Archean granitoids: classification, petrology, geochemistry and origin

2019 ◽  
Vol 489 (1) ◽  
pp. 15-49 ◽  
Author(s):  
Jean-François Moyen

AbstractThis paper describes the petrology, geochemistry and petrogenesis of Archean granitoids. Archean granites define a continuum of compositions between several end members: (i) magmas that originated by partial melting of a range of crustal sources, from amphibolites to metasediments (‘C-type’ granitoids); and (ii) magmas that formed by partial melting of an enriched mantle source, the most common agent of enrichment being felsic (TTG) melts. Differences in the degree of metasomatism results in different primitive liquids for these ‘M-type’ granitoids.Mixed sources, differentiation and interactions between different melts resulted in a continuous range of compositions, defined by variable proportions of each end member.During the Archean, evolved crustal sources (sediments or felsic crust) and metasomatized mantle sources become increasingly more important, mirroring the progressive maturation of crustal segments and the stabilization of the global tectonic system.

Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 711
Author(s):  
Irina Nedosekova ◽  
Nikolay Vladykin ◽  
Oksana Udoratina ◽  
Boris Belyatsky

The Ilmeno–Vishnevogorsk (IVC), Buldym, and Chetlassky carbonatite complexes are localized in the folded regions of the Urals and Timan. These complexes differ in geochemical signatures and ore specialization: Nb-deposits of pyrochlore carbonatites are associated with the IVC, while Nb–REE-deposits with the Buldym complex and REE-deposits of bastnäsite carbonatites with the Chetlassky complex. A comparative study of these carbonatite complexes has been conducted in order to establish the reasons for their ore specialization and their sources. The IVC is characterized by low 87Sr/86Sri (0.70336–0.70399) and εNd (+2 to +6), suggesting a single moderately depleted mantle source for rocks and pyrochlore mineralization. The Buldym complex has a higher 87Sr/86Sri (0.70440–0.70513) with negative εNd (−0.2 to −3), which corresponds to enriched mantle source EMI-type. The REE carbonatites of the Chetlassky сomplex show low 87Sr/86Sri (0.70336–0.70369) and a high εNd (+5–+6), which is close to the DM mantle source with ~5% marine sedimentary component. Based on Sr–Nd isotope signatures, major, and trace element data, we assume that the different ore specialization of Urals and Timan carbonatites may be caused not only by crustal evolution of alkaline-carbonatite magmas, but also by the heterogeneity of their mantle sources associated with different degrees of enrichment in recycled components.


2020 ◽  
Author(s):  
Ercan Aldanmaz ◽  
Aykut Güçtekin ◽  
Özlem Yıldız-Yüksekol

<p>The Late Triassic basaltic rocks that are dispersed as several lava sheets in a number of different tectonic slices within the Antalya nappes in SW Turkey represent the remnants of widespread oceanic magmatism with strong intra-plate geochemical signatures. The largest exposures are observed around the Antalya Bay, where pillow structured or massif lava flows are interlayered with Upper Triassic pelagic or carbonate platform sediments. Based on bulk-rock geochemical characteristics, the rocks mostly classify as alkaline basalts and display distinctive OIB-type trace element distributions characterized by significant enrichments in LILE and HFSE abundances, as well as LREE/HREE ratios, with respect to average N-MORB. Quantitative modeling of trace element data suggest that the primary melts that produced the alkaline lavas are largely the products of variable proportions of mixing between melts generated by variable, but generally low (<10) degrees of partial melting of more than one compositionally distinct mantle source. The samples, as a whole, display large variations in radiogenic isotope ratios with <sup>87</sup>Sr/<sup>86</sup>Sr = 0.703021–0.70553, <sup>143</sup>Nd/<sup>144</sup>Nd = 0.51247–0.51279, <sup>206</sup>Pb/<sup>204</sup>Pb = 18.049–20.030, <sup>207</sup>Pb/<sup>204</sup>Pb = 15.544–15.723 and <sup>208</sup>Pb/<sup>204</sup>Pb = 38.546–39.530. Such variations in isotopic ratios correlate with the change in incompatible trace element relative abundances and reflect the involvement of a number of compositionally distinct mantle end-members. These include EMI and EMII type enriched mantle components both having lower <sup>143</sup>Nd/<sup>144</sup>Nd than typical depleted MORB source with their contrasting low and high <sup>206</sup>Pb/<sup>204</sup>Pb and <sup>20</sup><sup>7</sup>Pb/<sup>204</sup>Pb ratios respectively, as well as a high time-integrated <sup>238</sup>U/<sup>204</sup>Pb component with high <sup>206</sup>Pb/<sup>204</sup>Pb at relatively low <sup>87</sup>Sr/<sup>86</sup>Sr and εNd values. The results from trace element and radiogenic isotope data are consistent with the view that the initial melt generation was likely related to partial melting of the shallow convecting upper mantle in response to Triassic rifting events, while continued mantle upwelling resulted in progressively increased melting of mantle lithosphere that contained compositionally contrasting lithological domains with strong isotopic heterogeneities.</p>


2012 ◽  
Vol 76 (2) ◽  
pp. 285-309 ◽  
Author(s):  
K. R. Moore

AbstractMelt compositions in equilibrium with peridotite assemblages were determined in the analogue system Na2O–CaO–MgO–Al2O3–SiO2–CO2 at 3 GPa with Ca/Ca + Mg = 0.56–0.43 and up to 6 wt.% Na2O. There is a greater compositional range generated isobarically over a larger temperature interval than in a sodium-absent system: increasing sodium content drives liquids to compositions with lower CaO and higher SiO2 concentrations. A positive correlation between silica and Na2O content of liquids produced at constant temperature is due to the depolymerization of silicate tetrahedra in the presence of monovalent cations, as in the volatile-free system. Liquids with Na2O >6 wt.% occur in association with wehrlites as the composition of diopsidic pyroxene expands towards enstatite with addition of Na2O, decreasing the orthopyroxene content of peridotite. The orthopyroxene-out curve intersects an enriched mantle solidus at 3 GPa where near-solidus liquids have Na2O = 7 1.5 wt.%. Sodium partitioning between a metaluminous liquid and clinopyroxene follows the jadeite partitioning models calculated for the dry silicate system but sodium partitions into peralkaline carbonated liquids as both the pyroxene and the carbonate molecules. The peralkaline liquids generated are essentially carbonated silicate melts that are analogous to silica-bearing carbonatites and silicocarbonatites from a range of possible metasomatized mantle sources.


1993 ◽  
Vol 30 (6) ◽  
pp. 1141-1146 ◽  
Author(s):  
R. W. Carlson ◽  
R. A. Wiebe ◽  
R. I. Kalamarides

Basaltic dikes cutting the Nain Plutonic Suite (NPS) of Labrador include two chemically distinct groups. One is a high-Fe tholeiitic to transitional alkalic composition similar to some of the magmas involved in the formation of the NPS. The other, distinguished by high phosphorus and incompatible element contents, is similar in major element composition to intraplate oceanic alkalic basalts. A Rb–Sr mineral isochron for one high-P2O5 sample defines an age of 1276 ± 23 Ma indicating that it is similar in age to, or only slightly younger than, the circa 1305 Ma anorthosites.Compositional and isotopic characteristics of the high- and low-P2O5 dikes show that the gross features of their initial isotopic characteristics (i.e., low 87Sr/86Sr, negative εNd, nonradiogenic Pb) probably derive from a distinct lithospheric mantle source with similar characteristics. To have developed these isotopic characteristics by the time of dike emplacement, their mantle source must have formed and separated from oceanic-type upper mantle well prior to Nain anorthosite genesis, possibly between 2.0 and 2.6 Ga.


2020 ◽  
Author(s):  
Yu Zhu ◽  
shaocong Lai

<p>High-Mg<sup>#</sup> (molar 100 × Mg/(Mg + Fe)) diorites can provide significant insights on the mantle metasomatism under the subduction zone. Here we investigate the genesis of Neoproterozoic high-Mg<sup>#</sup> diorites in the western Yangtze Block to constrain mantle metasomatism during the subduction process. Zircon U-Pb dating results display new weighted mean <sup>206</sup>Pb/<sup>238</sup>U ages of 850.1 ± 1.7 Ma, 840.9 ± 2.4 Ma, and 836.6 ± 1.9 Ma for these high-Mg<sup>#</sup> diorites. They are metaluminous and calc-alkaline rocks, and characterized by moderate SiO<sub>2 </sub>(57.08–61.12 wt.%), high MgO (3.36–4.30 wt.%) and Mg<sup>#</sup> values (56–60). The relatively low initial <sup>87</sup>Sr/<sup>86</sup>Sr ratios (0.703406 to 0.704157), highly positive whole-rock εNd(t) (+3.26 to +4.26) and zircon εHf(t) values (+8.43 to +13.6) imply that they were predominantly sourced from depleted lithospheric mantle. These high-Mg<sup>#</sup> diorites also show the enrichment of large ion lithophile elements (LILEs, e.g., Rb, Ba, K, and Sr) and depletion of high field strength elements (HFSEs, e.g., Nb, Ta, Zr, and Hf), resembling typical arc magma affinity. The highly variable Rb/Y, Th/Ce, Th/Sm, and Th/Yb ratios indicate the significant incorporation of subduction-related fluids and sediment-derived melts into primary mantle source. We therefore propose that the ca. 850–835 Ma high-Mg<sup>#</sup> diorites in this study were formed by the partial melting of metasomatized mantle source influenced by subduction fluids and sediment melts. Our new data, in conjunction with numerous studies of metasomatized mantle magmatism from the western Yangtze Block, suggest that Neoproterozoic mantle sources were progressively metasomatized by the subduction-related compositions from slab fluids, sediment melts, to oceanic slab melts during persistent subduction process.</p>


1986 ◽  
Vol 23 (4) ◽  
pp. 561-578 ◽  
Author(s):  
Christian Picard ◽  
Michel Piboule

In the northeastern part of the Abitibi orogenic belt, the Archean Matagami–Chibougamou greenstone belt (2700 Ma) includes a basal volcanic sequence named the Roy Group, unconformably overlain by a volcano-sedimentary series called the Opemisca Group.The Roy Group, to the west of the town of Chapais, consists of a thick, stratified, and polycyclic volcanic series (thickness = 11 000 m) resembling the large, western Abitibi submarine stratovolcanoes constructed by three mafic to felsic magmatic cycles. The first cycle (Chrissie Formation) shows lateral spreading and is composed only of a meta-andesite and felsic pyroclastite sequence of calc-alkaline affinity. The other two cycles (Obatogamau and Waconichi formations; then Gilman, Blondeau, and Scorpio formations) are characterized by a sequence of repeated MORB type basaltic lava flows of tholeiitic affinity and by intermediate to acid lava and pyroclastic sequences calc-alkaline affinity.The stratigraphic and petrographic data suggest emplacement of mafic lavas on an abyssal plain (Obatogamau Formation) or at a later time on the flanks of a large submarine volcanic shield (Gilman and Blondeau formations). The lava and felsic pyroclastite flows were formed by very explosive eruptions from central spreading type volcanoes above a pre-existing continental crust. In particular, the Scorpio volcanic rocks were emplaced on volcanic islands later dismantled by erosion.The contents and distribution of trace elements and rare earths show that basaltic lavas resulted from an equilibrium partial melting (F = 15–35%) of spinel lherzolite type mantle sources depleted to weakly enriched in Th, Ta, Nb, and light rare-earth elements (LREE), and from fractional crystallization at low pressure of feldspar, clinopyroxene, and olivine. The lavas and the felsic pyroclastites of the Waconichi and Scorpio formations appear to result from partial melting of a mantle source of lherzolite type enriched in LREE and involving some garnet. At a late stage, the melts were probably contaminated by some continental crust materials and then differentiated by fractional crystallization of plagioclase, amphibole, biotite, and magnetite. The lavas in the Chrissie Formation and the middle member of the Gilman Formation seem to result from partial melting of a mantle source enriched in LREE with a composition between the two described above. They were subsequently modified by fractional crystallization of the plagioclase, clinopyroxene, olivine, and titanomagnetite.In general, the mafic to felsic magmatic cycles observed are characterized by a thick sequence of repeated tholeiitic basalt flows similar to those of modern mid-oceanic ridges and by a lava and felsic pyroclastite sequence of calc-alkaline affinity comparable to those occurring in orogenic belts. The transition from one lava sequence to another is marked by a significant chemical discontinuity, and the mantle sources exhibit an increasing enrichment in LREE during a given magmatic cycle. A model is proposed to satisfactorily explain all the stratigraphic, petrographic, and geochemical data implying a hot spot type mechanism, which could be responsible for the cyclic, rising diapirs inside the stratified Archean mantle and for initiating the repeated mantle source meltings, depleted and enriched in LREE, respectively. [Journal Translation]


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Samuele Agostini ◽  
Paolo Di Giuseppe ◽  
Piero Manetti ◽  
Carlo Doglioni ◽  
Sandro Conticelli

AbstractThe northern and northwestern margins of the Arabian Plate are a locus of a diffuse and long-lasting (early Miocene to Pleistocene) Na-alkali basaltic volcanism, sourced in the asthenosphere mantle. The upwelling asthenosphere at the Africa–Arabia margin produces very limited magma volumes in the axial zone. Therefore, portions of hot, fertile mantle continue their eastward migration and are stored at shallower depths under the 100-km thick Arabian lithosphere, which is much thinner than the African one (≈175 km): this causes the occurrence and 20-Ma persistence of magma supply under the study area. Erupted basalts sampled a continuous variation of the mantle source, with a striking correlation among temperature, pressure and isotopic composition shifting between two end members: a 100 km-deep, more depleted source, and a 60 km-deep, more enriched one. In particular, we observed an unusual variation in boron isotopes, which in the oceanic domain does not vary between more depleted and more enriched mantle sources. This study shows that, at least in the considered region, subcontinental mantle is more heterogeneous than the suboceanic one, and able to record for very long times recycling of shallow material.


2018 ◽  
Vol 115 (35) ◽  
pp. 8682-8687 ◽  
Author(s):  
Xiao-Jun Wang ◽  
Li-Hui Chen ◽  
Albrecht W. Hofmann ◽  
Takeshi Hanyu ◽  
Hiroshi Kawabata ◽  
...  

The extreme Sr, Nd, Hf, and Pb isotopic compositions found in Pitcairn Island basalts have been labeled enriched mantle 1 (EM1), characterizing them as one of the isotopic mantle end members. The EM1 origin has been vigorously debated for over 25 years, with interpretations ranging from delaminated subcontinental lithosphere, to recycled lower continental crust, to recycled oceanic crust carrying ancient pelagic sediments, all of which may potentially generate the requisite radiogenic isotopic composition. Here we find that δ26Mg ratios in Pitcairn EM1 basalts are significantly lower than in normal mantle and are the lowest values so far recorded in oceanic basalts. A global survey of Mg isotopic compositions of potentially recycled components shows that marine carbonates constitute the most common and typical reservoir invariably characterized by extremely low δ26Mg values. We therefore infer that the subnormal δ26Mg of the Pitcairn EM1 component originates from subducted marine carbonates. This, combined with previously published evidence showing exceptionally unradiogenic Pb as well as sulfur isotopes affected by mass-independent fractionation, suggests that the Pitcairn EM1 component is most likely derived from late Archean subducted carbonate-bearing sediments. However, the low Ca/Al ratios of Pitcairn lavas are inconsistent with experimental evidence showing high Ca/Al ratios in melts derived from carbonate-bearing mantle sources. We suggest that carbonate–silicate reactions in the late Archean subducted sediments exhausted the carbonates, but the isotopically light magnesium of the carbonate was incorporated in the silicates, which then entered the lower mantle and ultimately became the Pitcairn plume source.


1995 ◽  
Vol 59 (396) ◽  
pp. 401-408 ◽  
Author(s):  
Alan F. Cooper ◽  
Lorraine A. Paterson ◽  
David L. Reid

AbstractThe rare Li-mica taeniolite is described from the Dicker Willem carbonatite complex, Namibia, and from the Alpine carbonatitic lamprophyre dyke swarm at Haast River, New Zealand. At Haast River, taeniolite occurs in sodic and ultrasodic fenites derived from quartzo-feldspathic schists and rarely in metabasites, adjacent to dykes of tinguaite, trachyte and a spectrum of carbonatites ranging from Ca- to Fe- rich types. In Namibia, taeniolite is present in potassic fenites derived from quartz-feldspathic gneisses and granitoids at the margin of an early sövite phase of the complex and in a radial sövite dyke emanating from this centre.The occurrence of taeniolite in these totally disparate carbonatite complexes, together with examples of lithian mica from other carbonatite complexes worldwide, raises the question of the status of Li as a ‘carbonatitic element’. We argue that lithium is not a consequence of crustal assimilation or interaction, but reflects the geochemical character of the magmatic source. Li, an overlooked and little-analysed element, may be an integral part of metasomatic enrichment in the mantle, and of magmas derived by partial melting of such a source.


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