scholarly journals Assessment of the potential ecological and human health risks of heavy metals in Ahvaz oil field, Iran

PLoS ONE ◽  
2020 ◽  
Vol 15 (11) ◽  
pp. e0242703
Author(s):  
Mahmood Reza Ghorbani ◽  
Navid Ghanavati ◽  
Timoor Babaenejad ◽  
Ahad Nazarpour ◽  
Khoshnaz Payandeh
Keyword(s):  
Heavy Metals ◽  
Human Health ◽  
Inductively Coupled Plasma ◽  
Surface Soil ◽  
Principal Component ◽  
Potential Ecological Risk ◽  
Oil Field ◽  
Anthropogenic Sources ◽  
Potential Hazard ◽  
Drilling Mud

The potential hazard to human health from exposure to heavy metals in surface soil was assessed using 66 soil samples collected from Ahvaz oil field. To this end, the contents of heavy metals were measured by the inductively coupled plasma spectroscopy (ICP-OES). Mean levels of As, Cd, Co, Cr, Cu, Ni, Pb, V, and Zn were 5.9, 0.4, 7.1, 36.5, 41.2, 39.8, 67.4, 31.5, and 77.6 mg/kg, respectively. Contents of all studied heavy metals, with the exception of Co, Cr, and V, were several times higher than that of baselines. Correlation coefficients and principal component analysis (PCA) identified two main groups as sources of heavy metals in the surface soil of Ahvaz oil-field. Metals such as Co, Cr, and V were observed to originate from natural sources and As, Cd, Cu, Ni, Pb, and Zn originated from anthropogenic sources such as petroleum leakage and the pollution caused by drilling mud from oil wells. Pb and Zn were of significantly high EF mean enrichment value, and Co, Cu, Cd, and As had high enrichment in surface soil. Pb, Cr, V, Zn, Co, Cu, Ni, and As had a low potential ecological risk (PER) whereas Cd had a moderate PER. The risk of carcinogenic and non-carcinogenic diseases was detected to be higher in children than in adults. The carcinogenic risk (Cr) calculation was more than 1 × 10-6 for children and adults. Additionally, the CR of Cr for both children and adults indicated risk under control conditions.

scholarly journals GEOCHEMISTRY AND ENVIRONMENTAL ASSESSMENT OF HEAVY METALS IN SURFACE SOIL IN AL-HAWIJA, SOUTHWEST KIRKUK

2020 ◽  
Vol 53 (2E) ◽  
pp. 36-61
Author(s):  
Ahmed Al-Obeidi
Keyword(s):  
Heavy Metals ◽  
Soil Pollution ◽  
Ecological Risk ◽  
Inductively Coupled Plasma ◽  
Surface Soil ◽  
Risk Index ◽  
Size Fraction ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Anthropogenic Sources

Soil pollution adversely affects the safety and health of the human being. The main objective of the study is to determine the concentrations of heavy metals (As, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb and Zn) in surface soil in Al-Hawija, southwestern Kirkuk. Twenty-one samples were collected and analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) to measure the content of heavy metals and assess the soil pollution by using the contamination factor, degree of contamination, geoaccumulation index, pollution load index and ecological risk index (RI). The results indicate that there is high pollution by lead, chromium and copper (78.8, 87.4 and 53.8 mg/kg) respectively, in industrial areas due to anthropogenic sources with the presence of significant ecological risk (Er) of the lead (116) in site S7, due to its high concentrations, while size fraction analysis indicated that all heavy metals are concentrated in the fine parts as a result of adsorption processes by clay minerals.

scholarly journals Heavy Metals Distribution, Sources, and Ecological Risk Assessment in Huixian Wetland, South China

Water ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 431
Author(s):  
Liangliang Huang ◽  
Saeed Rad ◽  
Li Xu ◽  
Liangying Gui ◽  
Xiaohong Song ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Ecological Risk ◽  
South China ◽  
Ecological Risk Assessment ◽  
Risk Index ◽  
Pollution Index ◽  
Principal Component ◽  
Potential Ecological Risk ◽  
Anthropogenic Sources

This research has focused on the source identification, concentration, and ecological risk assessment of eight heavy metals in the largest karst wetland (Huixian) of south China. Numerous samples from superficial soil and sediment within ten representative landuse types were collected and examined, and the results were analyzed using multiple methods. Single pollution index (Pi) results were underpinned by the Geoaccumulation index (Igeo) method, in which Cd was observed as the priority pollutant with the highest contamination degree in this area. As for the most polluted landuse type, via applying Nemerow’s synthetical contamination index (PN) and Potential ecological risk index (RI), the river and rape field posed the highest ecological risks, while moderate for the rest. To quantify the drivers of the contaminants, a principal component analysis (PCA) was carried out and weathering of the watershed’s parent carbonate rocks was found to be the main possible origin, followed by anthropogenic sources induced by agricultural fertilizer. Considering the impacts of these potentially toxic elements on public health, the results of this study are essential to take preventive actions for environmental protection and sustainable development in the region.

scholarly journals Health Risks Assessment of Rainwater Pollutants in Jengka, Pahang, Malaysia

2018 ◽  
Vol 7 (3.30) ◽  
pp. 15
Author(s):  
Siti Nadzifah Ghazali ◽  
Fazrul Razman ◽  
Mohd Zahari Abdullah
Keyword(s):  
Heavy Metals ◽  
Inductively Coupled Plasma ◽  
Principal Component ◽  
Anthropogenic Sources ◽  
Inductively Coupled ◽  
Icp Ms ◽  
Significant Difference ◽  
Plasma Mass Spectrometry ◽  
Health Risks Assessment ◽  
Risks Assessment

Rainwater samples were collected in Jengka, Pahang Malaysia. Temperature, pH, TDS, EC, Al, Cu, Mn, and Zn were measured. The concentrations of heavy metals (Al, Cu, Mn and Zn) in thirty-eight samples were analysed using inductively coupled plasma-mass spectrometry (ICP-MS). Statistical analysis results indicate that pH, TDS, and EC showed significant differences between wet and dry seasons. However, no significant difference was observed seasonally for heavy metals (HMs). All parameters, except pH, were below the Malaysian Drinking Water Guidelines (MDWG) value and the health risk assessment for HMs indicates the safe levels. Principal component analysis (PCA) suggests that HMs in rainwater in Jengka, Pahang were originated from natural and anthropogenic sources.  

scholarly journals Ecological Risk Assessment and Contamination History of Heavy Metals in the Sediments of Chagan Lake, Northeast China

Water ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 894
Author(s):  
Panfeng Liu ◽  
Chaojie Zheng ◽  
Meilan Wen ◽  
Xianrong Luo ◽  
Zhiqiang Wu ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Principal Component Analysis ◽  
Ecological Risk ◽  
Surface Sediment ◽  
Northeast China ◽  
Principal Component ◽  
Potential Ecological Risk ◽  
210Pb Dating ◽  
History Of ◽  
Chagan Lake

The study deals with the spatio-temporal distribution of heavy metals in the sediments of Chagan lake, Northeast China. The pollution history of heavy metals is studied simultaneously through the 210Pb dating method by analyzing the characteristic of As, Hg, Cd, Cr, Ni, Cu, Pb, and Zn concentration-depth profiles. The potential ecological risk index (RI) and geo-accumulation index (Igeo) were used to evaluate the contamination degree. Principal component analysis (PCA), based on the logarithmic transformation and isometric log-ratio (ilr) transformed data, was applied with the aim of identifying the sources of heavy metals. The element concentrations show that the heavy metals are enriched in the surface sediment and sediment core with a varying degree, which is higher in the surficial residue. The results of Igeo indicate that the Cd and Hg in the surface sediment have reached a slightly contaminated level while other elements, uncontaminated. The results of RI show that the study area can be classified as an area with moderate ecological risk in which Cd and Hg mostly contribute to the overall risk. For the sediment core, the 210Pb dating results accurately reflect the sedimentary history over 153 years. From two evaluation indices (RI and Igeo) calculated by element concentration, there is no contamination, and the potential ecological risk is low during this period. The comparative study between raw and ilr transformed data shows that the closure effect of the raw data can be eliminated by ilr transformation. After that, the components obtained by robust principal component analysis (RPCA) are more representative than those obtained by PCA, both based on ilr transformed dataset, after eliminating the influence of outliers. Based on ilr transformed data with RPCA, three primary sources could be inferred: Cr, Ni, As, Zn, and Cu are mainly derived from natural sources; the main source of Cd and Hg are associated with agricultural activities and energy development; as for Pb, it originated from traffic and coal-burning activities, which is consistent with the fact that the development of tourism, fishery, and agriculture industries has led to the continuous increasing levels of anthropogenic Pb in Chagan Lake. The summarized results and conclusions will undoubtedly enhance the governmental awareness of heavy metal pollution and facilitate appropriate pollution control measures in Chagan Lake.

Contamination status and ecological risk of heavy metals in surface sediment of Kelantan River and its nearshore area, Malaysia

2019 ◽  
Vol 20 (1) ◽  
pp. 103-117
Author(s):  
Nagaiah Pooveneswary ◽  
Ahmad Farid Bin Abu Bakar ◽  
Bong Chui Wei ◽  
Choon Weng Lee ◽  
Wang Ai Jun ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Ecological Risk ◽  
Surface Sediment ◽  
Inductively Coupled Plasma ◽  
Risk Index ◽  
Potential Ecological Risk ◽  
Pollution Load Index ◽  
Emission Spectrometry ◽  
Nearshore Area ◽  
Significant Enrichment

Abstract A study on contamination status and ecological risk of heavy metals in surface sediment at selected sites on Kelantan River and its nearshore area was carried out. Ten samples along Kelantan River and 25 samples from the nearshore were analyzed using inductively coupled plasma optical emission spectrometry (ICP-OES) to determine heavy metal concentrations. Sediment samples were also analyzed for particle size compositions, total organic matter and pH content. The average concentrations for As, Cd, Cr, Cu, Mn, Ni, Pb, Zn were 7.38, 1.31, 17.71, 11.40, 507.15, 5.97, 22.61, 32.95 mg/kg for riverine and 14.14, 4.59, 29.79, 14.07, 389.96, 9.65, 62.21, 41.04 mg/kg for nearshore samples respectively. The potential ecological risk index showed stations Bekok, Manek Urai, and RH under considerable risk followed by station Pasir Mas under moderate risk. The pollution load index classified four nearshore sites (KW10, KW17, KW18, KW37) as polluted. The geo-accumulation index (Igeo) categorized moderate contamination for Cd and Pb. The enrichment factor (EF) along the river categorized extremely high enrichment for Cd, and significant enrichment for As, Pb and Mn while Pb and As were under very high and significant enrichment in nearshore areas. Pb, Cu, Zn, As, Ni and Cr showed significant correlations with each other.

Risk estimation and multivariate statistical analysis of the heavy metal content of drinking water samples

2018 ◽  
Vol 34 (10) ◽  
pp. 714-725
Author(s):  
Rajan Jakhu ◽  
Rohit Mehra
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Drinking Water ◽  
Statistical Analysis ◽  
Water Samples ◽  
Multivariate Statistical Analysis ◽  
Inductively Coupled Plasma ◽  
Principal Component ◽  
Multivariate Statistical ◽  
Drinking Water Samples

Drinking water samples of Jaipur and Ajmer districts of Rajasthan, India, were collected and analyzed for the measurement of concentration of heavy metals. The purpose of this study was to determine the sources of the heavy metals in the drinking water. Inductively coupled plasma mass spectrometry was used for the determination of the heavy metal concentrations, and for the statistical analysis of the data, principal component analysis and cluster analysis were performed. It was observed from the results that with respect to WHO guidelines, the water samples of some locations exceeded the contamination levels for lead (Pb), selenium (Se), and mercury (Hg), and with reference to the EPA guidelines, the samples were determined unsuitable for drinking because of high concentrations of Pb and Hg. Using multivariate statistical analysis, we determined that copper, manganese, arsenic, Se, and Hg were of anthropogenic origin, while Pb, copper, and cadmium were of geogenic origin. The present study reports the dominance of the anthropogenic contributions over geogenics in the studied area. The sources of the anthropogenic contaminants need to be investigated in a future study.

scholarly journals Kontaminasi pestisida organofosfat dan logam berat pada airtanah di Wilayah Pantai Utara Jawa Tengah dan Jawa Timur

2020 ◽  
Vol 23 (3) ◽  
pp. 341-348
Author(s):  
B Tyas Susanti ◽  
Baskoro Rochaddi ◽  
Chrisna Adhi Suryono ◽  
Irwani Irwani
Keyword(s):  
Heavy Metals ◽  
Human Health ◽  
Fresh Water ◽  
Coastal Areas ◽  
Anthropogenic Sources ◽  
Organophosphate Pesticides ◽  
Central Java ◽  
Coastal Cities

 Groundwater is the main source of clean fresh water in coastal areas. Coastal cities development in many sectors often produces waste that pollutes groundwater, among others, in the form of pesticides and heavy metals. Chlorpyrifos, mercury and arsenic are contaminants that are toxic and endanger human health or the environment. The purpose of this study was to examine groundwater conditions against contamination of organophosphate pesticides, heavy metals Hg and As in the northern coastal areas of Central Java and East Java. Chlorpyrifos content was found in 4 sample locations with a concentration of 0.0004 - 0.0021 ppm. Hg content was found at 8 sample locations with a concentration of 0.004 - 0.321 ppm and As was found at all locations (26) samples with a concentration of 0.102 - 0.505 ppm. The results of the analysis show that the incidence of pesticides and heavy metals in groundwater has anthropogenic sources due to agricultural, industrial or residential waste activities.  Airtanah merupakan sumber daya air tawar bersih yang utama di wilayah pesisir. Perkembangan kota-kota pesisir di banyak sektor seringkali menghasilkan limbah yang mencemari airtanah antara lain berupa pestisida dan logam berat. Khlorpirifos, merkuri dan arsen merupakan kontaminan yang bersifat toksik dan membahayakan kesehatan manusia ataupun lingkungan. Tujuan penelitian ini mengkaji kondisi airtanah terhadap kontaminasi pestisida organofosfat, logam berat Hg dan As di daerah pantai utara Jawa Tengah dan Jawa Timur. Kandungan khlorpirifos ditemukan di 4 lokasi sampel dengan konsentrasi 0,0004 – 0,0021 ppm. Kandungan Hg ditemukan pada 8 lokasi sampel dengan konsentrasi 0,004 – 0,321 ppm dan As ditemukan pada semua lokasi (26) sampel dengan konsentrasi 0,102 – 0,505 ppm. Hasil analisis menunjukkan kejadian pestisida dan logam berat pada airtanah bersumber antropogenik akibat kegiatan pertanian,  industri atau limbah pemukiman.

scholarly journals Risk Assessment of Heavy Metal Pollution of Topsoil in the Proposed Land for UNIOSUN Teaching Hospital

2020 ◽  
Vol 2 (2) ◽  
Author(s):  
A. J. Anifowose
Keyword(s):  
Heavy Metals ◽  
Teaching Hospital ◽  
Ecological Risk ◽  
Inductively Coupled Plasma ◽  
Surface Soil ◽  
Risk Index ◽  
University Teaching ◽  
Emission Spectrometry ◽  
Elevated Concentration ◽  
Potential Threat

Heavy metals which are released to the soil are found to be deleterious to environment and biota. Such soil quality, particularly in residential proximities, must be assessed periodically. This study investigated nine (9) heavy metals (Cu, Pb, Cd, Fe, Cr, Zn, As, Mn, Ni) in the surface soil of an agrarian land for Osun State University Teaching Hospital, Osogbo, with a view to establishing their potential threat. They were measured in twenty (20) composite soil samples of the site by inductively coupled plasma-optical emission spectrometry (ICP-OES). The results showed that the average concentrations of Cu (6.5 mg/kg), Pb (5.4 mg/kg), Fe (5831 mg/kg), Cr (22 mg/kg), Zn (14.8 mg/kg), As (1.4 mg/kg), Mn (575 mg/kg), Ni (2.6 mg/kg) were within the permissible range and posed no ecological risk. However, Cd ranging 0.1–1.3 mg/kg (average, 0.6 mg/kg) moderately posed ecological risk due to its positive geo-accumulation index and constituted 86.5% of risk index of all the metals. Applications of agrochemicals, fertilizers in the previous agricultural activities could be the primary sources of the elevated concentration of Cd measured in the soil. The overall pollution assessment of the surface soil indicated moderate pollution of the site soil by the heavy metals.

scholarly journals Human health risk assessment of lead, cadmium, and mercury co-exposure from agricultural soils in the Tuzla Canton (Bosnia and Herzegovina)

2021 ◽  
Vol 72 (4) ◽  
pp. 268-279
Author(s):  
Maida Šljivić Husejnović ◽  
Saša Janković ◽  
Dragica Nikolić ◽  
Biljana Antonijević
Keyword(s):  
Heavy Metals ◽  
Health Risk ◽  
Human Health ◽  
Bosnia And Herzegovina ◽  
Inductively Coupled Plasma ◽  
Human Health Risk ◽  
Hazard Index ◽  
Probabilistic Methods ◽  
Skin Contact ◽  
Metal Levels

Abstract The aim of this study was to assess the risk of human exposure to lead (Pb), cadmium (Cd), and mercury (Hg) through agricultural soil by considering both uncertainty and variability in key exposure parameters. For this reason we collected soil samples from 29 locations in the Tuzla Canton (Bosnia and Herzegovina) and measured their metal levels with inductively coupled plasma atomic emission or absorption spectrometry (ICP-AES and ICP-AAS, respectively). The levels of Pb ranged from 13.33 to 1692.33 mg/kg, of Cd from 0.05 to 3.67 mg/kg, and of Hg from 0.02 to 2.73 mg/kg. To estimate cancer and non-cancer risks we used deterministic and semi-probabilistic methods. Lead was found to involve higher health risk than the other two heavy metals. Its hazard index (HI) decreased between population groups (children>women>men) and exposure routes (ingestion>skin contact>inhalation). Our Monte Carlo simulations indicated that Pb HIs for both adult populations had a 0.6 % probability to exceed the threshold value of 1, while in children this probability was 14.2 %. Cd and Hg showed no probability to exceed the threshold in any scenario. Our simulation results raise concern about possible adverse health effects of heavy metals from soil, especially in children. It is very important to continue monitoring environmental pollution and assess human health risk, not only with respect to soil, but also with other important environmental compartments, such as air and water.

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