scholarly journals Physico-chemical characterization of olive-oil mill wastewaters of Ben Karrich area (Tetouan province, North of Morocco) and optimization study of their treatment using activated carbon

2018 ◽  
Vol 7 (4) ◽  
pp. 253-258 ◽  
Author(s):  
Dorsaf Bouharat ◽  
Farida EL Yousfi ◽  
Anas Ellaghdach ◽  
Badr Dine Souhail ◽  
Nabila Slimani Alaoui

A physio-chemical characterization of olive oil mill wastewater (OMW) obtained from a continuous two-phases olive oil extraction process is presented. High organic load of OMW from Ben Karrich region has been registered. The values of chemical oxygen demand (COD) and total phenolic compounds were 84.5 g of O2/L and 3.79 g/L, respectively. In this sense, a treatment using activated carbon as adsorbent was proposed. Results have shown high removal percentages in total phenolic compounds (98%) and COD (90%). The optimal operating conditions were 4 g of activated carbon and adsorbing time equal to 5 minutes.

Author(s):  
Camila Peitz ◽  
Claudia Regina Xavier

The pulp industry generates high effluent flows, which contain high chemical oxygen demand (COD), biochemical oxygen demand (BOD5), colour and ecotoxicity. This study aimed to evaluate the treatment of Kraft pulp effluent by aerated lagoon modified with sponge support media (APG). It was assessed the arrangement of the support media in the aerated lagoons in the organic load rate (OLR) of 0.2 kgCOD m-3 d-1, and after that, with OLR variation from 0.2 to 1.2 kgCOD m-3 d-1. The parameters evaluated were BOD5, COD, colour, lignin derivatives, total phenolic compounds and acute ecotoxicity in D. magna. COD and BOD5 removals were 32% and 88%, respectively, for free and confined support media in 0.2 kgCOD m-3 d-1. There was no colour or total phenolic compounds removal under these conditions. Considering the treatment in which there was a variation of the organic load rate, 1.2 kgCOD m-3 d-1 had the best performance. In this case, 50% and 75% of COD and BOD5 were removed, respectively. Removal of colour, total phenolic compounds and lignin derivatives were around 20%, 18% and 10%, respectively. The acute ecotoxicity was reduced to toxicity factor equal to 1 in all treatments. Comparing the aerated lagoon modified systems with those without the APG, it was suggested to apply spongy support in higher organic load rate than these typically used in aerated lagoons.


Ingeniería ◽  
2020 ◽  
Vol 26 (1) ◽  
pp. 77-92
Author(s):  
Ciliana Florez Montes ◽  
Andrés Felipe Rojas González ◽  
Sneyder Rodríguez Barona

Context: Currently, the increase in agroindustrial waste generation has encouraged the search for viable use alternatives. In this paper, four methods to obtain extracts from mango, soursop, and grape peels, as well as and grape seeds, are studied. Their efficiency is analyzed through extraction yields and antioxidant capacity characterization of the extracts. Method: The extraction was performed using solvent, Soxhlet, microwave-assisted, and ultrasound assisted extraction. The characterization of the extracts was made by total phenolic compounds and flavonoids quantification, as well as antioxidant capacity determination, using the DPPH, FRAP, and ORAC tests. Results: It was found that grape seed extracts obtained by different extraction methods, highlighting those obtained by microwave assisted extraction, present a high total content phenolic compounds (>321.381,41 ± 3.476,85 μg Gallic Acid/g) and flavonoids (>103.232,01 ± 4.638,19 μg Quercetin/g), in addition to high antioxidant activity, according to the results of the DPPH (<1,06 ± 0,01), FRAP (>152.280,08 ± 5.197,53 µg TROLOX/g), and ORAC (>124.566,81 ± 581,96 μg TROLOX/g) tests. Conclusions: The results presented in this study suggest that the extracts obtained from grape seeds, especially those obtained by means of microwave-assisted extraction, have a potential use in food and pharmaceutical industries, due to their high antioxidant capacity and their total phenolic compounds and flavonoids content.


Author(s):  
Everaldo Attard ◽  
Joseph Mizzi

Honey quality is clearly defined in the EU Directive 2001/110/EC, and by Codex Alimentarius (Codex Stan 12-1981) and the International Honey Commission (IHC, 2002). Our investigation aimed to characterize the physicochemical properties of honey produced on a small island, Gozo which is situated near Malta.  Ten randomly collected honey samples were analysed for moisture content, pH, free acidity, water insoluble content, hydroxymethylfurfural (HMF) content and total phenolic compounds.  Moisture content, pH, free acidity, water insoluble content, and HMF content were within the range specified in standards but the electrical conductivity was generally higher than 0.800 mS cm-1. This may be the result of the relatively high atmospheric and soil salinity on this small island. All the samples analysed were within the 40 mg kg-1 HMF limit, which is an indicator of honey quality. The total phenolic compounds, which represent some of the constituents derived from the nectar and pollen obtained during foraging, ranged between 236.555 and 294.209 GAE kg-1 honey. Principal Component Analysis showed the properties of polyfloral honey samples obtained from the southern part of the island to be different from those obtained from the northern part.


Catalysts ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 554
Author(s):  
Gassan Hodaifa ◽  
Cristina Agabo García ◽  
Rafael Borja

The high production of raw olive oil mill wastewater (OMW) is a current environmental problem due to its high organic load and phenol compounds. In this work, photo-Fenton reaction as an advanced oxidation process has been chosen for OMW treatment. In this sense, different iron salts (FeCl3, Fe2(SO4)3, FeSO4·7H2O, and Fe(ClO4)3) as catalysts were used in order to compare their effects on treatment. For each catalyst, different H2O2 concentrations (2.5, 5.0, 7.5, 10.0, 15.0, 20.0, and 30.0%, w/v) as oxidizing agents were tested. The common experimental conditions were temperature 20 °C, the catalyst/H2O2 ratio = 0.03, pH = 3, and ultraviolet light. The Lagergren kinetic model, in cases of total organic carbon removal, for the best H2O2 concentration per catalyst was used. During the experiments, the water quality was determined by measuring the removal percentages on chemical oxygen demand, total carbon, total organic carbon, total nitrogen, total phenolic compounds, total iron, turbidity and electric conductivity. The best catalyst was FeCl3 and the optimum H2O2 concentration was 7.5% (w/v). At these optimal conditions, the removal percentages for chemical oxygen demand, total phenolic compounds, total carbon, total organic carbon and total nitrogen were 60.3%, 88.4%, 70.1%, 63.2% and 51.5%, respectively.


Author(s):  
Camila Peitz ◽  
Claudia Regina Xavier

The pulp industry uses more than 40 m3 of water per ton of pulp produced, generating high effluent flows. In general, it presents high concentrations of organic matter, color and ecotoxicity. The most widely used effluent treatment systems in the pulp industry are biological, including moving bed biofilm systems that are efficient in removing biodegradable organic matter.  This work evaluated the removal of organic matter, total phenolic compounds, color and lignin derivatives in the treatment of Kraft cellulose effluent using the moving bed biofilm reactor (MBBR), and also evaluated the support media biofilm development by solid analysis and scanning electron microscopy. The parameters evaluated during treatment were: BOD5, COD, color, total phenolic compounds, lignin derivatives, and solids, with tests performed on organic loads from 0.7 and 8.9 kgCOD m-3 d-1. Organic matter removal remained stable, being over 80% to BOD5 and over 42% to COD. The color and the total phenolic compounds were removed up to approximately 7 and 28%, respectively. Over 19% removal of derivatives of lignin compounds was observed in both organic load rates. In the MBBR, biofilm was confirmed and enabled this biological system to treat the cellulose effluent in a stable way.


2013 ◽  
Vol 2 (2) ◽  
Author(s):  
Everaldo Attard ◽  
Joseph Mizzi

Honey quality is clearly defined in the EU Directive 2001/110/EC, and by Codex Alimentarius (Codex Stan 12-1981) and the International Honey Commission (IHC, 2002). Our investigation aimed to characterize the physicochemical properties of honey produced on a small island, Gozo which is situated near Malta.  Ten randomly collected honey samples were analysed for moisture content, pH, free acidity, water insoluble content, hydroxymethylfurfural (HMF) content and total phenolic compounds.  Moisture content, pH, free acidity, water insoluble content, and HMF content were within the range specified in standards but the electrical conductivity was generally higher than 0.800 mS cm-1. This may be the result of the relatively high atmospheric and soil salinity on this small island. All the samples analysed were within the 40 mg kg-1 HMF limit, which is an indicator of honey quality. The total phenolic compounds, which represent some of the constituents derived from the nectar and pollen obtained during foraging, ranged between 236.555 and 294.209 GAE kg-1 honey. Principal Component Analysis showed the properties of polyfloral honey samples obtained from the southern part of the island to be different from those obtained from the northern part.


Molecules ◽  
2019 ◽  
Vol 24 (11) ◽  
pp. 2041 ◽  
Author(s):  
Vasilisa Pedan ◽  
Martin Popp ◽  
Sascha Rohn ◽  
Matthias Nyfeler ◽  
Annette Bongartz

Olive oil is not only known for its pungent, bitter, and fruity taste, but also for its health potential, which is often hypothesized to depend on its phenolic compounds. One hundred extra virgin olive oil samples (monocultivaric as well as blends of varieties) were assessed with regard to their sensory properties and phenolic compound composition. Nineteen phenolic compounds have been determined and correlated with sensory data. In all olive oil samples, oleocanthal and oleacein were the most abundant phenolic compounds, with average amounts of 77.9 mg/kg and 41.8 mg/kg, respectively. The highest correlation coefficient between a sensory descriptor and the phenolic compounds was found for the bitter taste sensation and the total phenolic content with r = 0.72 and in particular, for 3,4-DHPEA-EA, with r = 0.57. Intensity plots were assessed for the three main sensory descriptors fruitiness, bitterness, pungency, and for the quality factor harmony, which is associated with the degree of ripeness aroma of olive oil. Positive correlations for the aroma descriptors freshly cut grass, leaves, and nuts, and the phenolic compounds were especially observed for oleoside 11-methylester and vanillic acid. The present study provides a comprehensive database of phenolic compounds in olive oils from six different varieties and seven countries.


2005 ◽  
Vol 51 (1) ◽  
pp. 53-60 ◽  
Author(s):  
A.G. Vlyssides ◽  
E.M. Barampouti ◽  
S. Mai

The present paper deals with the characterization of wastewater generated from Greek wineries and wine distilleries. The quantity and the quality of the wastewater of a distillery depends on the type of wine (white or red), on the processes followed for the production of wine as well as on the volume of the tanks that are used. The total production of wastewater from a winery is about 1.2 times greater than the production of wine with BOD5 1740 mg/l and 1970 mg/l for white and red wine respectively, while the corresponding prices for COD are 3112 mg/l and 3997 mg/l and for the total phenolic compounds 280 and 1440 mg/l respectively. From these results, it is expected that the biological treatment of wastewater from white wines will be more efficient than that from red wines. The characteristics from the waste (vinasses) from the distillation of wines and wine lees are also presented.


BioResources ◽  
2021 ◽  
Vol 16 (3) ◽  
pp. 5203-5219
Author(s):  
Jackeline Valendolf Nunes ◽  
Mac Wendell Barbosa da Silva ◽  
Gustavo Henrique Couto ◽  
Eduarda Roberta Bordin ◽  
Wanessa Algarte Ramdsdorf ◽  
...  

The microbiological diversity of cultivable bacteria was analyzed in an aerated facultative lagoon. The removal of specific compounds and measures of pollutant load was evaluated with isolated native bacteria, selected and identified in kraft cellulose effluent. The system was operated with an organic loading rate of 0.2 kgCODm-3d-1 for 60 days. Analyses of the fluorescence excitation-emission matrix, acute ecotoxicity, and microbiology were performed. Bioaugmentation tests were done to emphasize the removal of color, using promising species. The removals of biochemical oxygen demand, chemical oxygen demand, and total organic carbon in AFL were 94%, 51%, and 41%, respectively. Regarding color, removal was up to 4%, and the total phenolic compounds were not removed through biological treatment. The treatment also decreased turbidity by 94% and lignin derivatives by 12%. The bacteria identified through NCBI-BLAST and statistical similarity totaled 9 species in the cellulose effluent, three of which have the potential for color treatment: Bacillus cereus, Bacillus thuringiensis, and Paenibacillus sp. The Bacillus cereus combined with biomass removed color (69%), total phenolic compounds (37%), and compounds derived from lignin (53%). These species are promising for removing specific parameters combined with biomass from biological AFL treatment systems.


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