The Authentication of Basmati Rice Using near Infrared Spectroscopy: Some Further Analysis

1995 ◽  
Vol 3 (3) ◽  
pp. 111-117 ◽  
Author(s):  
W.J. Krzanowski
Keyword(s):  
Near Infrared ◽  
Principal Component ◽  
Basmati Rice ◽  
Multivariate Techniques ◽  
Infrared Transmission ◽  
Linear Discriminant ◽  
Canonical Variates ◽  
Rice Samples ◽  
Single Category ◽  
Pooled Samples

The feasibility of using near infrared transmission spectroscopy to discriminate between Basmati and other long-grain rice samples has been demonstrated previously by Osborne et al. In their analysis they pooled samples from different countries of origin into the single category “other” and used the multivariate techniques of principal component analysis and linear discriminant functions to arrive at their conclusions. We reanalyse here their data but without such a major pooling of samples, retaining four groups in the discrimination. Using the multivariate techniques of partial least squares, orthogonal canonical variates and a recently proposed search for “extremeness”, we demonstrate complete support for the previous conclusions.

The Authentication of Basmati Rice Using near Infrared Spectroscopy

1993 ◽  
Vol 1 (2) ◽  
pp. 77-83 ◽  
Author(s):  
B.G. Osborne ◽  
B. Mertens ◽  
M. Thompson ◽  
T. Fearn
Keyword(s):  
Near Infrared ◽  
Principal Component ◽  
Basmati Rice ◽  
Infrared Transmission ◽  
Fisher Linear Discriminant ◽  
Linear Discriminant ◽  
Rice Samples ◽  
Individual Grains ◽  
Component Scores

The feasibility of using near infrared transmission spectroscopy to discriminate between Basmati and other long-grain rice samples was investigated. A discriminant rule was derived using the Fisher linear discriminant function calculated from the first few principal component scores of the NIR spectra. The discriminant rule was assessed by cross-validation. Nine Basmati and 53 other rice samples were classified correctly from NIR spectra measured on 200 g bulk samples but 8% of the Basmatis and 14% of the others were misclassified on the basis of spectra of individual grains. Using average spectra from 23 grains resulted in correct classification of 16 Basmatis but a 20% error rate on 100 other samples.

scholarly journals A fast and low-cost approach to quality control of alcohol-based hand sanitizer using portable near infrared spectrometer and chemometrics

2021 ◽  
pp. 096703352098731
Author(s):  
Adenilton C da Silva ◽  
Lívia PD Ribeiro ◽  
Ruth MB Vidal ◽  
Wladiana O Matos ◽  
Gisele S Lopes
Keyword(s):  
Quality Control ◽  
Discriminant Analysis ◽  
Near Infrared ◽  
Nir Spectroscopy ◽  
Principal Component ◽  
Partial Least Square ◽  
Least Square ◽  
Chemical Components ◽  
Linear Discriminant ◽  
Hand Sanitizer

The use of alcohol-based hand sanitizers is recommended as one of several strategies to minimize contamination and spread of the COVID-19 disease. Current reports suggest that the virucidal potential of ethanol occurs at concentrations close to 70%. Traditional methods of verifying the ethanol concentration in such products invite potential errors due to the viscosity of chemical components or may be prohibitively expensive to undertake in large demand. Near infrared (NIR) spectroscopy and chemometrics have already been used for the determination of ethanol in other matrices and present an alternative fast and reliable approach to quality control of alcohol-based hand sanitizers. In this study, a portable NIR spectrometer combined with classification chemometric tools, i.e., partial least square discriminant analysis (PLS–DA) and linear discriminant analysis with successive algorithm projection (SPA–LDA) were used to construct models to identify conforming and non-conforming commercial and laboratory synthesized hand sanitizer samples. Principal component analysis (PCA) was applied in an exploratory data study. Three principal components accounted for 99% of data variance and demonstrate clustering of conforming and non-conforming samples. The PLS–DA and SPA–LDA classification models presented 77 and 100% of accuracy in cross/internal validation respectively and 100% of accuracy in the classification of test samples. A total of 43% commercial samples evaluated using the PLS–DA and SPA–LDA presented ethanol content non-conforming for hand sanitizer gel. These results indicate that use of NIR spectroscopy and chemometrics is a promising strategy, yielding a method that is fast, portable, and reliable for discrimination of alcohol-based hand sanitizers with respect to conforming and non-conforming ethanol concentrations.

scholarly journals Tracing the Geographical Origin of Durum Wheat by FT-NIR Spectroscopy

Foods ◽  
2019 ◽  
Vol 8 (10) ◽  
pp. 450 ◽  
Author(s):  
Annalisa De Girolamo ◽  
Marina Cortese ◽  
Salvatore Cervellieri ◽  
Vincenzo Lippolis ◽  
Michelangelo Pascale ◽  
...  
Keyword(s):  
Durum Wheat ◽  
Near Infrared ◽  
Southern Italy ◽  
Geographical Origin ◽  
Nir Spectroscopy ◽  
Principal Component ◽  
Classification Model ◽  
North Central ◽  
Linear Discriminant ◽  
The World

Fourier transform near infrared (FT-NIR) spectroscopy, in combination with principal component-linear discriminant analysis (PC-LDA), was used for tracing the geographical origin of durum wheat samples. The classification model PC-LDA was applied to discriminate durum wheat samples originating from Northern, Central, and Southern Italy (n = 181), and to differentiate Italian durum wheat samples from those cultivated in other countries across the world (n = 134). Developed models were validated on a separated set of wheat samples. Different pre-treatments of spectral data and different spectral regions were selected and compared in terms of overall discrimination (OD) rates obtained in validation. The LDA models were able to correctly discriminate durum Italian wheat samples according to their geographical origin (i.e., North, Central, and South) with OD rates of up of 96.7%. Better results were obtained when LDA models were applied to the discrimination of Italian durum wheat samples from those originating from other countries across the world, having OD rates of up to 100%. The excellent results obtained herein clearly indicate the potential of FT-NIR spectroscopy to be used for the discrimination of durum wheat samples according to their geographical origin.

scholarly journals Evaluation of Visible-Near Infrared Reflectance Spectra of Avocado Leaves as a Non-destructive Sensing Tool for Detection of Laurel Wilt

Plant Disease ◽  
2012 ◽  
Vol 96 (11) ◽  
pp. 1683-1689 ◽  
Author(s):  
Sindhuja Sankaran ◽  
Reza Ehsani ◽  
Sharon A. Inch ◽  
Randy C. Ploetz
Keyword(s):  
Discriminant Analysis ◽  
Vegetation Index ◽  
Near Infrared ◽  
Principal Component ◽  
Persea Americana ◽  
Near Infrared Reflectance ◽  
Laurel Wilt ◽  
Linear Discriminant ◽  
Raffaelea Lauricola ◽  
Non Destructive

Laurel wilt, caused by the fungus Raffaelea lauricola, affects the growth, development, and productivity of avocado, Persea americana. This study evaluated the potential of visible-near infrared spectroscopy for non-destructive sensing of this disease. The symptoms of laurel wilt are visually similar to those caused by freeze damage (leaf necrosis). In this work, we performed classification studies with visible-near infrared spectra of asymptomatic and symptomatic leaves from infected plants, as well as leaves from freeze-damaged and healthy plants, both of which were non-infected. The principal component scores computed from principal component analysis were used as input features in four classifiers: linear discriminant analysis, quadratic discriminant analysis (QDA), Naïve-Bayes classifier, and bagged decision trees (BDT). Among the classifiers, QDA and BDT resulted in classification accuracies of higher than 94% when classifying asymptomatic leaves from infected plants. All of the classifiers were able to discriminate symptomatic-infected leaves from freeze-damaged leaves. However, the false negatives mainly resulted from asymptomatic-infected leaves being classified as healthy. Analyses of average vegetation indices of freeze-damaged, healthy (non-infected), asymptomatic-infected, and symptomatic-infected leaves indicated that the normalized difference vegetation index and the simple ratio index were statistically different.

Application of Visible-Near Infrared Spectra Technique Based on to the Non-Destructive Measurement of the Salmon Quality

2014 ◽  
Vol 926-930 ◽  
pp. 961-964
Author(s):  
Jiao Jiao Yin
Keyword(s):  
Infrared Spectra ◽  
Near Infrared ◽  
Principal Component ◽  
Support Vector ◽  
Analysis Method ◽  
Linear Discriminant ◽  
Near Infrared Spectra ◽  
Destructive Measurement ◽  
Non Destructive

Because the reflectivity of astaxanthin vary in different bands (mainly 400nm-600nm), so we use the visible-near infrared spectra technique to irradiate the salmon. Because in daily life, people grade the salmon flesh with a color card. In this paper, we first use principal component analysis to reduce the dimensionality of the spectral data of salmon, then use linear discriminant analysis method, least squares support vector machine classification method to distinguish the flesh quality. The correct classification rates are 60%and73.3%. The results show that we can use visible – near infrared spectra to distinguish the quality of the salmon which doesn’t be dissected.

scholarly journals Rapid Authentication of 100% Italian Durum Wheat Pasta by FT-NIR Spectroscopy Combined with Chemometric Tools

Foods ◽  
2020 ◽  
Vol 9 (11) ◽  
pp. 1551
Author(s):  
Annalisa De Girolamo ◽  
Salvatore Cervellieri ◽  
Erminia Mancini ◽  
Michelangelo Pascale ◽  
Antonio Francesco Logrieco ◽  
...  
Keyword(s):  
Durum Wheat ◽  
Near Infrared ◽  
Nir Spectroscopy ◽  
Principal Component ◽  
Linear Discriminant ◽  
Production And Consumption ◽  
High Prediction ◽  
Validation Set ◽  
Performance Results ◽  
Prediction Capability

Italy is the country with the largest durum wheat pasta production and consumption. The mandatory labelling for pasta indicating the country of origin of wheat has made consumers more aware about the consumed pasta products and is influencing their choice towards 100% Italian wheat pasta. This aspect highlights the need to promote the use of domestic wheat as well as to develop rapid methodologies for the authentication of pasta. A rapid, inexpensive, and easy-to-use method based on infrared spectroscopy was developed and validated for authenticating pasta made with 100% Italian durum wheat. The study was conducted on pasta marketed in Italy and made with durum wheat cultivated in Italy (n = 176 samples) and on pasta made with mixtures of wheat cultivated in Italy and/or abroad (n = 185 samples). Pasta samples were analyzed by Fourier transform-near infrared (FT-NIR) spectroscopy coupled with supervised classification models. The good performance results of the validation set (sensitivity of 95%, specificity and accuracy of 94%) obtained using principal component-linear discriminant analysis (PC-LDA) clearly demonstrated the high prediction capability of this method and its suitability for authenticating 100% Italian durum wheat pasta. This output is of great interest for both producers of Italian pasta pointing toward authentication purposes of their products and consumer associations aimed to preserve and promote the typicity of Italian products.

scholarly journals Identification of Copper in Stems and Roots of Jatropha curcas L. by Hyperspectral Imaging

Processes ◽  
2020 ◽  
Vol 8 (7) ◽  
pp. 823
Author(s):  
Juan Francisco García-Martín ◽  
Amanda Teixeira Badaró ◽  
Douglas Fernandes Barbin ◽  
Paloma Álvarez-Mateos
Keyword(s):  
Jatropha Curcas ◽  
Near Infrared ◽  
Prediction Models ◽  
Plant Stress ◽  
Principal Component ◽  
Linear Discriminant ◽  
Jatropha Curcas L ◽  
Potential Applications

The in situ determination of metals in plants used for phytoremediation is still a challenge that must be overcome to control the plant stress over time due to metals uptake as well as to quantify the concentration of these metals in the biomass for further potential applications. In this exploratory study, we acquired hyperspectral images in the visible/near infrared regions of dried and ground stems and roots of Jatropha curcas L. to which different amounts of copper (Cu) were added. The spectral information was extracted from the images to build classification models based on the concentration of Cu. Optimum wavelengths were selected from the peaks and valleys showed in the loadings plots resulting from principal component analysis, thus reducing the number of spectral variables. Linear discriminant analysis was subsequently performed using these optimum wavelengths. It was possible to differentiate samples without addition of copper from samples with low (0.5–1% wt.) and high (5% wt.) amounts of copper (83.93% accuracy, >0.70 sensitivity and specificity). This technique could be used after enhancing prediction models with a higher amount of samples and after determining the potential interference of other compounds present in plants.

scholarly journals Application of Near-Infrared Spectroscopy to Investigate Some Endogenic Properties of Pleurotus ostreatus Cultivars

Sensors ◽  
2020 ◽  
Vol 20 (22) ◽  
pp. 6632
Author(s):  
Marietta Fodor ◽  
Erika Etelka Mikola ◽  
András Geösel ◽  
Éva Stefanovits-Bányai ◽  
Zsuzsanna Mednyánszky
Keyword(s):  
Amino Acid ◽  
Free Amino Acid ◽  
Pleurotus Ostreatus ◽  
Free Amino ◽  
Near Infrared ◽  
Amino Acid Content ◽  
Principal Component ◽  
Automatic Amino Acid Analyzer ◽  
Linear Discriminant ◽  
Reducing Ability

Fourteen different Pleurotus ostreatus cultivars (Po_1–Po_14) were tested for free amino acid content (fAA), total polyphenol content (TPC), and antioxidant capacity (Ferric Reducing Ability of Plasma—FRAP) to select the cultivars with the most favorable traits. Automatic amino acid analyzer (fAA) and spectrophotometric assay (TPC, FRAP) results as well as Fourier-transform near infrared (FT-NIR) spectra were evaluated with different chemometric methods (Kruskal–Wallis test, Principal Component Analysis—PCA, Linear Discriminant Analysis—LDA). Based on total free amino acid concentrations and FRAP values, the Po_2 cultivar was found to be the most favorable. Types Po_3, Po_8, Po_10 and Po_12 were separated using PCA. Based on the spectral profile, they may contain polyphenols and reducing compounds of different qualities. LDA classification that was based on the concentrations of all free amino acids, cysteine, and proline of the cultivars was performed with an accuracy of over 90%. LDA classification that was based on the TPC and FRAP values was performed with an accuracy of over 83%.

scholarly journals Feasibility Study of the Use of Handheld NIR Spectrometer for Simultaneous Authentication and Quantification of Quality Parameters in Intact Pineapple Fruits

2019 ◽  
Vol 2019 ◽  
pp. 1-9 ◽  
Author(s):  
Charles L. Y. Amuah ◽  
Ernest Teye ◽  
Francis Padi Lamptey ◽  
Kwasi Nyandey ◽  
Jerry Opoku-Ansah ◽  
...  
Keyword(s):  
Near Infrared ◽  
Nearest Neighbor ◽  
Multivariate Calibration ◽  
Principal Component ◽  
Quality Parameters ◽  
Soluble Solids ◽  
Least Squares Regression ◽  
Total Soluble Solids ◽  
Linear Discriminant ◽  
Identification Rate

The potential of predicting maturity using total soluble solids (TSS) and identifying organic from inorganic pineapple fruits based on near-infrared (NIR) spectra fingerprints would be beneficial to farmers and consumers alike. In this study, a portable NIR spectrometer and chemometric techniques were combined to simultaneously identify organically produced pineapple fruits from conventionally produced ones (thus organic and inorganic) and also predict total soluble solids. A total of 90 intact pineapple fruits were scanned with the NIR spectrometer while a digital refractometer was used to measure TSS from extracted pineapple juice. After attempting several preprocessing techniques, multivariate calibration models were built using principal component analysis (PCA), K-nearest neighbor (KNN), and linear discriminant analysis (LDA) to identify the classes (organic and conventional pineapple fruits) while partial least squares regression (PLSR) method was used to determine TSS of the fruits. Among the identification techniques, the MSC-PCA-LDA model accurately identified organic from conventionally produced fruits at 100% identification rate. For quantification of TSS, the MSC-PLSR model gave Rp = 0.851 and RMSEC = 0.950 °Brix, and Rc = 0.854 and RMSEP = 0.842 °Brix at 5 principal components in the calibration set and prediction set, respectively. The results generally indicated that portable NIR spectrometer coupled with the appropriate chemometric tools could be employed for rapid nondestructive examination of pineapple quality and also to detect pineapple fraud due to mislabeling of conventionally produced fruits as organic ones. This would be helpful to farmers, consumers, and quality control officers.

Detection of Aflatoxin B1 in Pistachio Kernels Using Visible/Near-Infrared Hyperspectral Imaging

2019 ◽  
Vol 62 (5) ◽  
pp. 1065-1074
Author(s):  
Qifang Wu ◽  
Huirong Xu
Keyword(s):  
Hyperspectral Imaging ◽  
Near Infrared ◽  
Correlation Coefficients ◽  
Principal Component ◽  
Nutrient Content ◽  
Aflatoxin Contamination ◽  
Quantitative Prediction ◽  
Spectra Analysis ◽  
Linear Discriminant ◽  
Standard Normal Variate

Abstract. Pistachios are susceptible to aflatoxin contamination because of their rich nutrient content. Hyperspectral imaging (HSI), a new method for collecting spectral and image information, has been successfully employed in contamination research to classify staple agricultural products, such as maize, that are contaminated with aflatoxins. However, only a few studies have been conducted on the nondestructive discrimination among contaminated nuts using HSI for both qualitative and quantitative purposes. Thus, the feasibility of directly detecting aflatoxin B1 (AFB1) in individual pistachio kernels using visible/near-infrared HSI (VNIR HSI) was explored in this study. A total of 300 pistachio kernels were randomly selected to prepare target samples that were artificially contaminated with 5, 10, 20, 30, or 50 ppb (parts per billion) of AFB1. Principal component analysis (PCA) showed an overall separation trend between the control and all contaminated kernels. Accuracies greater than 90.0% were obtained by linear discriminant analysis (LDA) for samples that were artificially contaminated with different concentrations of AFB1 based on spectra at 694 to 988 nm that had been preprocessed with standard normal variate (SNV) and Savitzky-Golay (SG) smoothing. The correlation coefficients of calibration and validation (rc and rv) from stepwise multiple linear regression (SMLR) models were all >0.9100. Moreover, five key wavelengths (708, 771, 892, 915, and 941 nm) closely associated with AFB1 contamination were identified using principal component spectra analysis. Generally, the results indicated that VNIR HSI could be employed for preliminary screening of pistachio kernels that were artificially contaminated with AFB1, even at the 5 ppb level. However, the quantitative prediction of the specific AFB1 concentration needed to be further improved. Keywords: Aflatoxins, Detection analysis, Hyperspectral information, Pistachios, Visible/near-infrared.

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