Identification of Oil Contaminants on Polymer Coated Beverage Cans Using Fluorescence Spectroscopy

2003 ◽  
Vol 57 (8) ◽  
pp. 1042-1048 ◽  
Author(s):  
Michael Malecha ◽  
Conrad Bessant ◽  
Selwayan Saini
Keyword(s):  
Fluorescence Spectroscopy ◽  
Fiber Optics ◽  
Fiber Optic ◽  
Indirect Measurements ◽  
Linear Discriminant ◽  
Alternative Approach ◽  
Novel Method ◽  
Components Analysis ◽  
Low Sensitivity ◽  
Detection And Recognition

In a recent publication we introduced a novel method for detection of impurities on beverage can surfaces using Raman spectroscopy. While investigating the technique, limitations emerged due to the low sensitivity of Raman scatter. This is a particular problem with the largest contributor of impurities in beverage cans: lubricants employed in the manufacturing process. This paper presents an alternative approach, using the more sensitive technique of fluorescence spectroscopy to tackle the same problem. Measurements using fluorescence spectroscopy were conducted indirectly in a cuvette as well as directly on a can surface with the aid of fiber optics. The chemometrics methods of linear discriminant analysis (LDA) and principal components analysis (PCA) were used to classify acquired spectra as belonging to one of the 16 investigated lubricants. Fiber-optic scans revealed that a successful detection and recognition of lubricant is possible down to a volume of 0.5 μL deposited on the can surface. Contaminant detection was possible at even lower levels down to 0.01 μL, but reliable identification proved difficult at such low volumes. Indirect measurements of lubricants dissolved in cyclohexane yielded the lowest detection limits between 1–0.1 ppb.

scholarly journals The Use of Right Angle Fluorescence Spectroscopy to Distinguish the Botanical Origin of Greek Common Honey Varieties

2021 ◽  
Vol 11 (9) ◽  
pp. 4047
Author(s):  
Marinos Xagoraris ◽  
Panagiota-Kyriaki Revelou ◽  
Eleftherios Alissandrakis ◽  
Petros A. Tarantilis ◽  
Christos S. Pappas
Keyword(s):  
Fluorescence Spectroscopy ◽  
External Validation ◽  
Three Dimensional ◽  
Excitation Wavelength ◽  
Botanical Origin ◽  
Linear Discriminant ◽  
Classification Score ◽  
Hydroxybenzoic Acids ◽  
Unifloral Honey ◽  
Novel Method

The standardization of the botanical origin of honey reflects the commercial value and quality of honey. Nowadays, most consumers are looking for a unifloral honey. The aim of the present study was to develop a novel method for honey classification using chemometric models based on phenolic compounds analyzed with right angle fluorescence spectroscopy, coupled with stepwise linear discriminant analysis (LDA). The deconstructed spectrum from three-dimensional-emission excitation matrix (3D-EEM) spectra provided a correct classification score of 94.9% calibration and cross-validation at an excitation wavelength (λex) of 330 nm. Subsequently, a score of 81.4% and 79.7%, respectively, at an excitation wavelength (λex) of 360 nm was achieved. Each chemometric model confirmed its power through the external validation with a score of 82.1% for both. Differentiation could be correlated with hydroxycinnamic and hydroxybenzoic acids, which absorb in this region of the spectrum. Fluorescence spectroscopy constitutes a rapid and sensitive technique, which, when combined with the stepwise algorithm and LDA method, can be used as a reliable and predictive authentication tool for honey. This study indicates that the developed methodology is a promising technique for determination of the botanical origin of common Greek honey varieties. Our long-term ambition is to support producers and suppliers to remain in a competitive national and international market.

Absorbance-Corrected Synchronous Fluorescence with a Fiber-Optic-Based Fluorometer

1995 ◽  
Vol 49 (7) ◽  
pp. 1041-1047 ◽  
Author(s):  
Mark A. Victor ◽  
Stanley R. Crouch
Keyword(s):  
Transfer Function ◽  
Fluorescence Spectroscopy ◽  
Fiber Optics ◽  
Fiber Optic ◽  
Coupling Efficiency ◽  
Synchronous Fluorescence ◽  
Fluorescence Measurement ◽  
Synchronous Fluorescence Spectroscopy ◽  
Inner Filter Effects ◽  
Filter Effects

Synchronous fluorescence spectroscopy is frequently used to resolve multiple components in mixtures without separation. However, uncompensated inner-filter effects can lead to unexpected and/or large quantitative errors. An instrument and a method that correct for primary and secondary inner-filter effects in synchronous fluorescence spectroscopy have been designed and characterized. A bifurcated fiber-optic-based diode array fluorometer that simultaneously measures front-surface fluorescence and absorbance was constructed. A transfer function that mathematically describes the coupling efficiency between the excitation and emission legs of the fiber optics is defined and characterized. Once characterized, such a fluorometer is capable of calculating what the fluorescence measurement would be in the absence of inner-filter effects. Several experimental procedures for determining the instrument's transfer function are compared and discussed. Applications of the various procedures to experimental fluorescence inner-filter corrections to problematic samples are demonstrated.

scholarly journals Fiber Optic Sensing Technologies for Battery Management Systems and Energy Storage Applications

Sensors ◽  
2021 ◽  
Vol 21 (4) ◽  
pp. 1397
Author(s):  
Yang-Duan Su ◽  
Yuliya Preger ◽  
Hannah Burroughs ◽  
Chenhu Sun ◽  
Paul Ohodnicki
Keyword(s):  
Energy Storage ◽  
Fiber Optics ◽  
Fiber Optic ◽  
Gas Sensing ◽  
Fiber Optic Sensors ◽  
Management Systems ◽  
Practical Implementation ◽  
Battery Management ◽  
Battery Management Systems ◽  
Battery Systems

Applications of fiber optic sensors to battery monitoring have been increasing due to the growing need of enhanced battery management systems with accurate state estimations. The goal of this review is to discuss the advancements enabling the practical implementation of battery internal parameter measurements including local temperature, strain, pressure, and refractive index for general operation, as well as the external measurements such as temperature gradients and vent gas sensing for thermal runaway imminent detection. A reasonable matching is discussed between fiber optic sensors of different range capabilities with battery systems of three levels of scales, namely electric vehicle and heavy-duty electric truck battery packs, and grid-scale battery systems. The advantages of fiber optic sensors over electrical sensors are discussed, while electrochemical stability issues of fiber-implanted batteries are critically assessed. This review also includes the estimated sensing system costs for typical fiber optic sensors and identifies the high interrogation cost as one of the limitations in their practical deployment into batteries. Finally, future perspectives are considered in the implementation of fiber optics into high-value battery applications such as grid-scale energy storage fault detection and prediction systems.

scholarly journals Microanchored borehole fiber optics allows strain profiling of the shallow subsurface

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Cheng-Cheng Zhang ◽  
Bin Shi ◽  
Song Zhang ◽  
Kai Gu ◽  
Su-Ping Liu ◽  
...  
Keyword(s):  
Fiber Optics ◽  
Field Experiments ◽  
Fiber Optic ◽  
Strain Sensing ◽  
Near Surface ◽  
Shallow Subsurface ◽  
Buried Cables ◽  
Capacity Theory ◽  
Confining Pressures ◽  
Strain Determination

AbstractVertical deformation profiles of subterranean geological formations are conventionally measured by borehole extensometry. Distributed strain sensing (DSS) paired with fiber-optic cables installed in the ground opens up possibilities for acquiring high-resolution static and quasistatic strain profiles of deforming strata, but it is currently limited by reduced data quality due to complicated patterns of interaction between the buried cables and their surroundings, especially in upper soil layers under low confining pressures. Extending recent DSS studies, we present an improved approach using microanchored fiber-optic cables—designed to optimize ground-to-cable coupling at the near surface—for strain determination along entire lengths of vertical boreholes. We proposed a novel criterion for soil–cable coupling evaluation based on the geotechnical bearing capacity theory. We applied this enhanced methodology to monitor groundwater-related vertical motions in both laboratory and field experiments. Corroborating extensometer recordings, acquired simultaneously, validated fiber optically determined displacements, suggesting microanchored DSS as an improved means for detecting and monitoring shallow subsurface strain profiles.

Design optimization of fiber optic probes for remote fluorescence spectroscopy

2009 ◽  
Vol 282 (14) ◽  
pp. 2676-2684 ◽  
Author(s):  
G.K. Bhowmick ◽  
Nutan Gautam ◽  
L.M. Gantayet
Keyword(s):  
Fluorescence Spectroscopy ◽  
Design Optimization ◽  
Fiber Optic ◽  
Fiber Optic Probes

Fiber-optic transmission catheter for regional venous oxygen saturation and blood flow

1992 ◽  
Vol 72 (4) ◽  
pp. 1616-1621 ◽  
Author(s):  
H. Iwasaki ◽  
K. Yoshizaki ◽  
H. Koyano
Keyword(s):  
Blood Flow ◽  
Oxygen Saturation ◽  
Fiber Optics ◽  
Fiber Optic ◽  
Supply And Demand ◽  
Flow Measurements ◽  
Face To Face ◽  
Flexible Polymer ◽  
Venous Oxygen Saturation ◽  
The Face

We have developed a method for monitoring regional venous oxygen saturation. The key feature of this system is the use of highly flexible polymer fiber optics, and this flexibility allowed the production of a new fiber-optic transmission catheter. The space between the “face-to-face” positioned fiber-optic tips forms a remote catheter-based transmission cell. Our method applies Twersky's theory, in which absorption and scattering can be treated independently. Fresh rabbit blood was pumped through a disk oxygenator in which gas exchange occurred and passed the catheter. Simultaneous results obtained by the catheter and a cuvette oximeter were excellent (r = 0.99, SD = 1.1%). Oxygen saturation measured by this catheter was independent of vessel wall artifacts, blood pH, and flow velocity. Another application of this method is measurement of blood flow by the dye- (indocyanine green) dilution technique. The results of flow measurements by the catheter appeared to be satisfactory (r = 0.99, SD = 1.7%). This study concludes that our method is effective for monitoring the balance between regional oxygen supply and demand.

scholarly journals Pendulum-Type Hetero-Core Fiber Optic Accelerometer for Low-Frequency Vibration Monitoring

Sensors ◽  
2018 ◽  
Vol 18 (8) ◽  
pp. 2528 ◽  
Author(s):  
Hiroshi Yamazaki ◽  
Ichiro Kurose ◽  
Michiko Nishiyama ◽  
Kazuhiro Watanabe
Keyword(s):  
Fiber Optics ◽  
Electromagnetic Interference ◽  
Large Scale ◽  
Fiber Optic ◽  
Low Frequency ◽  
Fiber Optic Sensor ◽  
Vibration Monitoring ◽  
Vibration Measurement ◽  
Displacement Sensor ◽  
Core Fiber

In this paper, a novel pendulum-type accelerometer based on hetero-core fiber optics has been proposed for structural health monitoring targeting large-scale civil infrastructures. Vibration measurement is a non-destructive method for diagnosing the failure of structures by assessing natural frequencies and other vibration patterns. The hetero-core fiber optic sensor utilized in the proposed accelerometer can serve as a displacement sensor with robustness to temperature changes, in addition to immunity to electromagnetic interference and chemical corrosions. Thus, the hetero-core sensor inside the accelerometer measures applied acceleration by detecting the rotation of an internal pendulum. A series of experiments showed that the hetero-core fiber sensor linearly responded to the rotation angle of the pendulum ranging within (−6°, 4°), and furthermore the proposed accelerometer could reproduce the waveform of input vibration in a frequency band of several Hz order.

scholarly journals A High-Frequency Sound based PGC Demodulation Scheme for Fiber Optics Hydrophone

2021 ◽  
Author(s):  
Yunjie Shi ◽  
Mengke Yin ◽  
Zijue Zhu ◽  
Shun Wang ◽  
Panting Niu ◽  
...  
Keyword(s):  
Fiber Optics ◽  
Sound Source ◽  
Acoustic Signal ◽  
High Frequency ◽  
Fiber Optic ◽  
Low Cost ◽  
Research Field ◽  
Interference Signal ◽  
High Frequency Sound ◽  
Frequency Sound

Abstract In the research field of fiber-optic hydrophone, the performance of demodulation scheme is crucial. In this work, a phase-generated-carrier (PGC) demodulation scheme based on high-frequency sound source is proposed. Highfrequency acoustic signal from the external sound source is applied to the fiber-optic hydrophone to achieve phase modulation of the interference signal instead of the piezo-electrical transducer (PZT) or frequency-modulated laser. It possesses the merits of low system complexity and low cost. Through the acoustic detection experiment, we achieve demodulation of acoustic signal at frequency varying from 300 Hz to 800 Hz, and the signal-to-noise ratio (SNR) is higher than 45 dB. Furthermore, the proposed scheme is successfully applied to time division multiplexing (TDM) experiment.

scholarly journals Analysis of Curvature in Fiber Optic Cable for Macrobending-Based Slope Sensor

2021 ◽  
Vol 3 (1) ◽  
pp. 45-56
Author(s):  
Imam Mulyanto
Keyword(s):  
Fiber Optics ◽  
Optical Fibers ◽  
Fiber Optic ◽  
Laser Light ◽  
Laser Intensity ◽  
Single Mode ◽  
Power Losses ◽  
Fiber Optic Cable ◽  
Power Meter ◽  
Working Principle

The analysis of fiber optics for macro bending-based slope sensors using SMF-28 single-mode optical fibers has been successfully conducted. Fiber optics were treated to silicon rubber molding and connected with laser light and power meters to measure the intensity of laser power generated. The working principle was carried out using the macrobending phenomenon on single-mode optical fibers. The intensity of laser light in fiber optic cables decreases in the event of indentation or bending of the fiber optic cable. Power losses resulting from the macrobending process can be seen in the result of the information sensitivity of fiber optics to the change of angle given. From the results of the study, the resulting fiber optic sensitivity value is -0.1534o/dBm. The larger the angle given, the lower the laser intensity received by the power meter.

Sign in / Sign up

Export Citation Format

Share Document