The pore types of marine shale in Longmaxi formation of the southern Sichuan and its influence on electrical characteristics

As an essential component in shale, OM (organic matter) grains and their arrangements may play essential roles in affecting the anisotropy of the reservoir. However, OM grains are commonly treated as an evenly distributed isotropic medium in current studies, and few works have been done to investigate their detailed arrangement characteristics. In this study, terrestrial and marine shale samples were collected from three different shale plays in China, and the arrangement characteristics of OM grains in each sample were investigated by SEM (scanning electron microscope) image analysis. The results indicate that OM grains in shale are not evenly distributed in isotropic medium, and their directional alignment is pervasive in both marine and terrestrial shale. OM grains in shale tend to subparallel to the bedding section, and their orientation degree and controlling factors differ among different shales. OM grains in samples from terrestrial C-7(Chang-7 Formation) exhibit the strongest directionality in their arrangement, and OM grains in samples from marine LMX (Longmaxi Formation) shale in the Fuling area also exhibit strong directional alignment. While in samples from marine LMX shale in the Baojing area, their directional alignment is much weaker. Shales with high clay content, high TOC (total organic carbon), low thermal maturity, and flat reservoir structure get more OM grains parallel to the bedding section. The biogenetic texture of graptolite in marine LMX shale is the dominating factor leading to the strong directional alignment of the OM grains. However, syncline structure may disorganize the preformed directional alignment and weaken the directionality of the OM grains, which results in the OM arrangement difference between LMX samples from Fuling and Baojing. While the compaction of the layered clay particles is the dominating mechanism leading to the strong directional alignment of the OM grains in terrestrial shale samples from C-7.

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Well logging evaluation of the shale gas potential in the lower Silurian Longmaxi Formation, Weiyuan, southern Sichuan Basin, China

Interpretation ◽

10.1190/int-2020-0069.1 ◽

2021 ◽

pp. 1-64

Author(s):

Guangzhao Zhou ◽

Zhiming Hu ◽

Xiangui Liu ◽

Xianggang Duan ◽

Jin Chang

Keyword(s):

Spatial Distribution ◽

Shale Gas ◽

Sichuan Basin ◽

Vitrinite Reflectance ◽

Well Logging ◽

Carbonaceous Shale ◽

Organic Carbon Content ◽

Type I ◽

Longmaxi Formation ◽

Marine Shale

Recent observations of shale gas breakthroughs have in the Weiyuan marine shale gas play in the Sichuan Basin have attracted great interest. To better understand these breakthroughs, we use core description, FIB-SEM data, XRD data, organic geochemistry, and well logging data, to better understand the reservoir characteristics carbonaceous shale, calcareous shale, and siliceous shale lithology, with a focus on the organic-rich shale units. We find conventional well log methods are effective in mapping the spatial distribution of the organic-rich shale in the Weiyuan area where the. total organic carbon content in the Longmaxi Formation ranges from 1.35%-6.95%, averaging 4.42%. The kerogen is Type I-II and the vitrinite reflectance (Ro) is greater than 2.57%, which indicates that the formation is susceptible to shale gas accumulation. The clay mineral content ranges from 48 wt.% to 63 wt.% (avg. 51 wt.%).with illite and chlorite averaging 73.8% and 25.7%, respectively. The brittle mineral quartz and plagioclase content ranges from 32 wt.% to 61 wt.% (avg. 47 wt.%). Compared to the surrounding litholgic units, the marine shale exhibits relatively high GR, CNL, AC, RT, K, and U values and relatively low DEN, PE and Th/U values, allowing us to construct. Cross-plots to define the units of interest. Using the same process, we quantify the TOC content providing a spatial distribution of organic-rich shale using conventional well logging.

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A Comparative Study of the Micropore Structure between the Transitional and Marine Shales in China

Geofluids ◽

10.1155/2021/5562532 ◽

2021 ◽

Vol 2021 ◽

pp. 1-14

Author(s):

Pengfei Jiao ◽

Genshun Yao ◽

Shangwen Zhou ◽

Zhe Yu ◽

Shiluo Wang

Keyword(s):

Natural Gas ◽

Shale Gas ◽

Ordos Basin ◽

Organic Carbon Content ◽

Type I ◽

Gas Generation ◽

Longmaxi Formation ◽

Micropore Structure ◽

Marine Shale ◽

Longmaxi Shale

To compare the micropore structure of marine-continental transitional shale with marine shale, organic geochemical, field emission scanning electron microscopy, and low-temperature nitrogen adsorption experiments were conducted on shale samples from the Shanxi Formation in the eastern Ordos Basin and the Longmaxi Formation in the southern Sichuan Basin. The results show that Shanxi Formation shale has a smaller specific surface area and pore volume than Longmaxi Formation shale; therefore, the transitional shales fail to provide sufficient pore spaces for the effective storage and preservation of natural gas. Both the transitional and marine shales are in an overmature stage with high total organic carbon content, but they differ considerably in pore types and development degrees. Inorganic pores and fractures are dominantly developed in transitional shales, such as intragranular pores and clay mineral interlayer fractures, while organic nanopores are rarely developed. In contrast, organic pores are the dominant pore type in the marine shales and inorganic pores are rarely observed. The fractal analysis also shows that pore structure complexity and heterogeneity are quite different. These differences were related to different organic types, i.e., type I of marine shale and type III of transitional shale. Marine Longmaxi shale has experienced liquid hydrocarbon cracking, gas generation, and pore-forming processes, providing good conditions for natural gas to be preserved. However, during the evolution of transitional Shanxi shale, gas cannot be effectively preserved due to the lack of the above evolution processes, leading to the poor gas-bearing property. The detailed comparison of the micropore structure between the transitional and marine shales is of great importance for the future exploitation of marine-continental transitional shale gas in China.

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