The Authentication of Basmati Rice Using near Infrared Spectroscopy

1993 ◽  
Vol 1 (2) ◽  
pp. 77-83 ◽  
Author(s):  
B.G. Osborne ◽  
B. Mertens ◽  
M. Thompson ◽  
T. Fearn
Keyword(s):  
Near Infrared ◽  
Principal Component ◽  
Basmati Rice ◽  
Infrared Transmission ◽  
Fisher Linear Discriminant ◽  
Linear Discriminant ◽  
Rice Samples ◽  
Individual Grains ◽  
Component Scores

The feasibility of using near infrared transmission spectroscopy to discriminate between Basmati and other long-grain rice samples was investigated. A discriminant rule was derived using the Fisher linear discriminant function calculated from the first few principal component scores of the NIR spectra. The discriminant rule was assessed by cross-validation. Nine Basmati and 53 other rice samples were classified correctly from NIR spectra measured on 200 g bulk samples but 8% of the Basmatis and 14% of the others were misclassified on the basis of spectra of individual grains. Using average spectra from 23 grains resulted in correct classification of 16 Basmatis but a 20% error rate on 100 other samples.

The Authentication of Basmati Rice Using near Infrared Spectroscopy: Some Further Analysis

1995 ◽  
Vol 3 (3) ◽  
pp. 111-117 ◽  
Author(s):  
W.J. Krzanowski
Keyword(s):  
Near Infrared ◽  
Principal Component ◽  
Basmati Rice ◽  
Multivariate Techniques ◽  
Infrared Transmission ◽  
Linear Discriminant ◽  
Canonical Variates ◽  
Rice Samples ◽  
Single Category ◽  
Pooled Samples

The feasibility of using near infrared transmission spectroscopy to discriminate between Basmati and other long-grain rice samples has been demonstrated previously by Osborne et al. In their analysis they pooled samples from different countries of origin into the single category “other” and used the multivariate techniques of principal component analysis and linear discriminant functions to arrive at their conclusions. We reanalyse here their data but without such a major pooling of samples, retaining four groups in the discrimination. Using the multivariate techniques of partial least squares, orthogonal canonical variates and a recently proposed search for “extremeness”, we demonstrate complete support for the previous conclusions.

scholarly journals A Rapid and Nondestructive Approach for the Classification of Different-Age Citri Reticulatae Pericarpium Using Portable Near Infrared Spectroscopy

Sensors ◽  
2020 ◽  
Vol 20 (6) ◽  
pp. 1586
Author(s):  
Pao Li ◽  
Xinxin Zhang ◽  
Shangke Li ◽  
Guorong Du ◽  
Liwen Jiang ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Near Infrared Spectroscopy ◽  
Near Infrared ◽  
Principal Component ◽  
Nondestructive Method ◽  
Linear Discriminant ◽  
Outer Skin ◽  
Data Pretreatment ◽  
Pca Method

Citri Reticulatae Pericarpium (CRP), has been used in China for hundreds of years as a functional food and medicine. However, some short-age CRPs are disguised as long-age CRPs by unscrupulous businessmen in order to obtain higher profits. In this paper, a rapid and nondestructive method for the classification of different-age CRPs was established using portable near infrared spectroscopy (NIRS) in diffuse reflectance mode combination with appropriate chemometric methods. The spectra of outer skin and inner capsule of CRPs at different storage ages were obtained directly without destroying the samples. Principal component analysis (PCA) with single and combined spectral pretreatment methods was used for the classification of different-age CRPs. Furthermore, the data were pretreated with the PCA method, and Fisher linear discriminant analysis (FLD) with optimized pretreatment methods was discussed for improving the accuracy of classification. Data pretreatment methods can be used to eliminate the noise and background interference. The classification accuracy of inner capsule is better than that of outer skin data. Furthermore, the best results with 100% prediction accuracy can be obtained with FLD method, even without pretreatment.

Classification of Apple Using near Infrared Spectroscopy Based on Fuzzy Discriminant Analysis

2013 ◽  
Vol 710 ◽  
pp. 524-528 ◽  
Author(s):  
Xiao Hong Wu ◽  
Xing Xing Wan ◽  
Bin Wu ◽  
Fan Wu
Keyword(s):  
Infrared Spectroscopy ◽  
Discriminant Analysis ◽  
Near Infrared Spectroscopy ◽  
Near Infrared ◽  
Principal Component ◽  
K Nearest Neighbor ◽  
Near Infrared Reflectance ◽  
Linear Discriminant ◽  
Discriminant Information

Classification of apple is an important link in postharvest commercialization processing. To realize the non-destructive, rapid and effective discrimination of apple fruits, the near infrared reflectance spectra of four varieties of apples were collected using near infrared spectroscopy, reduced by principal component analysis (PCA) and used to extract the discriminant information by linear discriminant analysis (LDA), quadratic discriminant analysis (QDA), fuzzy discriminant analysis (FDA) and Foley-Sammon discriminant analysis. Finally k-nearest neighbor finished the classification. The classification results showed that FDA could extract the discriminant information of NIR spectra more effectively, and achieved the highest classification accuracy.

Classification of jaboticaba fruits at three maturity stages using NIRS and LDA

2016 ◽  
Vol 8 (11) ◽  
pp. 2533-2538 ◽  
Author(s):  
Rosangela Câmara Costa ◽  
Luis C. Cunha Junior ◽  
Thayara Bittencourt Morgenstern ◽  
Gustavo Henrique de Almeida Teixeira ◽  
Kássio Michell Gomes de Lima
Keyword(s):  
Near Infrared ◽  
Principal Component ◽  
Reflectance Spectroscopy ◽  
Infrared Reflectance ◽  
Near Infrared Reflectance Spectroscopy ◽  
Near Infrared Reflectance ◽  
Linear Discriminant ◽  
Maturity Stages ◽  
Non Destructive

This study proposes a rapid and non-destructive method of jaboticaba [Myrciaria cauliflora (Mart.) O. Berg] fruit classification at three maturity stages using Near-Infrared Reflectance Spectroscopy (NIRS) combined with principal component analysis-linear discriminant analysis (PCA-LDA).

scholarly journals A fast and low-cost approach to quality control of alcohol-based hand sanitizer using portable near infrared spectrometer and chemometrics

2021 ◽  
pp. 096703352098731
Author(s):  
Adenilton C da Silva ◽  
Lívia PD Ribeiro ◽  
Ruth MB Vidal ◽  
Wladiana O Matos ◽  
Gisele S Lopes
Keyword(s):  
Quality Control ◽  
Discriminant Analysis ◽  
Near Infrared ◽  
Nir Spectroscopy ◽  
Principal Component ◽  
Partial Least Square ◽  
Least Square ◽  
Chemical Components ◽  
Linear Discriminant ◽  
Hand Sanitizer

The use of alcohol-based hand sanitizers is recommended as one of several strategies to minimize contamination and spread of the COVID-19 disease. Current reports suggest that the virucidal potential of ethanol occurs at concentrations close to 70%. Traditional methods of verifying the ethanol concentration in such products invite potential errors due to the viscosity of chemical components or may be prohibitively expensive to undertake in large demand. Near infrared (NIR) spectroscopy and chemometrics have already been used for the determination of ethanol in other matrices and present an alternative fast and reliable approach to quality control of alcohol-based hand sanitizers. In this study, a portable NIR spectrometer combined with classification chemometric tools, i.e., partial least square discriminant analysis (PLS–DA) and linear discriminant analysis with successive algorithm projection (SPA–LDA) were used to construct models to identify conforming and non-conforming commercial and laboratory synthesized hand sanitizer samples. Principal component analysis (PCA) was applied in an exploratory data study. Three principal components accounted for 99% of data variance and demonstrate clustering of conforming and non-conforming samples. The PLS–DA and SPA–LDA classification models presented 77 and 100% of accuracy in cross/internal validation respectively and 100% of accuracy in the classification of test samples. A total of 43% commercial samples evaluated using the PLS–DA and SPA–LDA presented ethanol content non-conforming for hand sanitizer gel. These results indicate that use of NIR spectroscopy and chemometrics is a promising strategy, yielding a method that is fast, portable, and reliable for discrimination of alcohol-based hand sanitizers with respect to conforming and non-conforming ethanol concentrations.

scholarly journals Determination of HPLC-UV Fingerprints of Spanish Paprika (Capsicum annuum L.) for Its Classification by Linear Discriminant Analysis

Sensors ◽  
2018 ◽  
Vol 18 (12) ◽  
pp. 4479 ◽  
Author(s):  
Xavier Cetó ◽  
Núria Serrano ◽  
Miriam Aragó ◽  
Alejandro Gámez ◽  
Miquel Esteban ◽  
...  
Keyword(s):  
Discriminant Analysis ◽  
Linear Discriminant Analysis ◽  
Principal Component ◽  
Reversed Phase ◽  
Classification Rate ◽  
Phenolic Profile ◽  
Linear Discriminant ◽  
Sample Extraction

The development of a simple HPLC-UV method towards the evaluation of Spanish paprika’s phenolic profile and their discrimination based on the former is reported herein. The approach is based on C18 reversed-phase chromatography to generate characteristic fingerprints, in combination with linear discriminant analysis (LDA) to achieve their classification. To this aim, chromatographic conditions were optimized so as to achieve the separation of major phenolic compounds already identified in paprika. Paprika samples were subjected to a sample extraction stage by sonication and centrifugation; extracting procedure and conditions were optimized to maximize the generation of enough discriminant fingerprints. Finally, chromatograms were baseline corrected, compressed employing fast Fourier transform (FFT), and then analyzed by means of principal component analysis (PCA) and LDA to carry out the classification of paprika samples. Under the developed procedure, a total of 96 paprika samples were analyzed, achieving a classification rate of 100% for the test subset (n = 25).

2D Image Matrix-Based Discriminator

2006 ◽  
pp. 258-286
Author(s):  
David Zhang ◽  
Xiao-Yuan Jing ◽  
Jian Yang
Keyword(s):  
Principal Component Analysis ◽  
Discriminant Analysis ◽  
Linear Discriminant Analysis ◽  
Principal Component ◽  
Component Analysis ◽  
Two Dimensional ◽  
Fisher Linear Discriminant ◽  
Linear Discriminant ◽  
Image Projection ◽  
Projection Techniques

This chapter presents two straightforward image projection techniques — two-dimensional (2D) image matrix-based principal component analysis (IMPCA, 2DPCA) and 2D image matrix-based Fisher linear discriminant analysis (IMLDA, 2DLDA). After a brief introduction, we first introduce IMPCA. Then IMLDA technology is given. As a result, we summarize some useful conclusions.

scholarly journals Characterization and classification of Romanian acacia honey based on its physicochemical parameters and chemometrics

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Mihaela Emanuela Crăciun ◽  
Oana Cristina Pârvulescu ◽  
Andreea Cristina Donise ◽  
Tănase Dobre ◽  
Dumitru Radu Stanciu
Keyword(s):  
Physicochemical Parameters ◽  
Stable Carbon Isotopes ◽  
Reducing Sugars ◽  
Activity Ratio ◽  
Sugar Content ◽  
Principal Component ◽  
Reducing Sugar ◽  
Linear Discriminant ◽  
Acacia Honey

AbstractThree groups of Romanian acacia honey, i.e., pure, directly adulterated (by mixing the pure honey with three sugar syrups), and indirectly adulterated (by feeding the bees with the same syrups), were characterized and discriminated based on their physicochemical parameters. Moisture, ash, 5-hydroxymethylfurfural (HMF), reducing sugars (fructose and glucose), and sucrose contents, free acidity, diastase activity, ratio between stable carbon isotopes of honey and its proteins (δ13CH and δ13CP) were evaluated. Adulteration led to a significant increase in sucrose content, HMF level, and Δδ13C = δ13CH‒δ13CP as well a decrease in reducing sugar content and diastase activity. Principal component analysis (PCA) and linear discriminant analysis (LDA) were applied to experimental data in order to distinguish between pure and adulterated honey. The most relevant discriminative parameters were diastase activity, HMF, sucrose, and reducing sugar contents. Posterior classification probabilities and classification functions obtained by LDA revealed that 100% of honey samples were correctly assigned to their original group.

scholarly journals Tracing the Geographical Origin of Durum Wheat by FT-NIR Spectroscopy

Foods ◽  
2019 ◽  
Vol 8 (10) ◽  
pp. 450 ◽  
Author(s):  
Annalisa De Girolamo ◽  
Marina Cortese ◽  
Salvatore Cervellieri ◽  
Vincenzo Lippolis ◽  
Michelangelo Pascale ◽  
...  
Keyword(s):  
Durum Wheat ◽  
Near Infrared ◽  
Southern Italy ◽  
Geographical Origin ◽  
Nir Spectroscopy ◽  
Principal Component ◽  
Classification Model ◽  
North Central ◽  
Linear Discriminant ◽  
The World

Fourier transform near infrared (FT-NIR) spectroscopy, in combination with principal component-linear discriminant analysis (PC-LDA), was used for tracing the geographical origin of durum wheat samples. The classification model PC-LDA was applied to discriminate durum wheat samples originating from Northern, Central, and Southern Italy (n = 181), and to differentiate Italian durum wheat samples from those cultivated in other countries across the world (n = 134). Developed models were validated on a separated set of wheat samples. Different pre-treatments of spectral data and different spectral regions were selected and compared in terms of overall discrimination (OD) rates obtained in validation. The LDA models were able to correctly discriminate durum Italian wheat samples according to their geographical origin (i.e., North, Central, and South) with OD rates of up of 96.7%. Better results were obtained when LDA models were applied to the discrimination of Italian durum wheat samples from those originating from other countries across the world, having OD rates of up to 100%. The excellent results obtained herein clearly indicate the potential of FT-NIR spectroscopy to be used for the discrimination of durum wheat samples according to their geographical origin.

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