Electrospinning, which is a technology to make nano fiber, has quite high requirements of the speed of feeding. In order to solve the unstable phenomenon, salivation, and achieve the stability of quality, numerical simulation is used to compute the nozzle exit pressure and exit velocity, while recursive least squares is used to identify of the results of the simulation. At last, PID algorithm and recursive least squares methods are combined together to form a model for the feeding system controller. And the pneumatic device and pressure sensor are used to build electrospinning feeding system. Finally, experimental verification PEO solution is used to verify this method, no drooling electrospinning phenomenon happens