVID-19 ini dapat membantu pemerintah daerah untuk membuat strategi dan kebijakan untuk mencegah penyebaran rantai virus COVID-19.Kata Kunci: COVID-19, Pandemi, Jawa, perkembangan kasus 

scholarly journals Comparison Between Pressure Swing Adsorption and Liquid Oxygen Enrichment Techniques in the Atacama Large Millimeter/Submillimeter Array Facility at the Chajnantor Plateau (5,050 m)

2021 ◽  
Vol 12 ◽  
Author(s):  
Ivan Lopez ◽  
Reinaldo Aravena ◽  
Daniel Soza ◽  
Alicia Morales ◽  
Silvia Riquelme ◽  
...  
Keyword(s):  
High Altitude ◽  
Pressure Swing Adsorption ◽  
Large Scale ◽  
High Mobility ◽  
Oxygen Enrichment ◽  
Oxygen Availability ◽  
Liquid Oxygen ◽  
High Altitudes ◽  
Pressure Swing ◽  
Very High

The Chilean workforce has over 200,000 people that are intermittently exposed to altitudes over 4,000 m. In 2012, the Ministry of Health provided a technical guide for high-altitude workers that included a series of actions to mitigate the effects of hypoxia. Previous studies have shown the positive effect of oxygen enrichment at high altitudes. The Atacama Large Millimeter/submillimeter Array (ALMA) radiotelescope operates at 5,050 m [Array Operations Site (AOS)] and is the only place in the world where pressure swing adsorption (PSA) and liquid oxygen technologies have been installed at a large scale. These technologies reduce the equivalent altitude by increasing oxygen availability. This study aims to perform a retrospective comparison between the use of both technologies during operation in ALMA at 5,050 m. In each condition, variables such as oxygen (O2), temperature, and humidity were continuously recorded in each AOS rooms, and cardiorespiratory variables were registered. In addition, we compared portable O2 by using continuous or demand flow during outdoor activities at very high altitudes. The outcomes showed no differences between production procedures (PSA or liquid oxygen) in regulating oxygen availability at AOS facilities. As a result, big-scale installations have difficulties reaching the appropriate O2 concentration due to leaks in high mobility areas. In addition, the PSA plant requires adequacy and maintenance to operate at a very high altitude. A continuous flow of 2–3 l/min of portable O2 is recommended at 5,050 m.

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